Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model

doi:10.1016/j.cjche.2016.03.007

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (11): 1522-1526.DOI: 10.1016/j.cjche.2016.03.007

• 第25届中国过程控制会议专栏 • 上一篇下一篇

Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model

Changhai Li^1,2, Dongmei Jia^1,2

1 Department of Chemical Engineering, Binzhou University, Binzhou 256603, China;
2 Research Center of Chemical Engineering and Technology, Binzhou University, Binzhou 256603, China

收稿日期:2016-01-31 修回日期:2016-03-23 出版日期:2016-11-28 发布日期:2016-12-06
通讯作者: Changhai Li
基金资助:
Supported by the National Natural Science Foundation of China (No. 21276027) and the Higher Educational Science and Technology Program of Shandong Province, China (No.J14LC05).

Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model

Changhai Li^1,2, Dongmei Jia^1,2

1 Department of Chemical Engineering, Binzhou University, Binzhou 256603, China;
2 Research Center of Chemical Engineering and Technology, Binzhou University, Binzhou 256603, China

Received:2016-01-31 Revised:2016-03-23 Online:2016-11-28 Published:2016-12-06
Contact: Changhai Li
Supported by:
Supported by the National Natural Science Foundation of China (No. 21276027) and the Higher Educational Science and Technology Program of Shandong Province, China (No.J14LC05).

摘要/Abstract

摘要： Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid (NSA), sulfuric acid and sulfurous acid from their solution at 298K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbedmodel coupledwith the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.

关键词: 2-naphthalenesulfonic acid, Hybrid iron impregnated D301, Adsorption, Non-ideal competitive adsorbed model, Model, Equilibrium

Abstract: Commercial grade weakly basic resin D301 was impregnated with iron through a simple method using ferric chloride. Experiments for single, bisolute and trinary competitive adsorption were carried out to investigate the adsorption behavior of 2-naphthalenesulfonic acid (NSA), sulfuric acid and sulfurous acid from their solution at 298K onto the novel hybrid iron impregnated D301(Fe-D301). Adsorption affinity of NSA on Fe-D301 was found to be much higher than that of sulfuric acid, while adsorption affinity of sulfuric acid was slightly higher than that of sulfurous acid. The data of single-solute adsorption were fitted to the Langmuir model and the Freundlich adsorption model. The non-ideal competitive adsorbedmodel coupledwith the single-solute adsorption models were used to predict the bisolute and trinary-solute competitive adsorption equilibria. The NICM coupled with the Langmuir model yields the favorable representation of the bisolute and trinary-solute competitive adsorption behavior.

Key words: 2-naphthalenesulfonic acid, Hybrid iron impregnated D301, Adsorption, Non-ideal competitive adsorbed model, Model, Equilibrium

Changhai Li, Dongmei Jia. Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model[J]. Chinese Journal of Chemical Engineering, 2016, 24(11): 1522-1526.

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Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model

Adsorption of 2-naphthalenesulfonic acid/sulfuric acid/sulfurous acid from aqueous solution by iron-impregnated weakly basic resin: Equilibrium and model

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