SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (12): 2900-2908.DOI: 10.1016/j.cjche.2018.09.017

• Separation Science and Engineering • 上一篇    下一篇

Thermal degradation of diethanolamine at stripper condition for CO2 capture: Product types and reaction mechanisms

Idris Mohamed Saeed1, Brahim Si Ali2, Badrul Mohamed Jan2, Wan Jefrey Basirun1, Shaukat Ali Mazari3, Ibrahim Ali Obid Birima1   

  1. 1 Department of Chemistry, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia;
    2 Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia;
    3 Department of Chemical Engineering, Faculty of Engineering, Dawood University of Engineering and Technology, MA Jinnah Road, Karachi 74800, Pakistan
  • 收稿日期:2018-01-15 修回日期:2018-08-25 出版日期:2019-12-28 发布日期:2020-03-17
  • 通讯作者: Idris Mohamed Saeed, Badrul Mohamed Jan
  • 基金资助:
    Supported by the University of Malaya Research Grant (RP038C15HTM, RP020C-14AFR, RP031B-15AFR, IPPP (PG209-2014B)) and the High Impact Research Grant of the University of Malaya (UM.C/625/1/HIR/123).

Thermal degradation of diethanolamine at stripper condition for CO2 capture: Product types and reaction mechanisms

Idris Mohamed Saeed1, Brahim Si Ali2, Badrul Mohamed Jan2, Wan Jefrey Basirun1, Shaukat Ali Mazari3, Ibrahim Ali Obid Birima1   

  1. 1 Department of Chemistry, Faculty of Science, University of Malaya, Kuala Lumpur 50603, Malaysia;
    2 Department of Chemical Engineering, Faculty of Engineering, University of Malaya, Kuala Lumpur 50603, Malaysia;
    3 Department of Chemical Engineering, Faculty of Engineering, Dawood University of Engineering and Technology, MA Jinnah Road, Karachi 74800, Pakistan
  • Received:2018-01-15 Revised:2018-08-25 Online:2019-12-28 Published:2020-03-17
  • Contact: Idris Mohamed Saeed, Badrul Mohamed Jan
  • Supported by:
    Supported by the University of Malaya Research Grant (RP038C15HTM, RP020C-14AFR, RP031B-15AFR, IPPP (PG209-2014B)) and the High Impact Research Grant of the University of Malaya (UM.C/625/1/HIR/123).

摘要: Amine-based absorption/stripping is one of the promising technology for CO2 capture from natural and industrial gas streams. During the process, amines and CO2 undergo irreversible reactions to produce undesired compounds, which cause corrosion, foaming, increased viscosity and breakdown of equipment, ultimately contributing to the economic loss and environmental pollution. In this study, the thermal degradation of aqueous diethanolamine in the presence and absence of dissolved CO2 was investigated. The experiments were performed in stainless steel cylinders. The results show that thermal degradation in the absence of CO2 was a slow process; triethanolamine, and tris(2-aminoethyl)amine were only the degradation products identified in the mixture In addition, the rate of degradation was very low, only 3% degradation was observed after 4 weeks. But in the presence of CO2, sixteen degradation products were identified, nine of which were new degradation products reported for the first time in this study. The 3-(2-hydroxyethyl)-2-oxazolidinone, 1,4-bis(2-hydroxyethyl) piperazine and triethanolamine were the most abundant degradation products. The remaining DEA concentration after 4 weeks was about 20% of the total amine concentration. The most probable degradation reactions and their mechanisms are also proposed.

关键词: Diethanolamine, CO2 capture, Degradation, Mechanism

Abstract: Amine-based absorption/stripping is one of the promising technology for CO2 capture from natural and industrial gas streams. During the process, amines and CO2 undergo irreversible reactions to produce undesired compounds, which cause corrosion, foaming, increased viscosity and breakdown of equipment, ultimately contributing to the economic loss and environmental pollution. In this study, the thermal degradation of aqueous diethanolamine in the presence and absence of dissolved CO2 was investigated. The experiments were performed in stainless steel cylinders. The results show that thermal degradation in the absence of CO2 was a slow process; triethanolamine, and tris(2-aminoethyl)amine were only the degradation products identified in the mixture In addition, the rate of degradation was very low, only 3% degradation was observed after 4 weeks. But in the presence of CO2, sixteen degradation products were identified, nine of which were new degradation products reported for the first time in this study. The 3-(2-hydroxyethyl)-2-oxazolidinone, 1,4-bis(2-hydroxyethyl) piperazine and triethanolamine were the most abundant degradation products. The remaining DEA concentration after 4 weeks was about 20% of the total amine concentration. The most probable degradation reactions and their mechanisms are also proposed.

Key words: Diethanolamine, CO2 capture, Degradation, Mechanism