Ethanol steam reforming study over ZSM-5 supported cobalt versus nickel catalyst for renewable hydrogen generation

doi:10.1016/j.cjche.2018.03.036

摘要/Abstract

摘要： The renewable hydrogen generation through ethanol steam reforming is one of the anticipated areas for sustainable hydrogen generation. To elucidate the role of Ni and Co with ZSM-5 support, catalysts were prepared by wet impregnation method and ethanol steam reforming (ESR) was performed. The catalysts were characterized by HR-XRD, ATR-FTIR, HR-SEM, TEM with SAED, EDAX, surface area analyzer and TPR. It had shown complete ethanol conversion at 773 K, but the selectivity in hydrogen generation was found higher for 10% Ni/ZSM-5 catalyst as compared to 10% Co/ZSM-5. The 10% Ni/ZSM-5 catalyst has about 72% hydrogen selectivity at temperature 873 K. It indicates that Ni is a more sustainable catalyst as compared to Co with ZSM-5 support for ESR. The C₂H₄ was found major undesirable products up to 823 K temperature. Nevertheless, the 10% Ni/ZSM-5 catalyst had shown its stability for high temperature (873 K) ESR performance.

关键词: Ethanol steam reforming, Zeolite, Hydrogen, Renewable energy, Catalyst

Abstract: The renewable hydrogen generation through ethanol steam reforming is one of the anticipated areas for sustainable hydrogen generation. To elucidate the role of Ni and Co with ZSM-5 support, catalysts were prepared by wet impregnation method and ethanol steam reforming (ESR) was performed. The catalysts were characterized by HR-XRD, ATR-FTIR, HR-SEM, TEM with SAED, EDAX, surface area analyzer and TPR. It had shown complete ethanol conversion at 773 K, but the selectivity in hydrogen generation was found higher for 10% Ni/ZSM-5 catalyst as compared to 10% Co/ZSM-5. The 10% Ni/ZSM-5 catalyst has about 72% hydrogen selectivity at temperature 873 K. It indicates that Ni is a more sustainable catalyst as compared to Co with ZSM-5 support for ESR. The C₂H₄ was found major undesirable products up to 823 K temperature. Nevertheless, the 10% Ni/ZSM-5 catalyst had shown its stability for high temperature (873 K) ESR performance.

Key words: Ethanol steam reforming, Zeolite, Hydrogen, Renewable energy, Catalyst

Ashutosh Kumar, Ram Prasad, Yogesh Chandra Sharma. Ethanol steam reforming study over ZSM-5 supported cobalt versus nickel catalyst for renewable hydrogen generation[J]. 中国化学工程学报, 2019, 27(3): 677-684.

Ashutosh Kumar, Ram Prasad, Yogesh Chandra Sharma. Ethanol steam reforming study over ZSM-5 supported cobalt versus nickel catalyst for renewable hydrogen generation[J]. Chinese Journal of Chemical Engineering, 2019, 27(3): 677-684.

参考文献 47

[1]	J. Lin, L. Chen, C.K.S. Choong, Z. Zhong, L. Huang, Molecular catalysis for the steam reforming of ethanol, Sci. China Chem. 58(1) (2015) 60-78.
[2]	C. Montero, L. Oar-Arteta, A. Remiro, A. Arandia, J. Bilbao, A.G. Gayubo, Thermodynamic comparison between bio-oil and ethanol steam reforming, Int. J. Hydrogen Energy 40(46) (2015) 15963-15971.
[3]	J.F. Haw, Zeolite acid strength and reaction mechanisms in catalysis, Phys. Chem. Chem. Phys. 4(22) (2002) 5431-5441.
[4]	C. Zhang, S. Li, G. Wu, et al., Steam reforming of ethanol over skeletal Ni-based catalysts:A temperature programmed desorption and kinetic study, AICHE J. 60(2) (2014) 635-644.
[5]	A.F. Lucredio, J.D.A. Bellido, A. Zawadzki, E.M. Assaf, Co catalysts supported on SiO2 and γ-Al2O3 applied to ethanol steam reforming:Effect of the solvent used in the catalyst preparation method, Fuel 90(4) (2011) 1424-1430.
[6]	C. Wu, P.T. Williams, A novel nano-Ni/SiO2 catalyst for hydrogen production from steam reforming of ethanol, Environ. Sci. Technol. 44(15) (2010) 5993-5998.
[7]	L. Zhang, W. Li, J. Liu, C. Guo, Y. Wang, J. Zhang, Ethanol steam reforming reactions over Al2O3·SiO2-supported Ni-La catalysts, Fuel 88(3) (2009) 511-518.
[8]	E. Moretti, L. Storaro, A. Talon, S. Chitsazan, G. Garbarino, G. Busca, et al., Ceria-zirconia based catalysts for ethanol steam reforming, Fuel 153(2015) 166-175.
[9]	M.S. Scott, G.I.N. Waterhouse, K. Kato, S.L.Y. Chang, H. Idriss, T. Sohnel, Structural analysis of Rh-Pd/CeO2 catalysts under reductive conditions:An X-ray investigation, Top. Catal. 58(2-3) (2015) 123-133.
[10]	E. Varga, Z. Ferencz, A. Oszko, A. Erdohelyi, J. Kiss, Oxidation states of active catalytic centers in ethanol steam reforming reaction on ceria based Rh promoted Co catalysts:An XPS study, J. Mol. Catal. A Chem. 397(2015) 127-133.
[11]	G. Vari, L. Ovari, C. Papp, H.P. Steinruck, J. Kiss, Z. Konya, The interaction of cobalt with CeO2(111) prepared on Cu(111), J. Phys. Chem. C 119(17) (2015) 9324-9333.
[12]	S.R. Wang, W.W. Guo, L. Guo, X.B. Li, Q. Wang, Experimental and subsequent mechanism research on the steam reforming of ethanol over a Ni/CeO2 catalyst, Int. J. Green Energy 12(7) (2015) 694-701.
[13]	A.M. Karim, Y. Su, M.H. Engelhard, D.L. King, Y. Wang, Catalytic roles of Co0 and Co2+ during steam reforming of ethanol on Co/MgO catalysts, ACS Catal. 1(4) (2011) 279-286.
[14]	A. Machocki, A. Denis, W. Grzegorczyk, W. Gac, Nano-and micro-powder of zirconia and ceria-supported cobalt catalysts for the steam reforming of bio-ethanol, Appl. Surf. Sci. 256(17) (2010) 5551-5558.
[15]	B.S. Kwak, K.M. Kim, S.W. Jo, et al., Characterizations of bimetallic NiV-supported SiO2 catalysts prepared for effectively hydrogen evolutions from ethanol steam reforming, J. Ind. Eng. Chem. 37(2016) 57-66.
[16]	P.K. Sharma, N. Saxena, V.K. Bind, P.K. Roy, A. Bhatt, Steam reforming of ethanol over mesoporous Rh/CeZrO2:Mechanistic evaluation using in situ DRIFT spectroscopy, Can. J. Chem. Eng. 94(4) (2016) 752-760.
[17]	L. Huang, C. Choong, L. Chen, et al., Monometallic carbonyl-derived CeO2-supported Rh and Co bicomponent catalysts for CO-free, high-yield H2 generation from lowtemperature ethanol steam reforming, ChemCatChem 7(10) (2015) 1509.
[18]	K. Sato, K. Kawano, A. Ito, Y. Takita, K. Nagaoka, Hydrogen production from bioethanol:Oxidative steam reforming of aqueous ethanol triggered by oxidation of Ni/Ce0.5Zr0.5O2-x at low temperature, ChemSusChem 3(12) (2010) 1364-1366.
[19]	G. Busca, U. Costantino, T. Montanari, G. Ramis, C. Resini, M. Sisani, Nickel versus cobalt catalysts for hydrogen production by ethanol steam reforming:Ni-Co-Zn-Al catalysts from hydrotalcite-like precursors, Int. J. Hydrogen Energy 35(11) (2010) 5356-5366.
[20]	M. Li, X. Wang, S. Li, S. Wang, X. Ma, Hydrogen production from ethanol steam reforming over nickel based catalyst derived from Ni/Mg/Al hydrotalcite-like compounds, Int. J. Hydrogen Energy 35(13) (2010) 6699-6708.
[21]	A.F. Lucredio, J.D.A. Bellido, E.M. Assaf, Effects of adding La and Ce to hydrotalcitetype Ni/Mg/Al catalyst precursors on ethanol steam reforming reactions, Appl. Catal. A Gen. 388(1-2) (2010) 77-85.
[22]	C. Resini, T. Montanari, L. Barattini, et al., Hydrogen production by ethanol steam reforming over Ni catalysts derived from hydrotalcite-like precursors:Catalyst characterization, catalytic activity and reaction path, Appl. Catal. A Gen. 355(1-2) (2009) 83-93.
[23]	F. Aupretre, C. Descorme, D. Duprez, D. Casanave, D. Uzio, Ethanol steam reforming over MgxNi1-x Al2O3 spinel oxide-supported Rh catalysts, J. Catal. 233(2) (2005) 464-477.
[24]	M.N. Barroso, M. Gomez, L. Arrua, M.C. Abello, Reactivity of aluminum spinels in the ethanol steam reforming reaction, Catal. Lett. 109(1-2) (2006) 13-19.
[25]	S.M. de Lima, A.M. da Silva, L.O.O. da Costa, et al., Evaluation of the performance of Ni/La2O3 catalyst prepared from LaNiO3 perovskite-type oxides for the production of hydrogen through steam reforming and oxidative steam reforming of ethanol, Appl. Catal. A Gen. 377(1-2) (2010) 181-190.
[26]	L. Lang, S. Zhao, X. Yin, W. Yang, C. Wu, Catalytic activities of K-modified zeolite ZSM-5 supported rhodium catalysts in low-temperature steam reforming of bioethanol, Int. J. Hydrogen Energy 40(32) (2015) 9924-9934.
[27]	A. Vizcaino, A. Carrero, J. Calles, Hydrogen production by ethanol steam reforming over Cu-Ni supported catalysts, Int. J. Hydrogen Energy 32(10-11) (2007) 1450-1461.
[28]	F.C. Campos-Skrobot, R.C.P. Rizzo-Domingues, N.R.C. Fernandes-Machado, M.P. Cantao, Novel zeolite-supported rhodium catalysts for ethanol steam reforming, J. Power Sources 183(2) (2008) 713-716.
[29]	H. Inokawa, S. Nishimoto, Y. Kameshima, M. Miyake, Difference in the catalytic activity of transition metals and their cations loaded in zeolite Y for ethanol steam reforming, Int. J. Hydrogen Energy 35(21) (2010) 11719-11724.
[30]	H. Inokawa, S. Nishimoto, Y. Kameshima, M. Miyake, Promotion of H2 production from ethanol steam reforming by zeolite basicity, Int. J. Hydrogen Energy 36(23) (2011) 15195-15202.
[31]	B.S. Kwak, J.S. Lee, J.S. Lee, B.-H. Choi, M.J. Ji, M. Kang, Hydrogen-rich gas production from ethanol steam reforming over Ni/Ga/Mg/Zeolite Y catalysts at mild temperature, Appl. Energy 88(12) (2011) 4366-4375.
[32]	N. Wu, J. Low, T. Liu, J. Yu, S. Cao, Hierarchical hollow cages of Mn-Co layered double hydroxide as supercapacitor electrode materials, Appl. Surf. Sci. 413(2017) 35-40.
[33]	D. Kim, B.S. Kwak, B.-K. Min, M. Kang, Characterization of Ni and W co-loaded SBA-15 catalyst and its hydrogen production catalytic ability on ethanol steam reforming reaction, Appl. Surf. Sci. 332(2015) 736-746.
[34]	C.M.A. Parlett, A. Aydin, L.J. Durndell, et al., Tailored mesoporous silica supports for Ni catalysed hydrogen production from ethanol steam reforming, Catal. Commun. 91(2017) 76-79.
[35]	S. He, Z. Mei, N. Liu, et al., Ni/SBA-15 catalysts for hydrogen production by ethanol steam reforming:Effect of nickel precursor, Int. J. Hydrogen Energy 42(21) (2017) 14429-14438.
[36]	S. He, S. He, L. Zhang, et al., Hydrogen production by ethanol steam reforming over Ni/SBA-15 mesoporous catalysts:Effect of Au addition, Catal. Today 258(2015) 162-168.
[37]	A.J. Vizcaino, A. Carrero, J.A. Calles, Comparison of ethanol steam reforming using Co and Ni catalysts supported on SBA-15 modified by Ca and Mg, Fuel Process. Technol. 146(2016) 99-109.
[38]	B. Bej, N.C. Pradhan, S. Neogi, Production of hydrogen by steam reforming of methane over alumina supported nano-NiO/SiO2 catalyst, Catal. Today 207(2013) 28-35.
[39]	A. Chica, Zeolites:Promised materials for the sustainable production of hydrogen, ISRN Chem. Eng. 2013(2013) 1-19.
[40]	Y.C. Sharma, A. Kumar, R. Prasad, S.N. Upadhyay, Ethanol steam reforming for hydrogen production:Latest and effective catalyst modification strategies to minimize carbonaceous deactivation, Renew. Sust. Energ. Rev. 74(2017) 89-103.
[41]	A. Kumar, R. Prasad, Y.C. Sharma, Ethanol steam reforming with Co0(111) for hydrogen and carbon nanofilament generation, Resource-Efficient Technol. 3(4) (2017) 422-428.
[42]	X. Wang, H.-Y. Chen, W.M.H. Sachtler, Catalytic reduction of NOx by hydrocarbons over Co/ZSM-5 catalysts prepared with different methods, Appl. Catal. B Environ. 26(4) (2000) L227-L39.
[43]	A. Penkova, S. Dzwigaj, R. Kefirov, K. Hadjiivanov, M. Che, Effect of the preparation method on the state of nickel ions in BEA zeolites. A study by Fourier transform infrared spectroscopy of adsorbed CO and NO, temperature-programmed reduction, and X-ray diffraction, Phys. Chem. C 111(24) (2007) 8623-8631.
[44]	C.I. Round, C.D. Williams, K. Latham, C.V.A. Duke, Ni-ZSM-5 and Cu-ZSM-5 synthesized directly from aqueous fluoride gels, Chem. Mater. 13(2) (2001) 468-472.
[45]	S.-J. Jong, S. Cheng, Reduction behavior and catalytic properties of cobalt containing ZSM-5 zeolites, Appl. Catal. A Gen. 126(1) (1995) 51-66.
[46]	J.R. Ferraro, Low-frequency Vibrations of Inorganic and Coordination Compounds, Springer, US, 2012.
[47]	B. Zhang, X. Tang, Y. Li, Y. Xu, W. Shen, Hydrogen production from steam reforming of ethanol and glycerol over ceria-supported metal catalysts, Int. J. Hydrogen Energy 32(13) (2007) 2367-2373.