Composite bilayer films with organic compound-triggered bending properties

doi:10.1016/j.cjche.2018.11.018

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (10): 2587-2595.DOI: 10.1016/j.cjche.2018.11.018

• Materials and Product Engineering • 上一篇下一篇

Composite bilayer films with organic compound-triggered bending properties

Ke Deng¹, Zhuang Liu^1,2, Jiaqi Hu¹, Wenying Liu¹, Lei Zhang¹, Rui Xie^1,2, Xiaojie Ju^1,2, Wei Wang^1,2, Liangyin Chu^1,2

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

收稿日期:2018-09-27 修回日期:2018-11-21 出版日期:2019-10-28 发布日期:2020-01-17
通讯作者: Zhuang Liu, Liangyin Chu
基金资助:
Supported by the National Natural Science Foundation of China (21490582, 21622604), the Program for Changjiang Scholars and Innovative Research Team in University (IRT15R48) and the State Key Laboratory of Polymer Materials Engineering (sklpme2017-3-03, sklpme2014-1-01).

Composite bilayer films with organic compound-triggered bending properties

Ke Deng¹, Zhuang Liu^1,2, Jiaqi Hu¹, Wenying Liu¹, Lei Zhang¹, Rui Xie^1,2, Xiaojie Ju^1,2, Wei Wang^1,2, Liangyin Chu^1,2

1 School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2 State Key Laboratory of Polymer Materials Engineering, Sichuan University, Chengdu 610065, China

Received:2018-09-27 Revised:2018-11-21 Online:2019-10-28 Published:2020-01-17
Contact: Zhuang Liu, Liangyin Chu
Supported by:
Supported by the National Natural Science Foundation of China (21490582, 21622604), the Program for Changjiang Scholars and Innovative Research Team in University (IRT15R48) and the State Key Laboratory of Polymer Materials Engineering (sklpme2017-3-03, sklpme2014-1-01).

摘要/Abstract

摘要： Organic compounds are widely used in both industry and daily life, and composite bilayer films with organic compound-triggered bending properties are promising for applications of transducers, soft robotics, and so on. Here, a universal and straightforward strategy to generate composite bilayer films with organic compoundtriggered bending properties is demonstrated. The composite bilayer films with organic compound-triggered bending properties are designed with bilayer structures, in which one layer is a porous polymeric membrane with appropriate solubility parameter that matches the value of organic solvents in order to produce prominent affinity to the solvent molecules, and the other layer is reduced graphene oxide membrane stacked on the porous polymeric membrane as an inert layer for restraining the swelling of the polymeric membrane on one side. Guided by matching the solubility parameters between solvent and polymer, a significant bending curvature of 27.3 cm^-1 is obtained in acetone vapor. The results in this study will provide valuable guidance for designing and developing functional composite materials with significant organic compound-triggered bending properties.

关键词: Responsive materials, Composite bilayer films, Organic compound-triggered bending, Graphene, Porous polymeric membranes

Abstract: Organic compounds are widely used in both industry and daily life, and composite bilayer films with organic compound-triggered bending properties are promising for applications of transducers, soft robotics, and so on. Here, a universal and straightforward strategy to generate composite bilayer films with organic compoundtriggered bending properties is demonstrated. The composite bilayer films with organic compound-triggered bending properties are designed with bilayer structures, in which one layer is a porous polymeric membrane with appropriate solubility parameter that matches the value of organic solvents in order to produce prominent affinity to the solvent molecules, and the other layer is reduced graphene oxide membrane stacked on the porous polymeric membrane as an inert layer for restraining the swelling of the polymeric membrane on one side. Guided by matching the solubility parameters between solvent and polymer, a significant bending curvature of 27.3 cm^-1 is obtained in acetone vapor. The results in this study will provide valuable guidance for designing and developing functional composite materials with significant organic compound-triggered bending properties.

Key words: Responsive materials, Composite bilayer films, Organic compound-triggered bending, Graphene, Porous polymeric membranes

Ke Deng, Zhuang Liu, Jiaqi Hu, Wenying Liu, Lei Zhang, Rui Xie, Xiaojie Ju, Wei Wang, Liangyin Chu. Composite bilayer films with organic compound-triggered bending properties[J]. 中国化学工程学报, 2019, 27(10): 2587-2595.

参考文献

[1] M. Kondo, Y. Yu, T. Ikeda, How does the initial alignment of mesogens affect the photoinduced bending behavior of liquid-crystalline elastomers, Angew. Chem. 45(9) (2006) 1378-1382.
[2] S. Taccola, F. Greco, E. Sinibaldi, A. Mondini, B. Mazzolai, V. Mattoli, Toward a new generation of electrically controllable hygromorphic soft actuators, Adv. Mater. 27(10) (2015) 1668-1675.
[3] J. Gong, H. Lin, J.W. Dunlop, J. Yuan, Hierarchically arranged helical fiber actuators derived from commercial cloth, Adv. Mater. 29(16) (2017), 1605103.
[4] P. Chen, Y. Xu, S. He, X. Sun, S. Pan, J. Deng, D. Chen, H. Peng, Hierarchically arranged helical fibre actuators driven by solvents and vapours, Nat. Nanotechnol. 10(12) (2015) 1077-1083.
[5] J. Mu, C. Hou, H. Wang, Y. Li, Q. Zhang, M. Zhu, Origami-inspired active graphenebased paper for programmable instant self-folding walking devices, Sci. Adv. 1(10) (2015), e1500533.
[6] Q. Zhao, J. Heyda, J. Dzubiella, K. Täuber, J.W. Dunlop, J. Yuan, Sensing solvents with ultrasensitive porous poly (ionic liquid) actuators, Adv. Mater. 27(18) (2015) 2913-2917.
[7] A. Buguin, M.-H. Li, P. Silberzan, B. Ladoux, P. Keller, Micro-actuators:When artificial muscles made of nematic liquid crystal elastomers meet soft lithography, J. Am. Chem. Soc. 128(4) (2006) 1088-1089.
[8] T. Mirfakhrai, J.D. Madden, R.H. Baughman, Polymer artificial muscles, Mater. Today 10(4) (2007) 30-38.
[9] S.M. Mirvakili, I.W. Hunter, Multidirectional artificial muscles from nylon, Adv. Mater. 29(4) (2017), 1604734.
[10] S.M. Mirvakili, I.W. Hunter, Artificial muscles:Mechanisms, applications, and challenges, Adv. Mater. 30(6) (2018), 1704407.
[11] F. Ilievski, A.D. Mazzeo, R.F. Shepherd, X. Chen, G.M. Whitesides, Soft robotics for chemists, Angew. Chem. 123(8) (2011) 1930-1935.
[12] D. Rus, M.T. Tolley, Design, fabrication and control of soft robots, Nature 521(7553) (2015) 467-475.
[13] R.F. Shepherd, F. Ilievski, W. Choi, S.A. Morin, A.A. Stokes, A.D. Mazzeo, X. Chen, M. Wang, G.M. Whitesides, Multigait soft robot, Proc. Natl. Acad. Sci. 108(51) (2011) 20400-20403.
[14] M.D. Manrique-Juárez, F. Mathieu, A. Laborde, S. Rat, V. Shalabaeva, P. Demont, O. Thomas, L. Salmon, T. Leichle, L. Nicu, Micromachining-compatible, facile fabrication of polymer nanocomposite spin crossover actuators, Adv. Funct. Mater. 28(29) (2018), 1801970.
[15] H. Kim, H. Lee, I. Ha, J. Jung, P. Won, H. Cho, J. Yeo, S. Hong, S. Han, J. Kwon, Biomimetic color changing anisotropic soft actuators with integrated metal nanowire percolation network transparent heaters for soft robotics, Adv. Funct. Mater. 28(32) (2018) 1801847.
[16] Y.C. Lai, J. Deng, R. Liu, Y.C. Hsiao, S.L. Zhang, W. Peng, H.M. Wu, X. Wang, Z.L. Wang, Actively perceiving and responsive soft robots enabled by self-powered, highly extensible, and highly sensitive triboelectric proximity- and pressure-sensing skins, Adv. Mater. 30(28) (2018), 1801114.
[17] M. Ma, L. Guo, D.G. Anderson, R. Langer, Bio-inspired polymer composite actuator and generator driven by water gradients, Science 339(6116) (2013) 186-189.
[18] L. Zhang, S. Chizhik, Y. Wen, P. Naumov, Directed motility of hygroresponsive biomimetic actuators, Adv. Funct. Mater. 26(7) (2016) 1040-1053.
[19] J. Mu, C. Hou, B. Zhu, H. Wang, Y. Li, Q. Zhang, A multi-responsive water-driven actuator with instant and powerful performance for versatile applications, Sci. Rep. 5(1) (2015) 9503.
[20] Z. Hu, X. Zhang, Y. Li, Synthesis and application of modulated polymer gels, Science 269(5223) (1995) 525-527.
[21] F. Ilmain, T. Tanaka, E. Kokufuta, Volume transition in a gel driven by hydrogen bonding, Nature 349(6308) (1991) 400-401.
[22] S. Juodkazis, N. Mukai, R. Wakaki, A. Yamaguchi, S. Matsuo, H. Misawa, Reversible phase transitions in polymer gels induced by radiation forces, Nature 408(6809) (2000) 178-181.
[23] C. Yao, Z. Liu, C. Yang, W. Wang, X.J. Ju, R. Xie, L.Y. Chu, Poly (N-isopropylacrylamide)-clay nanocomposite hydrogels with responsive bending property as temperaturecontrolled manipulators, Adv. Funct. Mater. 25(20) (2015) 2980-2991.
[24] L. Zhang, Z. Liu, L.Y. Liu, J.L. Pan, F. Luo, C. Yang, R. Xie, X.J. Ju, W. Wang, L.Y. Chu, Nanostructured thermo-responsive surfaces engineered via stable immobilization of smart nanogels with assistance of polydopamine, ACS Appl. Mater. Interfaces (2018) https://doi.org/10.1021/acsami.8b20395.
[25] B.P. Lee, S. Konst, Novel hydrogel actuator inspired by reversible mussel adhesive protein chemistry, Adv. Mater. 26(21) (2014) 3415-3419.
[26] K. Lee, S.A. Asher, Photonic crystal chemical sensors:pH and ionic strength, J. Am. Chem. Soc. 122(39) (2000) 9534-9537.
[27] C. Ma, T. Li, Q. Zhao, X. Yang, J. Wu, Y. Luo, T. Xie, Supramolecular lego assembly towards three-dimensional multi-responsive hydrogels, Adv. Mater. 26(32) (2014) 5665-5669.
[28] T.S. Shim, S.H. Kim, C.J. Heo, H.C. Jeon, S.M. Yang, Controlled origami folding of hydrogel bilayers with sustained reversibility for robust microcarriers, Angew. Chem. 51(6) (2012) 1420-1423.
[29] Y. Tai, G. Lubineau, Z. Yang, Light-activated rapid-response polyvinylidene-fluoridebased flexible films, Adv. Mater. 28(23) (2016) 4665-4670.
[30] Y. Hu, J. Liu, L. Chang, L. Yang, A. Xu, K. Qi, P. Lu, G. Wu, W. Chen, Y. Wu, Electrically and sunlight-driven actuator with versatile biomimetic motions based on rolled carbon nanotube bilayer composite, Adv. Funct. Mater. 27(44) (2017) 1703083.
[31] Y. Hu, G. Wu, T. Lan, J. Zhao, Y. Liu, W. Chen, A graphene-based bimorph structure for design of high performance photoactuators, Adv. Mater. 27(47) (2015) 7867-7873.
[32] K. Kwan, S. Li, N. Hau, W.-D. Li, S. Feng, A.H. Ngan, Light-stimulated actuators based on nickel hydroxide-oxyhydroxide, Sci. Robot. 3(18) (2018), eaat4051.
[33] K. Kajiwara, S.B. Ross-Murphy, Synthetic gels on the move, Nature 355(6357) (1992) 208-209.
[34] B. Xue, M. Qin, T. Wang, J. Wu, D. Luo, Q. Jiang, Y. Li, Y. Cao, W. Wang, Electrically controllable actuators based on supramolecular peptide hydrogels, Adv. Funct. Mater. 26(48) (2016) 9053-9062.
[35] C. Keplinger, J.-Y. Sun, C.C. Foo, P. Rothemund, G.M. Whitesides, Z. Suo, Stretchable, transparent, ionic conductors, Science 341(6149) (2013) 984-987.
[36] L. Kong, W. Chen, Carbon nanotube and graphene-based bioinspired electrochemical actuators, Adv. Mater. 26(7) (2014) 1025-1043.
[37] G. Wu, Y. Hu, Y. Liu, J. Zhao, X. Chen, V. Whoehling, C. Plesse, G.T. Nguyen, F. Vidal, W. Chen, Graphitic carbon nitride nanosheet electrode-based high-performance ionic actuator, Nat. Commun. 6(2015) 7258.
[38] M.R. Islam, X. Li, K. Smyth, M.J. Serpe, Polymer-based muscle expansion and contraction, Angew. Chem. 52(39) (2013) 10330-10333.
[39] H. Cheng, J. Liu, Y. Zhao, C. Hu, Z. Zhang, N. Chen, L. Jiang, L. Qu, Graphene fibers with predetermined deformation as moisture-triggered actuators and robots, Angew. Chem. 52(40) (2013) 10482-10486.
[40] D.D. Han, Y.L. Zhang, H.B. Jiang, H. Xia, J. Feng, Q.D. Chen, H.L. Xu, H.B. Sun, Moistureresponsive graphene paper prepared by self-controlled photoreduction, Adv. Mater. 27(2) (2015) 332-338.
[41] S. Zeng, R. Li, S.G. Freire, V.M. Garbellotto, E.Y. Huang, A.T. Smith, C. Hu, W.R. Tait, Z. Bian, G. Zheng, Moisture-responsive wrinkling surfaces with tunable dynamics, Adv. Mater. 29(24) (2017), 1700828.
[42] L. Wang, M.Y. Razzaq, T. Rudolph, M. Heuchel, U. Nöchel, U. Mansfeld, Y. Jiang, O. Gould, M. Behl, K. Kratz, Reprogrammable, magnetically controlled polymeric nanocomposite actuators, Mater. Horiz. (2018). https://doi.org/10.1039/c8mh00266e.
[43] Q. Zhao, J.W. Dunlop, X. Qiu, F. Huang, Z. Zhang, J. Heyda, J. Dzubiella, M. Antonietti, J. Yuan, An instant multi-responsive porous polymer actuator driven by solvent molecule sorption, Nat. Commun. 5(2014) 4293.
[44] S. Brown, M.R. Sim, M.J. Abramson, C.N. Gray, Concentrations of volatile organic compounds in indoor air-A review, Indoor Air 4(2) (1994) 123-134.
[45] R. Atkinson, J. Arey, Atmospheric degradation of volatile organic compounds, Chem. Rev. 103(12) (2003) 4605-4638.
[46] G. Wypych (Ed.), Handbook of Solvents, ChemTec Publishing, Toronto, 2001.
[47] Z. Wang, J. Zhang, J. Xie, C. Li, Y. Li, S. Liang, Z. Tian, T. Wang, H. Zhang, H. Li, Bioinspired water-vapor-responsive organic/inorganic hybrid one-dimensional photonic crystals with tunable full-color stop band, Adv. Funct. Mater. 20(21) (2010) 3784-3790.
[48] V. Dua, S.P. Surwade, S. Ammu, S.R. Agnihotra, S. Jain, K.E. Roberts, S. Park, R.S. Ruoff, S.K. Manohar, All-organic vapor sensor using inkjet-printed reduced graphene oxide, Angew. Chem. 49(12) (2010) 2154-2157.
[49] P.-Y. Chen, M. Zhang, M. Liu, I.Y. Wong, R.H. Hurt, Ultrastretchable graphene-based molecular barriers for chemical protection, detection, and actuation, ACS Nano 12(1) (2017) 234-244.
[50] M.K. Khan, W.Y. Hamad, M.J. MacLachlan, Tunable mesoporous bilayer photonic resins with chiral nematic structures and actuator properties, Adv. Mater. 26(15) (2014) 2323-2328.
[51] C.S. Haines, M.D. Lima, N. Li, G.M. Spinks, J. Foroughi, J.D. Madden, S.H. Kim, S. Fang, M.J. de Andrade, F. Göktepe, Artificial muscles from fishing line and sewing thread, Science 343(6173) (2014) 868-872.
[52] J. Deng, J. Li, P. Chen, X. Fang, X. Sun, Y. Jiang, W. Weng, B. Wang, H. Peng, Tunable photothermal actuators based on a pre-programmed aligned nanostructure, J. Am. Chem. Soc. 138(1) (2015) 225-230.
[53] R.K. Gogoi, K. Raidongia, Strategic shuffling of clay layers to imbue them with responsiveness, Adv. Mater. 29(24) (2017), 1701164.
[54] R.K. Gogoi, K. Saha, J. Deka, D. Brahma, K. Raidongia, Solvent-driven responsive bilayer membranes of clay and graphene oxide, J. Mater. Chem. A 5(7) (2017) 3523-3533.
[55] K.J. Lee, J. Yoon, S. Rahmani, S. Hwang, S. Bhaskar, S. Mitragotri, J. Lahann, Spontaneous shape reconfigurations in multicompartmental microcylinders, Proc. Natl. Acad. Sci. 109(40) (2012) 16057-16062.
[56] Y. Gu, N.S. Zacharia, Self-healing actuating adhesive based on polyelectrolyte multilayers, Adv. Funct. Mater. 25(24) (2015) 3785-3792.
[57] H. Deng, Y. Dong, C. Zhang, Y. Xie, C. Zhang, J. Lin, An instant responsive polymer driven by anisotropy of crystal phases, Mater. Horiz. 5(1) (2018) 99-107.
[58] H. Lin, J. Gong, H. Miao, R. Guterman, H. Song, Q. Zhao, J.W. Dunlop, J. Yuan, Flexible and actuating nanoporous poly (ionic liquid)-paper-based hybrid membranes, ACS Appl. Mater. Interfaces 9(17) (2017) 15148-15155.
[59] L. Ionov, Soft microorigami:Self-folding polymer films, Soft Matter 7(15) (2011) 6786-6791.
[60] Y. Tan, Z. Chu, Z. Jiang, T. Hu, G. Li, J. Song, Gyrification-inspired highly convoluted graphene oxide patterns for ultralarge deforming actuators, ACS Nano 11(7) (2017) 6843-6852.
[61] C. Zhang, J.-W. Su, H. Deng, Y. Xie, Z. Yan, J. Lin, Reversible self-assembly of 3D architectures actuated by responsive polymers, ACS Appl. Mater. Interfaces 9(47) (2017) 41505-41511.
[62] W.E. Lee, Y.J. Jin, L.S. Park, G. Kwak, Fluorescent actuator based on microporous conjugated polymer with intramolecular stack structure, Adv. Mater. 24(41) (2012) 5604-5609.
[63] H. Deng, Y. Dong, J.-W. Su, C. Zhang, Y. Xie, C. Zhang, M.R. Maschmann, Y. Lin, J. Lin, Bioinspired programmable polymer gel controlled by swellable guest medium, ACS Appl. Mater. Interfaces 9(36) (2017) 30900-30908.
[64] L. Zhang, P.e. Naumov, X. Du, Z. Hu, J. Wang, Vapomechanically responsive motion of microchannel-programmed actuators, Adv. Mater. 29(37) (2017), 1702231.
[65] D.W. Van Krevelen, K. Te Nijenhuis, Properties of Polymers:Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions, Elsevier, Amsterdam, 2009.
[66] C.M. Hansen, The universality of the solubility parameter, Ind. Eng. Chem. Prod. Rd. 8(1) (1969) 2-11.
[67] J.E. Mark, Physical Properties of Polymers Handbook, Springer, London, 2007233-258.
[68] W. Zhai, J. Yu, W. Ma, J. He, Cosolvent effect of water in supercritical carbon dioxide facilitating induced crystallization of polycarbonate, Polym. Eng. Sci. 47(9) (2007) 1338-1343.
[69] R. Kambour, C. Gruner, E. Romagosa, Biphenol-A polycarbonate immersed in organic media. Swelling and response to stress, Macromolecules 7(2) (1974) 248-253.

Composite bilayer films with organic compound-triggered bending properties

Composite bilayer films with organic compound-triggered bending properties

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