Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures

doi:10.1016/j.cjche.2018.06.014

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (12): 2573-2580.DOI: 10.1016/j.cjche.2018.06.014

• Chemical Engineering Thermodynamics • 上一篇下一篇

Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures

Youchang Wang, Shaoming Zhou, Jinhui Tang, Yun Chen, Libo Li

Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

收稿日期:2017-05-23 修回日期:2018-01-24 出版日期:2018-12-28 发布日期:2019-01-09
通讯作者: Yun Chen, Libo Li
基金资助:
Supported by the National Natural Science Foundation of China (21506066), the Guangzhou Technology Project (201804010219), the State Key Laboratory of Pulp and Paper Engineering (201708) and the Fundamental Research Funds for the Central Universities SCUT.

Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures

Youchang Wang, Shaoming Zhou, Jinhui Tang, Yun Chen, Libo Li

Key Laboratory of Heat Transfer Enhancement and Energy Conservation of Ministry of Education, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

Received:2017-05-23 Revised:2018-01-24 Online:2018-12-28 Published:2019-01-09
Contact: Yun Chen, Libo Li
Supported by:
Supported by the National Natural Science Foundation of China (21506066), the Guangzhou Technology Project (201804010219), the State Key Laboratory of Pulp and Paper Engineering (201708) and the Fundamental Research Funds for the Central Universities SCUT.

摘要/Abstract

摘要： Liquid-liquid equilibrium (LLE) data were measured for the ternary system of water+resorcinol+mesityl oxide under atmospheric pressure at temperatures of (298.2, 323.2, 333.2, 343.2 and 353.2) K. The reliability of the experimental data was verified by the Hand and Bachman equations. The distribution coefficient and selectivity were calculated from the experimental LLE data, which showed high efficiency of mesityl oxide extracting resorcinol from the aqueous solution. The NRTL and UNIQUAC models were employed to fit the measured experimental LLE data and yield corresponding binary interaction parameters.

关键词: Liquid-liquid equilibrium, Mesityl oxide, Resorcinol, NRTL, UNIQUAC

Abstract: Liquid-liquid equilibrium (LLE) data were measured for the ternary system of water+resorcinol+mesityl oxide under atmospheric pressure at temperatures of (298.2, 323.2, 333.2, 343.2 and 353.2) K. The reliability of the experimental data was verified by the Hand and Bachman equations. The distribution coefficient and selectivity were calculated from the experimental LLE data, which showed high efficiency of mesityl oxide extracting resorcinol from the aqueous solution. The NRTL and UNIQUAC models were employed to fit the measured experimental LLE data and yield corresponding binary interaction parameters.

Key words: Liquid-liquid equilibrium, Mesityl oxide, Resorcinol, NRTL, UNIQUAC

Youchang Wang, Shaoming Zhou, Jinhui Tang, Yun Chen, Libo Li. Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2573-2580.

参考文献

[1] L.G.C. Villegas, N. Mashhadi, M. Chen, D. Mukherjee, K.E. Taylor, N. Biswas, A short review of techniques for phenol removal from wastewater, Current Pollution Reports 2016, pp. 1-11.

[2] S. Mohammadi, A. Kargari, H. Sanaeepur, K. Abbassian, A. Najafi, E. Mofarrah, Phenol removal from industrial wastewaters:A short review, Desalin. Water Treat. 53(8) (2015) 2215-2234.

[3] H. Jiang, Y. Fang, Y. Fu, Q. Guo, Studies on the extraction of phenol in wastewater, J. Hazard. Mater. 101(2003) 179-190.

[4] Y. Chen, R. Lv, H. Wang, M. Liao, L. Li, Ternary liquid-liquid equilibria for methyl isopropyl ketone+(resorcinol or hydroquinone)+water systems at different temperatures, Fluid Phase Equilib. 429(2016) 93-97.

[5] Y. Chen, H. Wang, R. Lv, L. Li, Liquid-liquid equilibrium for ternary systems, methyl isobutyl ketone+(catechol, resorcinol and hydroquinone)+water at 333.15 K, 343.15 K and 353.15 K, Fluid Phase Equilib. 433(2017) 206-211.

[6] P. Singer, F. Pfaender, J. Chinchilli, A. Maciorowski, J. Lamb Ⅲ, Assessment of Coal Conversion Wastewaters:Characterization and Preliminary Biotreatability. Report for November 1976-May 1978; North Carolina Univ., Chapel Hill (USA), Dept. of Environmental Sciences and Engineering, 1978.

[7] D.C. Greminger, Solvent Extraction of Phenols from Water[C]//American Institute of Chemical Engineering Conference, Philadelphia, PA, June 8-12, 1980, 2012.

[8] H. Dressler, Resorcinol:Its Uses and Derivatives, Springer Science & Business Media, 2013.

[9] C. Wang, J. Dai, M. Qi, Study on the liquid equilibrium of resorcinol solvent extraction, J. Shanghai Chem. Eng. 28(6) (2003) 23-25.

[10] R.T.P. Pinto, L. Lintomen, L.F.L. Luz, M.R. Wolf-Maciel, Strategies for recovering phenol from wastewater:thermodynamic evaluation and environmental concerns, Fluid Phase Equilib. 228(3) (2005) 447-457.

[11] Y. Chen, R. Lv, L. Li, et al., Measurement and thermodynamic modeling of ternary (liquid+liquid) equilibrium for extraction of o-cresol, m-cresol or p-cresol from aqueous solution with 2-pentanone, J. Chem. Thermodyn. 104(2017) 230-238.

[12] Y. Chen, R. Lv, F. Wang, L. Li, Determination and modeling of liquid-liquid equilibrium for ternary mixtures of methyl isopropyl ketone, cresol isomers and water, Fluid Phase Equilib. 429(2016) 107-112.

[13] R. Lv, Z. Wang, L. Li, Y. Chen, Liquid-liquid equilibria in the ternary systems water+cresols+methyl butyl ketone at 298.2 and 313.2 K:Experimental data and correlation, Fluid Phase Equilib. 404(2015) 89-95.

[14] Y. Chen, Y. Wang, S. Zhou, et al., Liquid phase equilibrium of the ternary systems, water+propionic or butyric acid+mesityl oxide, at (298.2 and 323.2) K, J. Chem. Thermodyn. 111(2017) 72-79.

[15] H. Wang, L. Li, R. Lv, Y. Chen, Measurement and correlation of liquid-liquid equilibria for the ternary methyl isobutyl ketone+phenol+water system at (333.15, 343.15 and 353.15) K under atmospheric pressure, J. Solut. Chem. (2016) 1-10.

[16] C.X. Duan, F. Li, S.J. Luo, J. Xiao, L.B. Li, H.X. Xi, Facile synthesis of hierarchical porous metal-organic frameworks with enhanced catalytic activity, Chem. Eng. J. 334(2018) 1477-1483.

[17] D. Liu, L. Li, R. Lv, Y. Chen, Liquid-liquid equilibria for the ternary system mesityl oxide+phenol+water at 298.15, 313.15, and 323.15 K, J. Chem. Eng. Data 61(7) (2016) 2493-2498.

[18] S. Zhou, L. Li, Y. Wang, et al., Measurement, correlation and COSMO-SAC prediction of liquid-liquid equilibrium for the ternary systems, mesityl oxide+o-, m-, p-cresol+water, at 333.2 K and 353.2 K, Fluid Phase Equilib. 440(2017) 45-53.

[19] H. Renon, J.M. Prausnitz, Local compositions in thermodynamic excess functions for liquid mixtures, AICHE J. 14(1968) 135-144.

[20] D.S. Abrams, J.M. Prausnitz, Statistical thermodynamics of liquid mixtures:A new expression for the excess Gibbs energy of partly or completely miscible systems, AICHE J. 21(1975) 116-128.

[21] Y. Chen, H. Wang, R. Lv, et al., Liquid-liquid equilibria for methyl isobutyl ketone+cresols+water at 333.15 K, 343.15 K and 353.15 K:Experimental results and data correlation, Fluid Phase Equilib. 427(2016) 291-296.

[22] D.C. Greminge, G.P. Burns, S. Lynn, D.N. Hanson, C.J. King, Solvent extraction of phenols from water, Ind. Eng. Chem. Process. Des. Dev. 21(1982) 51-54.

[23] J. Alvarez Gonzalez, E. Macedo, M. Soares, A. Medina, Liquid-liquid equilibria for ternary systems of water-phenol and solvents:Data and representation with models, Fluid Phase Equilib. 26(1986) 289-302.

[24] L. de Oliveira, M. Aznar, (Liquid+liquid) equilibrium of {water+phenol+(1-butanol, or 2-butanol, or tert-butanol)} systems, J. Chem. Thermodyn. 42(2010) 1379-1385.

[25] H. Ju, Y. Xu, H. Zhu, P. Zhou, M. Qian, X. Ye, Research on liquid-liquid equilibrium of water-isopropyl ether-phenol and water-isobutanol-phenol systems, J. Chem. Eng. Chin. Univ. 23(2009) 12-17.

[26] H. Ghanadzadeh Gilani, A. Ghanadzadeh Gilani, M. Sangashekan, Tie-line data for the aqueous solutions of phenol with organic solvents at T=298.2 K, J. Chem. Thermodyn. 58(2013) 142-148.

[27] Y. Chen, S. Zhou, Y. Wang, Screening solvents to extract phenol from aqueous solutions by the COSMO-SAC model and extraction process simulation, Fluid Phase Equilib. 451(2017) 12-24.

[28] D. Hand, Dineric distribution, J. Phys. Chem. 34(1929) 1961-2000.

[29] I. Bachman, Tie lines in ternary liquid systems, Ind. Eng. Chem. Anal. Ed. 12(1940) 38-39.

[30] Y. Chen, K.N. Xiong, S.M. Zhou, H.M. Wang, L.B. Li, Liquid-Liquid Equilibrium of Ternary Systems of Methyl Isobutyl Ketone plus o-Cresol+Water at 298.2, 313.2 and 323.2 K, J. Solution Chem. 46(2017) 2204-2213.

[31] M.R. Mafra, M.A. Krahenbuhl, Liquid-liquid equilibrium of (water+acetone) with cumene or α-methylstyrene or phenol at temperatures of (323.15 and 333.15) K, J. Chem. Eng. Data 51(2) (2006) 753-756.

[32] T. Magnussen, P. Rasmussen, A. Fredenslund, UNIFAC parameter table for prediction of liquid-liquid equilibriums, Ind. Eng. Chem. Process. Des. Dev. 20(2) (1981) 331-339.

[33] A.S. Aljimaz, M.S. Fandary, J.A. Alkandary, M.A. Fahim, Liquid-liquid equilibria of the ternary system water+acetic acid+1-heptanol, J. Chem. Eng. Data 45(2) (2000) 301-303.

Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures

Measurement and correlation of phase equilibrium data of the mixtures consisting of water, resorcinol, mesityl oxide at different temperatures

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Zhansheng Li, Jiayu Song, Shouhai Zhang, Jinyan Wang, Xigao Jian. Measurement and correlation of liquid-liquid equilibrium for the ternary system (water + 1,2-dichloroethane + sulfolane) at 288.15, 298.15, and 308.15 K[J]. 中国化学工程学报, 2022, 51(11): 109-114.
[2]	Lianzheng Zhang, Jie Wang, Lin Yang, Dongmei Xu, Yixin Ma, Jun Gao, Yinglong Wang. Separation of isopropyl alcohol + isopropyl acetate azeotropic mixture: Selection of ionic liquids as entrainers and vapor-liquid equilibrium validation[J]. 中国化学工程学报, 2022, 50(10): 326-334.
[3]	Yonglin Li, He'an Luo, Qiuhong Ai, Kuiyi You, Fei Zhao, Wenlong Xiao. Efficient separation of phenols from coal tar with aqueous solution of amines by liquid-liquid extraction[J]. 中国化学工程学报, 2021, 35(7): 180-188.
[4]	Huichao Lv, Dayong Tian. Designing and optimizing a parallel neural network model for predicting the solubility of diosgenin in n-alkanols[J]. 中国化学工程学报, 2021, 29(1): 288-294.
[5]	Yonghui Dou, Huanxin Li, Xiaoqiang Gao, Guoji Liu, Li Xu. Investigation of liquid-liquid equilibrium of the ternary system (water+1,6-diaminohexane+2-methyl-1-propanol or 3-methyl-1-butanol) at different temperatures[J]. 中国化学工程学报, 2020, 28(1): 191-197.
[6]	Mohammad Barzegar-Jalali, Abolghasem Jouyban, Fleming Martinez, Hemayat Shekaari, Seyyedeh Narjes Mirheydari. Solubility and thermodynamics of lamotrigine in ternary mixtures of ionic liquids ([OMIm][Br]+[HMIm][Br]+water) at different temperatures[J]. 中国化学工程学报, 2020, 28(1): 198-207.
[7]	Kangning Xiong, Shuai Shen, Youchang Wang, Yun Chen. Measurements and correlation of liquid-liquid equilibrium data for the ternary (methyl tert-butyl ketone + o, m, p-benzenediol + water) system at (333.2, 343.2 and 353.2) K[J]. 中国化学工程学报, 2019, 27(4): 905-911.
[8]	Dewi Selvia Fardhyanti, Bayu Triwibowo, Heri Istanto, Muhammad Khusni Anajib, Amalia Larasati, Windy Oktaviani. Liquid phase equilibrium of phenol extraction from bio-oil produced by biomass pyrolysis using thermodynamic models[J]. Chinese Journal of Chemical Engineering, 2019, 27(2): 391-399.
[9]	Yun Chen, Kangning Xiong, Shuai Shen, Huimin Wang, Shaoming Zhou, Libo Li. Salt effect on the liquid-liquid equilibrium of the ternary (water + phenol + methyl isobutyl ketone) system: Experimental data and correlation[J]. Chinese Journal of Chemical Engineering, 2019, 27(1): 168-173.
[10]	Hui Jia, Huixin Wang, Kang Ma, Mengxiao Yu, Zhaoyou Zhu, Yinglong Wang. Effect of thermodynamic parameters on prediction of phase behavior and process design of extractive distillation[J]. Chinese Journal of Chemical Engineering, 2018, 26(5): 993-1002.
[11]	Zuojun Wei, Haiyan Liu, Yidong Chen, Dechao Guo, Ruofei Pan, Yingxin Liu. Mechanistic insights into the selective hydrogenation of resorcinol to 1,3-cyclohexanedione over Pd/rGO catalyst through DFT calculation[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2542-2548.
[12]	Fatemeh Ahmadi, Mohsen Pirdashti, Abbas Ali Rostami. Density, refractive index and liquid-liquid equilibrium data of polyethylene glycol 3000 + potassium formate + water at different pH values[J]. Chinese Journal of Chemical Engineering, 2018, 26(1): 168-174.
[13]	Yuqian Li, LiguoWang, Peng He, Kelin Huang, Huiquan Li, Yan Cao. Isobaric vapor-liquid equilibrium for binary system of aniline+methyl-N-phenyl carbamate[J]. Chinese Journal of Chemical Engineering, 2016, 24(10): 1470-1476.
[14]	王训遒, 庄新亮, 蒋登高. Measurement and Correlation of Vapor-Liquid Equilibrium of the 1,2-Epoxycyclohexane-Cyclohexanone Binary System at 101.3 kPa[J]. Chinese Journal of Chemical Engineering, 2014, 22(3): 355-359.
[15]	邓东顺, 乔玉珍, 姬登祥, 葛筠, 章连众. Measurement and Modeling of Vapor-Liquid Equilibrium for Ternary System Water + 2-Propanol + 1-Butyl-3-methylimidazolium Chloride[J]. Chinese Journal of Chemical Engineering, 2014, 22(2): 164-169.