SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (9): 1998-2013.DOI: 10.1016/j.cjche.2018.12.002

• Special Issue on Natural Gas Hydrate • 上一篇    下一篇

Research progress in hydrate-based technologies and processes in China: A review

Chungang Xu, Xiaosen Li, Kefeng Yan, Xuke Ruan, Zhaoyang Chen, Zhiming Xia   

  1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510641, China;CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China;Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
  • 收稿日期:2018-09-20 修回日期:2018-11-22 出版日期:2019-09-28 发布日期:2019-12-04
  • 通讯作者: Xiaosen Li
  • 基金资助:
    Supported by the Key Program of National Natural Science Foundation of China (51736009), National Key R&D Program of China (2016YFC0304002, 2017YFC0307306), the National Natural Science Foundation of China (51476174), the CAS Science and Technology Apparatus Development Program (YZ201619), Frontier Sciences Key Research Program of the Chinese Academy of Sciences (QYZDJ-SSW-JSC033), Special project for Marine Economy Development of Guangdong Province (GDME-2018D002) and the National Natural Science Fund of Guangdong Province, China (2017A030313301).

Research progress in hydrate-based technologies and processes in China: A review

Chungang Xu, Xiaosen Li, Kefeng Yan, Xuke Ruan, Zhaoyang Chen, Zhiming Xia   

  1. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510641, China;CAS Key Laboratory of Gas Hydrate, Guangzhou 510640, China;Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development, Guangzhou 510640, China
  • Received:2018-09-20 Revised:2018-11-22 Online:2019-09-28 Published:2019-12-04
  • Contact: Xiaosen Li
  • Supported by:
    Supported by the Key Program of National Natural Science Foundation of China (51736009), National Key R&D Program of China (2016YFC0304002, 2017YFC0307306), the National Natural Science Foundation of China (51476174), the CAS Science and Technology Apparatus Development Program (YZ201619), Frontier Sciences Key Research Program of the Chinese Academy of Sciences (QYZDJ-SSW-JSC033), Special project for Marine Economy Development of Guangdong Province (GDME-2018D002) and the National Natural Science Fund of Guangdong Province, China (2017A030313301).

摘要: Natural gas hydrate (NGH) is considered as an alternative energy resource in the future as it is proven to contain about 2 times carbon resources of those contained in the fossil energy on Earth. Gas hydrate technology is a new technology which can be extensively used in methane production from NGH, gas separation and purification, gas transportation, sea-water desalination, pipeline safety and phase change energy storage, etc. Since the 1980s, the gas hydrate technology has become a research hotspot worldwide because of its relatively economic and environmental friendly characteristics. China is a big energy consuming country with coal as a dominant energy. With the development of the society, energy shortage and environmental pollution are becoming great obstacles to the progress of the country. Therefore, in order to ensure the sustainable development of the society, it is of great significance to develop and utilize NGH and vigorously develop the gas hydrate technology. In this paper, the research advances in hydrate-based processes in China are comprehensively reviewed from different aspects, mainly including gas separation and purification, hydrate formation inhibition, sea-water desalination and methane exploitation from NGH by CH4-CO2 replacement. We are trying to show the relevant research in China, and at the same time, summarize the characteristics of the research and put forward the corresponding problems in a technical way.

关键词: Gas hydrate, Natural gas hydrate (NGH), CO2 separation, Hydrate formation inhibition, CH4-CO2 replacement

Abstract: Natural gas hydrate (NGH) is considered as an alternative energy resource in the future as it is proven to contain about 2 times carbon resources of those contained in the fossil energy on Earth. Gas hydrate technology is a new technology which can be extensively used in methane production from NGH, gas separation and purification, gas transportation, sea-water desalination, pipeline safety and phase change energy storage, etc. Since the 1980s, the gas hydrate technology has become a research hotspot worldwide because of its relatively economic and environmental friendly characteristics. China is a big energy consuming country with coal as a dominant energy. With the development of the society, energy shortage and environmental pollution are becoming great obstacles to the progress of the country. Therefore, in order to ensure the sustainable development of the society, it is of great significance to develop and utilize NGH and vigorously develop the gas hydrate technology. In this paper, the research advances in hydrate-based processes in China are comprehensively reviewed from different aspects, mainly including gas separation and purification, hydrate formation inhibition, sea-water desalination and methane exploitation from NGH by CH4-CO2 replacement. We are trying to show the relevant research in China, and at the same time, summarize the characteristics of the research and put forward the corresponding problems in a technical way.

Key words: Gas hydrate, Natural gas hydrate (NGH), CO2 separation, Hydrate formation inhibition, CH4-CO2 replacement