Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution

doi:10.1016/j.cjche.2014.01.003

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (4): 646-651.DOI: 10.1016/j.cjche.2014.01.003

Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution

Yali Zhang¹, Xianjin Yu¹, Qinglong Wang¹, Zhijun Jiang², Tao Fang¹

1 College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China;
2 Zibo Guoli New Power Source Technology Co., Ltd., Zibo, Shandong 255086, China

收稿日期:2013-09-17 修回日期:2014-01-18 出版日期:2015-04-28 发布日期:2015-05-13
通讯作者: Xianjin Yu
基金资助:
Supported by Shandong provincial Natural Science Foundation,China (ZR2013EEM005),and the High Education Science Technology Program of Shandong Province,China (J12LA04).

Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution

Yali Zhang¹, Xianjin Yu¹, Qinglong Wang¹, Zhijun Jiang², Tao Fang¹

1 College of Chemical Engineering, Shandong University of Technology, Zibo 255049, China;
2 Zibo Guoli New Power Source Technology Co., Ltd., Zibo, Shandong 255086, China

Received:2013-09-17 Revised:2014-01-18 Online:2015-04-28 Published:2015-05-13
Contact: Xianjin Yu
Supported by:
Supported by Shandong provincial Natural Science Foundation,China (ZR2013EEM005),and the High Education Science Technology Program of Shandong Province,China (J12LA04).

摘要/Abstract

摘要： Removal of zinc fromcyanide barren solution is obligatory for its reuse in leach process. Batch experiments were carried out to evaluate the adsorption capacity of resins under different experimental conditions, including concentration, resin amount, initial pH, contact time and temperature. More than 99% of adsorption was achieved under the optimal condition. High adsorption rates on the resin were observed at the beginning and plateau values were obtained in 60 min. The thermodynamic parameters (free energy change ΔG, enthalpy change ΔS and entropy change ΔH) for the adsorption were evaluated. The adsorption kinetic mechanism was studied with four models. The experimental results show that the adsorption follows the Langmuir isotherm and the kinetics follows the pseudo-second-order model.

关键词: Anion-exchange resin, Adsorption isotherms, Adsorption kinetics

Abstract: Removal of zinc fromcyanide barren solution is obligatory for its reuse in leach process. Batch experiments were carried out to evaluate the adsorption capacity of resins under different experimental conditions, including concentration, resin amount, initial pH, contact time and temperature. More than 99% of adsorption was achieved under the optimal condition. High adsorption rates on the resin were observed at the beginning and plateau values were obtained in 60 min. The thermodynamic parameters (free energy change ΔG, enthalpy change ΔS and entropy change ΔH) for the adsorption were evaluated. The adsorption kinetic mechanism was studied with four models. The experimental results show that the adsorption follows the Langmuir isotherm and the kinetics follows the pseudo-second-order model.

Key words: Anion-exchange resin, Adsorption isotherms, Adsorption kinetics

Yali Zhang, Xianjin Yu, Qinglong Wang, Zhijun Jiang, Tao Fang. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution[J]. Chinese Journal of Chemical Engineering, 2015, 23(4): 646-651.

Yali Zhang, Xianjin Yu, Qinglong Wang, Zhijun Jiang, Tao Fang. Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution[J]. Chin.J.Chem.Eng., 2015, 23(4): 646-651.

参考文献

[1] Y.Y. Lu, W.D. Bin, Precious Metals Metallurgy, Central South University Press, 2004. 87-94.

[2] J.R. Parga, S.S. Shukla, F.R. Carrillo-Pedroza, Destruction of cyanide waste solutions using chlorine dioxide, ozone and titania sol, Waste Manag. 23 (2003) 183-191.

[3] N. GÖnen, O.S. Kabasakal, G. Özdil, Recovery of cyanide in gold leach waste solution by volatilization and absorption, J. Hazard. Mater. B113 (2004) 231-236.

[4] X. Dai, P.L. Breuer, M.I. Jeffrey, Comparison of activated carbon and ion-exchange resins in recovering copper from cyanide leach solutions, Hydrometallurgy 101 (2010) 48-57.

[5] X. Dai, P.L. Breuer, Cyanide and copper cyanide recovery by activated carbon, Miner. Eng. 22 (2009) 469-476.

[6] M.M. Botz, T.I. Mudder, A.U. Akcil, Cyanide treatment: Physical, chemical and biological process, Dev. Miner. Process. 15 (2005) 672-702.

[7] D. Bachiller, M. Torre, M. Rendueles, M. D?az, Cyanide recovery by ion exchange from gold ore waste effluents containing copper, Miner. Eng. 17 (2004) 767-774.

[8] G.H. Chen, Y.S. Zhang, Y.G. Sun, F.J. Zhou, S.G. Jiang, Experimental research on the treatment of cyanide poor liquid using resin exchange method, Gold Sci. Technol. 4 (2011) 74-77.

[9] F. Xie, D. Dreisinger, Recovery of copper cyanide from waste cyanide solution by LIX 7950, Miner. Eng. 22 (2009) 190-195.

[10] B.B. Han, Z.S. Shen, S.R.Wickramasinghe, Cyanide removal from industrial wastewaters using gas membranes, J. Membr. Sci. 257 (2005) 171-181.

[11] A. Akcil, A.G. Karahan, H. Ciftci, O. Sagdic, Biological treatment of cyanide by natural isolated bacteria, Miner. Eng. 16 (2003) 643-649.

[12] A. Akcil, T. Mudder, Microbial destruction of cyanide wastes in goldmining: Process review, Biotechnol. Lett. 25 (2003) 445-450.

[13] C.H. Xiong, J.F. Zhu, C. Shen, Q. Chen, Adsorption and desorption of praseodymium (III) from aqueous solution using D72 resin, Chin. J. Chem. Eng. 20 (5) (2012) 823-830.

[14] M.H. Mahaninia, P. Rahimian, T. Kaghazchi, Modified activated carbons with amino groups and their copper adsorption properties in aqueous solution, Chin. J. Chem. Eng. 23 (1) (2015) 50-56.

[15] J. Hua, C.L. Chen, X.X. Zhu, X.K.Wang, Removal of chromium from aqueous solution by using oxidized multiwalled carbon nanotubes, J. Hazard. Mater. 162 (2009) 1542-1550.

[16] I. Langmuir, The adsorption of gases on plane surfaces of glass,mica and platinum, J. Am. Chem. Soc. 40 (1918) 1361-1403.

[17] K.R. Hall, L.C. Eagleton, A. Acrivos, T. Vermeulen, Pore- and solid-diffusion kinetics in fixed-bed adsorption under constant-pattern conditions, Ind. Eng. Chem. Fundam. 5 (1966) 212-223.

[18] M. Arami, N.Y. Limaee, N.M. Mahmoodi, N.S. Tabrizi, Removal of dyes from colored textile wastewater by orange peel adsorbent: Equilibrium and kinetic studies, J. Colloid Interface Sci. 288 (2005) 371-376.

[19] H.M.F. Freundlich, Über die adsorption in lösungen, Z. Phys. Chem. 57 (3) (1906) 85-470.

[20] Y.S. Ho, G. McKay, Sorption of dye from aqueous solution by peat, Chem. Eng. J. 70 (1998) 115-124.

[21] C. Raji, T.S. Anirudhan, Batch Cr(VI) removal by polyacry lamide-grafted sawdust: kinetics and thermodynamics, Water Res. 32 (12) (1998) 3772-3780.

[22] G. Arslan, E. Pehlivan, Batch removal of chromium(VI) from aqueous solution by Turkish brown coals, Bioresour. Technol. 98 (2007) 2836-2845.

[23] S. Rengaraj, Y. Kyeong-Ho, M. Seung-Hyeon, Removal of chromium from water and wastewater by ion-exchange resins, J. Hazard. Mater. 87 (2001) 273-287.

[24] F. Gode, E. Pehlivan, A comparative study of two chelating ion-exchange resins for the removal of chromium(III) from aqueous solution, J. Hazard. Mater. 100 (2003) 231-243.

[25] N.K. Hamadi, X.D. Chen, M.M. Farid, M.G.Q. Lu, Adsorption kinetics for the removal of chromium(VI) from aqueous solution by adsorbents derived from used tyres and sawdust, Chem. Eng. J. 84 (2001) 95-105.

[26] C. Namasivayam, K. Kardivelu, Uptake of mercury(II) from wastewater by activated carbon from an unwanted agricultural solid by-product, Carbon 37 (1999) 79-84.

[27] Y.S. Ho, G. McKay, Kinetic models for the sorption of dye from aqueous solution by wood, Trans. I Chem E 76 (1998) 183-191.

[28] Y.S. Ho, G.McKay, Batch lead(II) removal fromaqueous solution by peat equilibrium and kinetics, Trans. I Chem E 77 (1999) 165-173.

[29] W.J. Weber, C.J. Morris, Advances in water pollution research, Proceedings of the First International Conference on Water Pollution Research, 221962. 31.

[30] S. Rengaraj, C.K. Joo, Y. Kim, J. Yi, Kinetics of removal of chromium from water and electronic process wastewater by ion exchange resins: 1200H, 1500H and IRN97H, J. Hazard. Mater. 102 (2003) 257-275.

[31] Y.S. Ho, G. McKay, Kinetic models for lead(II) sorption on to peat, Adsorpt. Sci. Technol. 16 (4) (1998) 243-255.

Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution

Adsorption of zinc onto anionic ion-exchange resin from cyanide barren solution

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