SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2017, Vol. 25 ›› Issue (11): 1581-1597.DOI: 10.1016/j.cjche.2017.07.006

• 膜和膜过程专刊 • 上一篇    下一篇

Recent advances on mixed matrix membranes for CO2 separation

Ming Wang1,2,3,4, Zhi Wang1,2,3,4, Song Zhao1,2,3,4, Jixiao Wang1,2,3,4, Shichang Wang1,2,3,4   

  1. 1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
    2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300350, China;
    3 State Key Laboratory of Chemical Engineering, Tianjin 300350, China;
    4 Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China
  • 收稿日期:2017-02-28 修回日期:2017-07-02 出版日期:2017-11-28 发布日期:2018-01-18
  • 通讯作者: Zhi Wang,E-mail address:wangzhi@tju.edu.cn
  • 基金资助:

    Supported by the National Natural Science Foundation of China (21436009) and the Program of Introducing Talents of Discipline to Universities (B06006).

Recent advances on mixed matrix membranes for CO2 separation

Ming Wang1,2,3,4, Zhi Wang1,2,3,4, Song Zhao1,2,3,4, Jixiao Wang1,2,3,4, Shichang Wang1,2,3,4   

  1. 1 Chemical Engineering Research Center, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China;
    2 Tianjin Key Laboratory of Membrane Science and Desalination Technology, Tianjin 300350, China;
    3 State Key Laboratory of Chemical Engineering, Tianjin 300350, China;
    4 Collaborative Innovation Center of Chemical Science and Engineering, Tianjin University, Tianjin 300350, China
  • Received:2017-02-28 Revised:2017-07-02 Online:2017-11-28 Published:2018-01-18
  • Contact: Zhi Wang,E-mail address:wangzhi@tju.edu.cn
  • Supported by:

    Supported by the National Natural Science Foundation of China (21436009) and the Program of Introducing Talents of Discipline to Universities (B06006).

摘要: Recent advances on mixed matrix membrane for CO2 separation are reviewed in this paper. To improve CO2 separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.

关键词: CO2 separation, Mixed matrix membrane, Material selection, Compatibility, Composite membrane, Future direction

Abstract: Recent advances on mixed matrix membrane for CO2 separation are reviewed in this paper. To improve CO2 separation performance of polymer membranes, mixed matrix membranes (MMMs) are developed. The concept of MMM is illustrated distinctly. Suitable polymer and inorganic or organic fillers for MMMs are summarized. Possible interface morphologies between polymer and filler, and the effect of interface morphologies on gas transport properties of MMMs are summarized. The methods to improve compatibility between polymer and filler are introduced. There are eight methods including silane coupling, Grignard treatment, incorporation of additive, grafting, in situ polymerization, polydopamine coating, particle fusion approach and polymer functionalization. To achieve higher productivity for industrial application, mixed matrix composite membranes are developed. The recent development on hollow fiber and flat mixed matrix composite membrane is reviewed in detail. Last, the future trend of MMM is forecasted.

Key words: CO2 separation, Mixed matrix membrane, Material selection, Compatibility, Composite membrane, Future direction