SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (1): 180-190.DOI: 10.1016/j.cjche.2018.12.013

• Process Systems Engineering and Process Safety • 上一篇    下一篇

3D printed millireactors for process intensification

Harrson S. Santana1, Alan C. Rodrigues1, Mariana G. M. Lopes1, Felipe N. Russo1, Jo?o L. Silva Jr2, Osvaldir P. Taranto1   

  1. 1 School of Chemical Engineering, University of Campinas, Brazil;
    2 Federal Institute of Education, Science and Technology of South of Minas Gerais, Brazil
  • 收稿日期:2018-10-04 修回日期:2018-12-07 出版日期:2020-01-28 发布日期:2020-03-31
  • 通讯作者: Harrson S. Santana

3D printed millireactors for process intensification

Harrson S. Santana1, Alan C. Rodrigues1, Mariana G. M. Lopes1, Felipe N. Russo1, Jo?o L. Silva Jr2, Osvaldir P. Taranto1   

  1. 1 School of Chemical Engineering, University of Campinas, Brazil;
    2 Federal Institute of Education, Science and Technology of South of Minas Gerais, Brazil
  • Received:2018-10-04 Revised:2018-12-07 Online:2020-01-28 Published:2020-03-31
  • Contact: Harrson S. Santana

摘要: The scope of the present research aims at demonstrating the 3D printing use in the manufacturing of microchannels for chemical process applications. A comparison among digital model processing applications for 3D print (slicers) and a print layer thickness analysis were performed. The 3D print fidelity was verified in several devices, including the microchannels' printing with and without micromixer zones. In order to highlight the 3D print potential in Chemical Engineering, the biodiesel synthesis was also carried out in a millireactor manufactured by 3D printing. The millireactor operated under laminar flow regime with a total flow rate of 75.25 ml·min-1 (increment of about 130 times over traditional microdevices used for biodiesel production). The printed millireactor provided a maximum yield of Ethyl Esters of 73.51% at 40℃, ethanol:oil molar ratio of 7 and catalyst concentration of 1.25 wt% and residence time about 10 s. As a result of flow rate increment attained in the millireactor, the number of required units for scaling-up the chemical processes is reduced. Using the approach described in the present research, anyone could produce their own millireactor for chemical process in a simple way with the aid of a 3D printer.

关键词: Process intensification, 3D printer, Millireactors, Micromixers, Microdevices, Biodiesel

Abstract: The scope of the present research aims at demonstrating the 3D printing use in the manufacturing of microchannels for chemical process applications. A comparison among digital model processing applications for 3D print (slicers) and a print layer thickness analysis were performed. The 3D print fidelity was verified in several devices, including the microchannels' printing with and without micromixer zones. In order to highlight the 3D print potential in Chemical Engineering, the biodiesel synthesis was also carried out in a millireactor manufactured by 3D printing. The millireactor operated under laminar flow regime with a total flow rate of 75.25 ml·min-1 (increment of about 130 times over traditional microdevices used for biodiesel production). The printed millireactor provided a maximum yield of Ethyl Esters of 73.51% at 40℃, ethanol:oil molar ratio of 7 and catalyst concentration of 1.25 wt% and residence time about 10 s. As a result of flow rate increment attained in the millireactor, the number of required units for scaling-up the chemical processes is reduced. Using the approach described in the present research, anyone could produce their own millireactor for chemical process in a simple way with the aid of a 3D printer.

Key words: Process intensification, 3D printer, Millireactors, Micromixers, Microdevices, Biodiesel