SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (11): 1513-1521.DOI: 10.1016/j.cjche.2016.03.006

• 第25届中国过程控制会议专栏 • 上一篇    下一篇

CO2/N2 separation using supported ionic liquid membranes with green and cost-effective[Choline] [Pro]/PEG200 mixtures

Tengteng Fan1, Wenlong Xie1, Xiaoyan Ji2, Chang Liu1, Xin Feng1, Xiaohua Lu1   

  1. 1 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
    2 Division of Energy Science/Energy Engineering, Luleå University of Technology, 97187 Luleå, Sweden
  • 收稿日期:2016-02-29 修回日期:2016-03-27 出版日期:2016-11-28 发布日期:2016-12-06
  • 通讯作者: Xin Feng
  • 基金资助:

    Supported by the National Basic Research Program of China (2013CB733501), the National Natural Science Foundation of China (21136004, 21176112, 21476106, and 21428601), Specialized Research Fund for the Doctoral Program of Higher Education (No. 20133221110001) and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

CO2/N2 separation using supported ionic liquid membranes with green and cost-effective[Choline] [Pro]/PEG200 mixtures

Tengteng Fan1, Wenlong Xie1, Xiaoyan Ji2, Chang Liu1, Xin Feng1, Xiaohua Lu1   

  1. 1 College of Chemistry and Chemical Engineering, State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
    2 Division of Energy Science/Energy Engineering, Luleå University of Technology, 97187 Luleå, Sweden
  • Received:2016-02-29 Revised:2016-03-27 Online:2016-11-28 Published:2016-12-06
  • Contact: Xin Feng
  • Supported by:

    Supported by the National Basic Research Program of China (2013CB733501), the National Natural Science Foundation of China (21136004, 21176112, 21476106, and 21428601), Specialized Research Fund for the Doctoral Program of Higher Education (No. 20133221110001) and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要: The high price and toxicity of ionic liquids (ILs) have limited the design and application of supported ionic liquid membranes (SILMs) for CO2 separation in both academic and industrial fields. In this work,[Choline] [Pro]/polyethylene glycol 200 (PEG200) mixtures were selected to prepare novel SILMs because of their green and costeffective characterization, and the CO2/N2 separation with the prepared SILMs was investigated experimentally at temperatures from 308.15 to 343.15 K. The temperature effect on the permeability, solubility and diffusivity of CO2 was modeled with the Arrhenius equation. A competitive performance of the prepared SILMs was observed with high CO2 permeability ranged in 343.3-1798.6 barrer and high CO2/N2 selectivity from 7.9 to 34.8. It was also found that the CO2 permeability increased 3 times by decreasing the viscosity of liquids from 370 to 38 mPa·s. In addition, the inherent mechanism behind the significant permeability enhancement was revealed based on the diffusion-reaction theory, i.e. with the addition of PEG200, the overall resistance was substantially decreased and the SILMs process was switched from diffusion-control to reaction-control.

关键词: CO2/N2 separation, Supported ionic liquid membranes (SILMs), [Choline] [Pro]/PEG200, Diffusion-reaction theory

Abstract: The high price and toxicity of ionic liquids (ILs) have limited the design and application of supported ionic liquid membranes (SILMs) for CO2 separation in both academic and industrial fields. In this work,[Choline] [Pro]/polyethylene glycol 200 (PEG200) mixtures were selected to prepare novel SILMs because of their green and costeffective characterization, and the CO2/N2 separation with the prepared SILMs was investigated experimentally at temperatures from 308.15 to 343.15 K. The temperature effect on the permeability, solubility and diffusivity of CO2 was modeled with the Arrhenius equation. A competitive performance of the prepared SILMs was observed with high CO2 permeability ranged in 343.3-1798.6 barrer and high CO2/N2 selectivity from 7.9 to 34.8. It was also found that the CO2 permeability increased 3 times by decreasing the viscosity of liquids from 370 to 38 mPa·s. In addition, the inherent mechanism behind the significant permeability enhancement was revealed based on the diffusion-reaction theory, i.e. with the addition of PEG200, the overall resistance was substantially decreased and the SILMs process was switched from diffusion-control to reaction-control.

Key words: CO2/N2 separation, Supported ionic liquid membranes (SILMs), [Choline] [Pro]/PEG200, Diffusion-reaction theory