SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (8): 1863-1869.DOI: 10.1016/j.cjche.2019.01.003

• • 上一篇    下一篇

2-Ethyl-9,10-anthraquinone assisted sol-gel synthesis of Pd/γ-Al2O3 nanorods with enhanced catalytic performance in 2-ethyl-9,10-anthraquinone hydrogenation

Weiquan Cai1,2, Junlin Zhuo1, Jimin Fang3, Zhichao Yang1,2   

  1. 1 School of Chemistry and Chemical Engineering, Guangzhou University, 230 Guangzhou University City Outer Ring Road, Guangzhou 510006, China;
    2 School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China;
    3 School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China
  • 收稿日期:2018-10-20 修回日期:2019-01-01 出版日期:2019-08-28 发布日期:2019-11-16
  • 通讯作者: Weiquan Cai
  • 基金资助:
    Supported by the 2016 Wuhan Yellow Crane Talents (Science) Program, and One Hundred Talents Project of Guangzhou University (No. 69-18ZX10016).

2-Ethyl-9,10-anthraquinone assisted sol-gel synthesis of Pd/γ-Al2O3 nanorods with enhanced catalytic performance in 2-ethyl-9,10-anthraquinone hydrogenation

Weiquan Cai1,2, Junlin Zhuo1, Jimin Fang3, Zhichao Yang1,2   

  1. 1 School of Chemistry and Chemical Engineering, Guangzhou University, 230 Guangzhou University City Outer Ring Road, Guangzhou 510006, China;
    2 School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Wuhan 430070, China;
    3 School of Resources and Environmental Engineering, Wuhan University of Technology, Wuhan 430070, China
  • Received:2018-10-20 Revised:2019-01-01 Online:2019-08-28 Published:2019-11-16
  • Contact: Weiquan Cai
  • Supported by:
    Supported by the 2016 Wuhan Yellow Crane Talents (Science) Program, and One Hundred Talents Project of Guangzhou University (No. 69-18ZX10016).

摘要: A series of nanorod-like porous Pd/γ-Al2O3 catalysts with controllable textural properties and enhanced catalytic performance in 2-ethyl-9,10-anthraquinone (eAQ) hydrogenation for H2O2 preparation were successfully prepared via a facile sol-gel method using aluminum isopropoxide as aluminum precursor and eAQ as structure directing agent, sequential calcination and impregnation process with Na2PdCl4 solution. The physicochemical properties of the catalysts obtained with different addition amounts of eAQ were comparatively characterized by XRD, TG-DSC, BET, TEM, CO-TPR, H2-TPR and H2-O2 titration. The results show that addition of eAQ can not only effectively control the textural properties (surface area, pore volume and average pore size) of the catalysts, but also lower their reduction temperature of active metal. Importantly, the catalyst obtained with an addition amount of 4 wt% eAQ shows the highest hydrogenation efficiency of 10.28 g·L-1, which is 37.3% higher than 7.49 g·L-1 of the catalyst obtained without eAQ.

关键词: Catalyst, Hydrogenation, Alumina, 2-Ethyl-9,10-anthraquinone, Structure directing agent, H2O2

Abstract: A series of nanorod-like porous Pd/γ-Al2O3 catalysts with controllable textural properties and enhanced catalytic performance in 2-ethyl-9,10-anthraquinone (eAQ) hydrogenation for H2O2 preparation were successfully prepared via a facile sol-gel method using aluminum isopropoxide as aluminum precursor and eAQ as structure directing agent, sequential calcination and impregnation process with Na2PdCl4 solution. The physicochemical properties of the catalysts obtained with different addition amounts of eAQ were comparatively characterized by XRD, TG-DSC, BET, TEM, CO-TPR, H2-TPR and H2-O2 titration. The results show that addition of eAQ can not only effectively control the textural properties (surface area, pore volume and average pore size) of the catalysts, but also lower their reduction temperature of active metal. Importantly, the catalyst obtained with an addition amount of 4 wt% eAQ shows the highest hydrogenation efficiency of 10.28 g·L-1, which is 37.3% higher than 7.49 g·L-1 of the catalyst obtained without eAQ.

Key words: Catalyst, Hydrogenation, Alumina, 2-Ethyl-9,10-anthraquinone, Structure directing agent, H2O2