Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO2 separation

doi:10.1016/j.cjche.2022.02.014

中国化学工程学报 ›› 2022, Vol. 43 ›› Issue (3): 152-160.DOI: 10.1016/j.cjche.2022.02.014

Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO₂ separation

Haoqing Xu^1,2, Wenyan Feng^1,2, Menglong Sheng^1,2, Ye Yuan^1,2, Bo Wang³, Jixiao Wang^1,2, Zhi Wang^1,2

1. Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2. Tianjin Key Laboratory of Membrane Science and Desalination Technology, State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China;
3. Life and Health Research Institute, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

收稿日期:2021-08-23 修回日期:2022-02-21 出版日期:2022-03-28 发布日期:2022-04-28
通讯作者: Zhi Wang,E-mail:wangzhi@tju.edu.cn
基金资助:
This research is supported by the National Key Research & Development Program of China (2017YFB0603400), the National Natural Science Foundation of China (21938007).

Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO₂ separation

Haoqing Xu^1,2, Wenyan Feng^1,2, Menglong Sheng^1,2, Ye Yuan^1,2, Bo Wang³, Jixiao Wang^1,2, Zhi Wang^1,2

1. Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
2. Tianjin Key Laboratory of Membrane Science and Desalination Technology, State Key Laboratory of Chemical Engineering, Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China;
3. Life and Health Research Institute, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China

Received:2021-08-23 Revised:2022-02-21 Online:2022-03-28 Published:2022-04-28
Contact: Zhi Wang,E-mail:wangzhi@tju.edu.cn
Supported by:
This research is supported by the National Key Research & Development Program of China (2017YFB0603400), the National Natural Science Foundation of China (21938007).

摘要/Abstract

摘要： Thin film composite (TFC) membranes with nanofillers additives for CO₂ separation show promising applications in energy and environment-related fields. However, the poor compatibility between nanofillers and polymers in TFC membranes is the main problem. In this work, covalent organic frameworks (COFs, TpPa-1) with rich —NH— groups were incorporated into polyamide (PA) segment via in situ interfacial polymerization to prepare defect-free TFC membranes for CO₂/N₂ separation. The formed covalent bonds between TpPa-1 and PA strengthen the interaction between nanofillers and polymers, thereby enhancing compatibility. Besides, the incorporated COFs disturb the rigid structure of the PA layer, and provide fast CO₂ transfer channels. The incorporated COFs also increase the content of effective carriers, which enhances the CO₂ facilitated transport. Consequently, in CO₂/N₂ mixed gas separation test, the optimal TFC (TpPa_0.025-PIP-TMC/mPSf) membrane exhibits high CO₂ permeance of 854 GPU and high CO₂/N₂ selectivity of 148 at 0.15 MPa, CO₂ permeance of 456 GPU (gas permeation unit) and CO₂/N₂ selectivity of 92 at 0.5 MPa. In addition, the TpPa_0.025-PIP-TMC/mPSf membrane also achieves high permselectivty in CO₂/CH₄ mixed gas separation test. Finally, the optimal TFC membrane showes good stability in the simulated flue gas test, revealing the application potential for CO₂ capture from flue gas.

关键词: Covalent organic frameworks, CO₂/N₂ separation, In situ interfacial polymerization, Compatibility, Covalent bonds

Abstract: Thin film composite (TFC) membranes with nanofillers additives for CO₂ separation show promising applications in energy and environment-related fields. However, the poor compatibility between nanofillers and polymers in TFC membranes is the main problem. In this work, covalent organic frameworks (COFs, TpPa-1) with rich —NH— groups were incorporated into polyamide (PA) segment via in situ interfacial polymerization to prepare defect-free TFC membranes for CO₂/N₂ separation. The formed covalent bonds between TpPa-1 and PA strengthen the interaction between nanofillers and polymers, thereby enhancing compatibility. Besides, the incorporated COFs disturb the rigid structure of the PA layer, and provide fast CO₂ transfer channels. The incorporated COFs also increase the content of effective carriers, which enhances the CO₂ facilitated transport. Consequently, in CO₂/N₂ mixed gas separation test, the optimal TFC (TpPa_0.025-PIP-TMC/mPSf) membrane exhibits high CO₂ permeance of 854 GPU and high CO₂/N₂ selectivity of 148 at 0.15 MPa, CO₂ permeance of 456 GPU (gas permeation unit) and CO₂/N₂ selectivity of 92 at 0.5 MPa. In addition, the TpPa_0.025-PIP-TMC/mPSf membrane also achieves high permselectivty in CO₂/CH₄ mixed gas separation test. Finally, the optimal TFC membrane showes good stability in the simulated flue gas test, revealing the application potential for CO₂ capture from flue gas.

Key words: Covalent organic frameworks, CO₂/N₂ separation, In situ interfacial polymerization, Compatibility, Covalent bonds

Haoqing Xu, Wenyan Feng, Menglong Sheng, Ye Yuan, Bo Wang, Jixiao Wang, Zhi Wang. Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO₂ separation[J]. 中国化学工程学报, 2022, 43(3): 152-160.

参考文献

[1] C. Marichy, M. Bechelany, N. Pinna, Atomic layer deposition of nanostructured materials for energy and environmental applications, Adv. Mater. 24 (8) (2012) 1017-1032
[2] B. Seoane, J. Coronas, I. Gascon, M. Etxeberria Benavides, O. Karvan, J. Caro, F. Kapteijn, J. Gascon, Metal-organic framework based mixed matrix membranes:A solution for highly efficient CO₂ capture? Chem. Soc. Rev. 44 (8) (2015) 2421-2454
[3] Y.W. Jeon, D.H. Lee, Gas membranes for CO₂/CH₄ (biogas) separation:A review, Environ. Eng. Sci. 32 (2) (2015) 71-85
[4] S. Basu, A.L. Khan, A. Cano-Odena, C.Q. Liu, I.F.J. Vankelecom, Membrane-based technologies for biogas separations, Chem. Soc. Rev. 39 (2) (2010) 750-768
[5] P. Bernardo, E. Drioli, G. Golemme, Membrane gas separation:A review/state of the art, Ind. Eng. Chem. Res. 48 (10) (2009) 4638-4663
[6] S.C. Li, Z. Wang, C.X. Zhang, M.M. Wang, F. Yuan, J.X. Wang, S.C. Wang, Interfacially polymerized thin film composite membranes containing ethylene oxide groups for CO₂ separation, J. Membr. Sci. 436 (2013) 121-131
[7] J.Y. Xu, Z. Wang, Z.H. Qiao, H.Y. Wu, S.L. Dong, S. Zhao, J.X. Wang, Post-combustion CO₂ capture with membrane process:Practical membrane performance and appropriate pressure, J. Membr. Sci. 581 (2019) 195-213
[8] S.R. Reijerkerk, M. Wessling, K. Nijmeijer, Pushing the limits of block copolymer membranes for CO₂ separation, J. Membr. Sci. 378 (1-2) (2011) 479-484
[9] J. Petersen, K.V. Peinemann, Novel polyamide composite membranes for gas separation prepared by interfacial polycondensation, J. Appl. Polym. Sci. 63 (12) (1997) 1557-1563
[10] M. Mulder, Basic Principles of Membrane Technology, Kluwer Academic Publishers, Netherlands, 1996
[11] I.C. Omole, D.A. Bhandari, S.J. Miller, W.J. Koros, Toluene impurity effects on CO₂ separation using a hollow fiber membrane for natural gas, J. Membr. Sci. 369 (1-2) (2011) 490-498
[12] X.W. Yu, Z. Wang, Z.H. Wei, S.J. Yuan, J. Zhao, J.X. Wang, S.C. Wang, Novel tertiary amino containing thin film composite membranes prepared by interfacial polymerization for CO₂ capture, J. Membr. Sci. 362 (1-2) (2010) 265-278
[13] J. Zhao, Z. Wang, J.X. Wang, S.C. Wang, Influence of heat-treatment on CO₂ separation performance of novel fixed carrier composite membranes prepared by interfacial polymerization, J. Membr. Sci. 283 (1-2) (2006) 346-356
[14] S.J. Yuan, Z. Wang, Z.H. Qiao, M.M. Wang, J.X. Wang, S.C. Wang, Improvement of CO₂/N₂ separation characteristics of polyvinylamine by modifying with ethylenediamine, J. Membr. Sci. 378 (1-2) (2011) 425-437
[15] J. Zou, W.S.W. Ho, CO₂-selective polymeric membranes containing amines in crosslinked poly(vinyl alcohol), J. Membr. Sci. 286 (1-2) (2006) 310-321
[16] L.Y. Deng, T.J. Kim, M.B. Hägg, Facilitated transport of CO₂ in novel PVAm/PVA blend membrane, J. Membr. Sci. 340 (1-2) (2009) 154-163
[17] Z.H. Qiao, Z. Wang, C.X. Zhang, S.J. Yuan, Y.Q. Zhu, J.X. Wang, S.C. Wang, PVAm-PIP/PS composite membrane with high performance for CO₂/N₂ Separation, Aiche J. 59 (1) (2013) 215-228
[18] W.J. He, Z. Wang, W. Li, S.C. Li, Z.H. Bai, J.X. Wang, S.C. Wang, Cyclic tertiary amino group containing fixed carrier membranes for CO₂ separation, J. Membr. Sci. 476 (2015) 171-181
[19] Y.N. Zhao, W.S. Winston Ho, Steric hindrance effect on amine demonstrated in solid polymer membranes for CO₂ transport, J. Membr. Sci. 415-416 (2012) 132-138
[20] S.C. Li, Z. Wang, X.W. Yu, J.X. Wang, S.C. Wang, High-performance membranes with multi-permselectivity for CO₂ separation, Adv. Mater. 24 (24) (2012) 3196-3200
[21] N. Li, Z. Wang, M. Wang, M. Gao, H.Y. Wu, S. Zhao, J.X. Wang, Swelling-controlled positioning of nanofillers through a polyamide layer in thin-film nanocomposite membranes for CO₂ separation, J. Membr. Sci. 624 (2021) 119095
[22] A.F. Bushell, P.M. Budd, M.P. Attfield, J.T.A. Jones, T. Hasell, A.I. Cooper, P. Bernardo, F. Bazzarelli, G. Clarizia, J.C. Jansen, Nanoporous organic polymer/cage composite membranes, Angewandte Chemie Int. Ed. 52 (4) (2013) 1253-1256
[23] J.D. Evans, D.M. Huang, M.R. Hill, C.J. Sumby, A.W. Thornton, C.J. Doonan, Feasibility of mixed matrix membrane gas separations employing porous organic cages, J. Phys. Chem. C 118 (3) (2014) 1523-1529
[24] C.L. Jiao, X.J. Song, X.Q. Zhang, L.X. Sun, H.Q. Jiang, MOF-Mediated Interfacial Polymerization to Fabricate Polyamide Membranes with a Homogeneous Nanoscale Striped Turing Structure for CO₂/CH₄ Separation, ACS Appl. Mater. Inter., 13 (2021) 18380-18388
[25] M.H. Davood Abadi Farahani, D. Hua, T.S. Chung, Cross-linked mixed matrix membranes (MMMs) consisting of amine-functionalized multi-walled carbon nanotubes and P84 polyimide for organic solvent nanofiltration (OSN) with enhanced flux, J. Membr. Sci. 548 (2018) 319-331
[26] J. Shen, G.P. Liu, K. Huang, Q.Q. Li, K.C. Guan, Y.K. Li, W.Q. Jin, UiO-66-polyether block amide mixed matrix membranes for CO₂ separation, J. Membr. Sci. 513 (2016) 155-165
[27] J.B. James, Y.S. Lin, Thermal stability of ZIF-8 membranes for gas separations, J. Membr. Sci. 532 (2017) 9-19
[28] S.S. Yuan, X. Li, J.Y. Zhu, G. Zhang, P. van Puyvelde, B. van der Bruggen, Covalent organic frameworks for membrane separation, Chem. Soc. Rev. 48 (10) (2019) 2665-2681
[29] Y.D. Cheng, L.Z. Zhai, Y.P. Ying, Y.X. Wang, G.L. Liu, J.Q. Dong, D.Z.L. Ng, S.A. Khan, D. Zhao, Highly efficient CO₂ capture by mixed matrix membranes containing three-dimensional covalent organic framework fillers, J. Mater. Chem. A 7 (9) (2019) 4549-4560
[30] S. Kandambeth, A. Mallick, B. Lukose, M.V. Mane, T. Heine, R. Banerjee, Construction of crystalline 2D covalent organic frameworks with remarkable chemical (acid/base) stability via a combined reversible and irreversible route, J. Am. Chem. Soc. 134 (48) (2012) 19524-19527
[31] L.N. Xu, J. Xu, B.T. Shan, X.L. Wang, C.J. Gao, TpPa-2-incorporated mixed matrix membranes for efficient water purification, J. Membr. Sci. 526 (2017) 355-366
[32] X.Y. Guo, D.H. Liu, T.T. Han, H.L. Huang, Q.Y. Yang, C.L. Zhong, Preparation of thin film nanocomposite membranes with surface modified MOF for high flux organic solvent nanofiltration, AIChE J. 63 (4) (2017) 1303-1312
[33] L.Y. Wang, M.Q. Fang, J. Liu, J. He, J.D. Li, J.D. Lei, Layer-by-layer fabrication of high-performance polyamide/ZIF-8 nanocomposite membrane for nanofiltration applications, ACS Appl. Mater. Interfaces 7 (43) (2015) 24082-24093
[34] C.B. Wang, Z.Y. Li, J.X. Chen, Z. Li, Y.H. Yin, L. Cao, Y.L. Zhong, H. Wu, Covalent organic framework modified polyamide nanofiltration membrane with enhanced performance for desalination, J. Membr. Sci. 523 (2017) 273-281
[35] B.H. Jeong, E.M.V. Hoek, Y.S. Yan, A. Subramani, X.F. Huang, G. Hurwitz, A.K. Ghosh, A. Jawor, Interfacial polymerization of thin film nanocomposites:A new concept for reverse osmosis membranes, J. Membr. Sci. 294 (1-2) (2007) 1-7
[36] S. Sorribas, P. Gorgojo, C. Téllez, J. Coronas, A.G. Livingston, High flux thin film nanocomposite membranes based on metal-organic frameworks for organic solvent nanofiltration, J. Am. Chem. Soc. 135 (40) (2013) 15201-15208
[37] K.C. Wong, P.S. Goh, A.F. Ismail, Thin film nanocomposite:The next generation selective membrane for CO₂ removal, J. Mater. Chem. A 4 (41) (2016) 15726-15748
[38] R. Xu, Z. Wang, M. Wang, Z.H. Qiao, J.X. Wang, High nanoparticles loadings mixed matrix membranes via chemical bridging-crosslinking for CO₂ separation, J. Membr. Sci. 573 (2019) 455-464
[39] Z.G. Wang, D. Wang, S.X. Zhang, L. Hu, J. Jin, Interfacial design of mixed matrix membranes for improved gas separation performance, Adv. Mater. 28 (17) (2016) 3399-3405
[40] X.Y. Guo, H.L. Huang, Y.J. Ban, Q.Y. Yang, Y.L. Xiao, Y.S. Li, W.S. Yang, C.L. Zhong, Mixed matrix membranes incorporated with amine-functionalized titanium-based metal-organic framework for CO₂/CH₄ separation, J. Membr. Sci. 478 (2015) 130-139
[41] X.C. Cao, Z. Wang, Z.H. Qiao, S. Zhao, J.X. Wang, Penetrated COF channels:Amino environment and suitable size for CO₂ preferential adsorption and transport in mixed matrix membranes, ACS Appl. Mater. Interfaces 11 (5) (2019) 5306-5315
[42] O.G. Nik, X.Y. Chen, S. Kaliaguine, Functionalized metal organic framework-polyimide mixed matrix membranes for CO₂/CH₄ separation, J. Membr. Sci. 413-414 (2012) 48-61
[43] H. Li, L.H. Tuo, K. Yang, H.K. Jeong, Y. Dai, G.H. He, W. Zhao, Simultaneous enhancement of mechanical properties and CO₂ selectivity of ZIF-8 mixed matrix membranes:Interfacial toughening effect of ionic liquid, J. Membr. Sci. 511 (2016) 130-142
[44] S.R. Venna, M. Lartey, T. Li, A. Spore, S. Kumar, H.B. Nulwala, D.R. Luebke, N.L. Rosi, E. Albenze, Fabrication of MMMs with improved gas separation properties using externally-functionalized MOF particles, J. Mater. Chem. A 3 (9) (2015) 5014-5022
[45] S. Shahid, K. Nijmeijer, S. Nehache, I. Vankelecom, A. Deratani, D. Quemener, MOF-mixed matrix membranes:Precise dispersion of MOF particles with better compatibility via a particle fusion approach for enhanced gas separation properties, J. Membr. Sci. 492 (2015) 21-31
[46] S. Friebe, A. Mundstock, D. Unruh, F. Renz, J. Caro, NH₂-MIL-125 as membrane for carbon dioxide sequestration:Thin supported MOF layers contra Mixed-Matrix-Membranes, J. Membr. Sci. 516 (2016) 185-193
[47] S.W. Yu, S.C. Li, S.L. Huang, Z.H. Zeng, S. Cui, Y. Liu, Covalently bonded zeolitic imidazolate frameworks and polymers with enhanced compatibility in thin film nanocomposite membranes for gas separation, J. Membr. Sci. 540 (2017) 155-164
[48] S.Y. Ding, W. Wang, Covalent organic frameworks (COFs):From design to applications, Chem. Soc. Rev. 42 (2) (2013) 548-568
[49] L.C. Lin, J. Choi, J.C. Grossman, Two-dimensional covalent triazine framework as an ultrathin-film nanoporous membrane for desalination, Chem. Commun. (Camb) 51 (80) (2015) 14921-14924
[50] X. Gao, X.Q. Zou, H.P. Ma, S. Meng, G.S. Zhu, Highly selective and permeable porous organic framework membrane for CO₂ capture, Adv. Mater. 26 (22) (2014) 3644-3648
[51] C.X. Yang, C. Liu, Y.M. Cao, X.P. Yan, Facile room-temperature solution-phase synthesis of a spherical covalent organic framework for high-resolution chromatographic separation, Chem. Commun. 51 (61) (2015) 12254-12257
[52] Y.Q. Gao, Z.H. Qiao, S. Zhao, Z. Wang, J.X. Wang, In situ synthesis of polymer grafted ZIFs and application in mixed matrix membrane for CO₂ separation, J. Mater. Chem. A 6 (7) (2018) 3151-3161
[53] C.C. Zou, Q.Q. Li, Y.Y. Hua, B.H. Zhou, J.G. Duan, W.Q. Jin, Mechanical synthesis of COF nanosheet cluster and its mixed matrix membrane for efficient CO₂ removal, ACS Appl. Mater. Interfaces 9 (34) (2017) 29093-29100
[54] K. Kawakami, S.L. Zhang, R.S. Chauhan, N. Ishizuka, M. Yamamoto, Y. Masaoka, M. Kataoka, S. Yamashita, S. Sakuma, Preparation of fenofibrate solid dispersion using electrospray deposition and improvement in oral absorption by instantaneous post-heating of the formulation, Int. J. Pharm. 450 (1-2) (2013) 123-128
[55] M.A. Imran, T.T. Li, X.M. Wu, X.M. Yan, A.S. Khan, G.H. He, Sulfonated polybenzimidazole/amine functionalized titanium dioxide (sPBI/AFT) composite electrolyte membranes for high temperature proton exchange membrane fuel cells usage, Chin. J. Chem. Eng. 28 (9) (2020) 2425-2437
[56] M.N.A. Seman, M. Khayet, N. Hilal, Nanofiltration thin-film composite polyester polyethersulfone-based membranes prepared by interfacial polymerization, J. Membr. Sci. 348 (1-2) (2010) 109-116
[57] Y. Mansourpanah, S.S. Madaeni, A. Rahimpour, Fabrication and development of interfacial polymerized thin-film composite nanofiltration membrane using different surfactants in organic phase; study of morphology and performance, J. Membr. Sci. 343 (1-2) (2009) 219-228
[58] T.C. Merkel, H.Q. Lin, X.T. Wei, R. Baker, Power plant post-combustion carbon dioxide capture:An opportunity for membranes, J. Membr. Sci. 359 (1-2) (2010) 126-139
[59] M. Sandru, T.J. Kim, W. Capala, M. Huijbers, M.B. Hägg, Pilot scale testing of polymeric membranes for CO₂ capture from coal fired power plants, Energy Procedia 37 (2013) 6473-6480
[60] L.S. White, X.T. Wei, S. Pande, T. Wu, T.C. Merkel, Extended flue gas trials with a membrane-based pilot plant at a one-ton-per-day carbon capture rate, J. Membr. Sci. 496 (2015) 48-57
[61] A.P. Hallenbeck, J.R. Kitchin, Effects of O₂ and SO₂ on the capture capacity of a primary-amine based polymeric CO₂ sorbent, Ind. Eng. Chem. Res. 52 (31) (2013) 10788-10794
[62] J.H. Kim, S.Y. Ha, Y.M. Lee, Gas permeation of poly(amide-6-b-ethylene oxide) copolymer, J. Membr. Sci. 190 (2) (2001) 179-193
[63] H.Y. Zhang, R.L. Guo, J.P. Hou, Z. Wei, X.Q. Li, Mixed-matrix membranes containing carbon nanotubes composite with hydrogel for efficient CO₂ separation, ACS Appl. Mater. Interfaces 8 (42) (2016) 29044-29051

Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO₂ separation

Covalent organic frameworks-incorporated thin film composite membranes prepared by interfacial polymerization for efficient CO₂ separation

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[11]	Noel Jacob Kaleekkal, A. Thanigaivelan, M. Tarun, D. Mohan. A functional PES membrane for hemodialysis—Preparation, characterization and biocompatibility[J]. Chinese Journal of Chemical Engineering, 2015, 23(7): 1236-1244.
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