SCI和EI收录∣中国化工学会会刊

›› 2017, Vol. 25 ›› Issue (6): 809-814.DOI: 10.1016/j.cjche.2016.09.004

• Chemical Engineering Thermodynamics • 上一篇    下一篇

Experimental determination of solubilities and supersolubilities of 2,2',4,4',6,6'-hexanitrostilbene in different organic solvents

Lizhen Chen, Liang Song, Yupeng Gao, Aipeng Zhu, Duanlin Cao   

  1. School of Chemical Engineering and Environment, North University of China, Taiyuan 030051, China
  • 收稿日期:2016-07-08 修回日期:2016-09-04 出版日期:2017-06-28 发布日期:2017-08-02
  • 通讯作者: Lizhen Chen,E-mail address:chen17555@163.com

Experimental determination of solubilities and supersolubilities of 2,2',4,4',6,6'-hexanitrostilbene in different organic solvents

Lizhen Chen, Liang Song, Yupeng Gao, Aipeng Zhu, Duanlin Cao   

  1. School of Chemical Engineering and Environment, North University of China, Taiyuan 030051, China
  • Received:2016-07-08 Revised:2016-09-04 Online:2017-06-28 Published:2017-08-02

摘要: The laser monitor technique was used to determine solubilities and supersolubilities of HNS in N,N-dimethylformamide, dimethyl sulfoxide, acetonitrile, N-methyl-2-pyrrolidone and 1,4-butyrolactone. The experimental solubility values were correlated with λh equation, modified Apelblat equation and NRTL model. Furthermore, the dissolution enthalpy, dissolution entropy and the Gibbs energy of HNS were calculated by the experimental data. The results show that the solubilities of HNS in the above solvents increase with the increasing temperature. Besides, at the same temperature, the order of solubility is N-methyl-2-pyrrolidone > dimethyl sulfoxide > N,N-dimethylformamide > 1,4-butyrolactone > acetonitrile. The temperature dependence of predicted solubility is in agreement with the experimental data.

关键词: HNS, Solubility, Liquid-solid equilibrium, Correlation, Laser monitor technique

Abstract: The laser monitor technique was used to determine solubilities and supersolubilities of HNS in N,N-dimethylformamide, dimethyl sulfoxide, acetonitrile, N-methyl-2-pyrrolidone and 1,4-butyrolactone. The experimental solubility values were correlated with λh equation, modified Apelblat equation and NRTL model. Furthermore, the dissolution enthalpy, dissolution entropy and the Gibbs energy of HNS were calculated by the experimental data. The results show that the solubilities of HNS in the above solvents increase with the increasing temperature. Besides, at the same temperature, the order of solubility is N-methyl-2-pyrrolidone > dimethyl sulfoxide > N,N-dimethylformamide > 1,4-butyrolactone > acetonitrile. The temperature dependence of predicted solubility is in agreement with the experimental data.

Key words: HNS, Solubility, Liquid-solid equilibrium, Correlation, Laser monitor technique