Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature

doi:10.1016/j.cjche.2018.09.006

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (5): 1200-1206.DOI: 10.1016/j.cjche.2018.09.006

• Energy, Resources and Environmental Technology • 上一篇下一篇

Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature

Chengli Wu, Beibei Wang, Jiuqiang Zheng, Hanxu Li

School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China

收稿日期:2018-06-28 修回日期:2018-08-15 出版日期:2019-05-28 发布日期:2019-06-27
通讯作者: Chengli Wu
基金资助:
Supported partially by the Major Science and Technology Special Projects Foundation of Anhui Province (15czz02045), the Natural Science Foundation of Anhui Province (1508085MB41) and the China Postdoctoral Science Foundation (2015M571915).

Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature

Chengli Wu, Beibei Wang, Jiuqiang Zheng, Hanxu Li

School of Chemical Engineering, Anhui University of Science and Technology, Huainan 232001, China

Received:2018-06-28 Revised:2018-08-15 Online:2019-05-28 Published:2019-06-27
Contact: Chengli Wu
Supported by:
Supported partially by the Major Science and Technology Special Projects Foundation of Anhui Province (15czz02045), the Natural Science Foundation of Anhui Province (1508085MB41) and the China Postdoctoral Science Foundation (2015M571915).

摘要/Abstract

摘要： The melting temperature of Z coal ash was reduced by adding calcium-magnesium compound flux (W_CaO/W_MgO=1). In the process of simulated coal gasification, the coal ash and slag were prepared. The transformation of minerals in coal ash and slag upon the change of temperature was studied by using X-ray diffraction (XRD). With the increase of temperatures, forsterite in the ash disappears, while the diffraction peak strength of magnesium spinel increases, and the content of the calcium feldspar increases, then the content of the amorphous phase in the ash increases obviously. The species and evolution process of oxygen, silicon, aluminum, calcium, magnesium at different temperatures were analyzed by X-ray photoelectron spectroscopy (XPS). The decrease of the ash melting point mainly affects the structural changes of silicon, aluminum and oxygen. The coordination of aluminum and oxygen in the aluminum element structure, e.g., tetracoordinated aluminum oxide, was changed. Tetrahedral[AlO₄] and hexacoordinated aluminoxy octahedral[AlO₆] change with the temperature changing. The addition of Ca²⁺ and Mg²⁺ destroys silica chain, making bridge oxide silicon change into non-bridge oxysilicon; and bridge oxygen bond was broken and non-bridge oxygen bond was produced in the oxygen element structure. The addition of calcium and magnesium compound flux reacts with aluminum oxide tetrahedron, aluminum oxide octahedron and silicon tetrahedron to promote the breakage of the bridge oxygen bond. Ca²⁺ and Mg²⁺ are easily combined with silicon oxide and aluminum oxide tetrahedron and aluminum. Oxygen octahedrons combine with non-oxygen bonds to generate low-melting temperature feldspars and magnesite minerals, thereby reducing the coal ash melting temperatures. The structure of kaolinite and mullite was simulated by quantum chemistry calculation, and kaolinite molecule has a stable structure.

关键词: Coal ash and slag, Compound flux, X-ray photoelectron spectroscopy, Transformation of mineral structure, Structure of kaolinite and mullite

Abstract: The melting temperature of Z coal ash was reduced by adding calcium-magnesium compound flux (W_CaO/W_MgO=1). In the process of simulated coal gasification, the coal ash and slag were prepared. The transformation of minerals in coal ash and slag upon the change of temperature was studied by using X-ray diffraction (XRD). With the increase of temperatures, forsterite in the ash disappears, while the diffraction peak strength of magnesium spinel increases, and the content of the calcium feldspar increases, then the content of the amorphous phase in the ash increases obviously. The species and evolution process of oxygen, silicon, aluminum, calcium, magnesium at different temperatures were analyzed by X-ray photoelectron spectroscopy (XPS). The decrease of the ash melting point mainly affects the structural changes of silicon, aluminum and oxygen. The coordination of aluminum and oxygen in the aluminum element structure, e.g., tetracoordinated aluminum oxide, was changed. Tetrahedral[AlO₄] and hexacoordinated aluminoxy octahedral[AlO₆] change with the temperature changing. The addition of Ca²⁺ and Mg²⁺ destroys silica chain, making bridge oxide silicon change into non-bridge oxysilicon; and bridge oxygen bond was broken and non-bridge oxygen bond was produced in the oxygen element structure. The addition of calcium and magnesium compound flux reacts with aluminum oxide tetrahedron, aluminum oxide octahedron and silicon tetrahedron to promote the breakage of the bridge oxygen bond. Ca²⁺ and Mg²⁺ are easily combined with silicon oxide and aluminum oxide tetrahedron and aluminum. Oxygen octahedrons combine with non-oxygen bonds to generate low-melting temperature feldspars and magnesite minerals, thereby reducing the coal ash melting temperatures. The structure of kaolinite and mullite was simulated by quantum chemistry calculation, and kaolinite molecule has a stable structure.

Key words: Coal ash and slag, Compound flux, X-ray photoelectron spectroscopy, Transformation of mineral structure, Structure of kaolinite and mullite

Chengli Wu, Beibei Wang, Jiuqiang Zheng, Hanxu Li. Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature[J]. 中国化学工程学报, 2019, 27(5): 1200-1206.

Chengli Wu, Beibei Wang, Jiuqiang Zheng, Hanxu Li. Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature[J]. Chinese Journal of Chemical Engineering, 2019, 27(5): 1200-1206.

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Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature

Flux mechanism of compound flux on ash and slag of coal with high ash melting temperature

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