Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes

doi:10.1016/j.cjche.2019.04.011

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (1): 114-121.DOI: 10.1016/j.cjche.2019.04.011

• Separation Science and Engineering • 上一篇下一篇

Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes

Yazhi Yang, Qianqian Lan, Yong Wang

State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

收稿日期:2019-02-26 修回日期:2019-04-02 出版日期:2020-01-28 发布日期:2020-03-31
通讯作者: Yong Wang
基金资助:
Supported by the National Basic Research Program of China (2015CB655301), the Natural Science Foundation of China (21825803), and the Natural Science Foundation of Jiangsu Province (BK20150063), the Program of Excellent Innovation Teams of Jiangsu Higher Education Institutions, and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes

Yazhi Yang, Qianqian Lan, Yong Wang

State Key Laboratory of Materials-Oriented Chemical Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China

Received:2019-02-26 Revised:2019-04-02 Online:2020-01-28 Published:2020-03-31
Contact: Yong Wang
Supported by:
Supported by the National Basic Research Program of China (2015CB655301), the Natural Science Foundation of China (21825803), and the Natural Science Foundation of Jiangsu Province (BK20150063), the Program of Excellent Innovation Teams of Jiangsu Higher Education Institutions, and the Project of Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD).

摘要/Abstract

摘要： Thin film composite (TFC) membranes represent a highly promising platform for efficient nanofiltration (NF) processes. However, the improvement in permeance is impeded by the substrates with low permeances. Herein, highly permeable gradient phenolic membranes with tight selectivity are used as substrates to prepare TFC membranes with high permeances by the layer-by-layer assembly method. The negatively charged phenolic substrates are alternately assembled with polycation polyethylenimine (PEI) and polyanion poly(acrylic acid) (PAA) as a result of electrostatic interactions, forming thin and compact PEI/PAA layers tightly attached to the substrate surface. Benefiting from the high permeances and tight surface pores of the gradient nanoporous structures of the substrates, the produced PEI/PAA membranes exhibit a permeance up to 506 L·m^-2·h^-1·MPa^-1, which is ~2-10 times higher than that of other membranes with similar rejections. The PEI/PAA membranes are capable of retaining >96.1% of negatively charged dyes following the mechanism of electrostatic repulsion. We demonstrate that the membranes can also separate positively and neutrally charged dyes from water via other mechanisms. This work opens a new avenue for the design and preparation of high-flux NF membranes, which is also applicable to enhance the permeance of other TFC membranes.

关键词: Nanofiltration membrane, Polyelectrolyte, Layer-by-layer assembly, High permeance, Gradient phenolic

Abstract: Thin film composite (TFC) membranes represent a highly promising platform for efficient nanofiltration (NF) processes. However, the improvement in permeance is impeded by the substrates with low permeances. Herein, highly permeable gradient phenolic membranes with tight selectivity are used as substrates to prepare TFC membranes with high permeances by the layer-by-layer assembly method. The negatively charged phenolic substrates are alternately assembled with polycation polyethylenimine (PEI) and polyanion poly(acrylic acid) (PAA) as a result of electrostatic interactions, forming thin and compact PEI/PAA layers tightly attached to the substrate surface. Benefiting from the high permeances and tight surface pores of the gradient nanoporous structures of the substrates, the produced PEI/PAA membranes exhibit a permeance up to 506 L·m^-2·h^-1·MPa^-1, which is ~2-10 times higher than that of other membranes with similar rejections. The PEI/PAA membranes are capable of retaining >96.1% of negatively charged dyes following the mechanism of electrostatic repulsion. We demonstrate that the membranes can also separate positively and neutrally charged dyes from water via other mechanisms. This work opens a new avenue for the design and preparation of high-flux NF membranes, which is also applicable to enhance the permeance of other TFC membranes.

Key words: Nanofiltration membrane, Polyelectrolyte, Layer-by-layer assembly, High permeance, Gradient phenolic

Yazhi Yang, Qianqian Lan, Yong Wang. Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes[J]. 中国化学工程学报, 2020, 28(1): 114-121.

参考文献

[1] F.X. Xiao, M. Pagliaro, Y.J. Xu, et al., Layer-by-layer assembly of versatile nanoarchitectures with diverse dimensionality:A new perspective for rational construction of multilayer assemblies, Chem. Soc. Rev. 45(2016) 3088-3121.
[2] J.F. Quinn, A.P. Johnston, G.K. Such, et al., Next generation, sequentially assembled ultrathin films:Beyond electrostatics, Chem. Soc. Rev. 36(2007) 707-718.
[3] M. Herzberg, A. Sweity, M. Brami, et al., Surface properties and reduced biofouling of graft-copolymers that possess oppositely charged groups, Biomacromolecules 12(2011) 1169-1177.
[4] Y. Lv, H.C. Yang, H.Q. Liang, et al., Nanofiltration membranes via co-deposition of polydopamine/polyethylenimine followed by cross-linking, J. Membr. Sci. 476(2015) 50-58.
[5] W.Z. Qiu, Y. Lv, Y. Du, et al., Composite nanofiltration membranes via the codeposition and cross-linking of catechol/polyethylenimine, RSC Adv. 6(2016) 34096-34102.
[6] C. Liu, W.X. Fang, S.R., et al., Fabrication of layer-by-layer assembled FO hollow fiber membranes and their performances using low concentration draw solutions, Desalination 308(2013) 147-153.
[7] H.Y. Shi, L.X. Xue, A.L. Gao, et al., Fouling-resistant and adhesion-resistant surface modification of dual layer PVDF hollow fiber membrane by dopamine and quaternary polyethyleneimine, J. Membr. Sci. 498(2016) 39-47.
[8] W.N. Wang, Y.S. Xu, S. Backes, et al., Construction of compact polyelectrolyte multilayers inspired by marine mussel:Effects of salt concentration and pH as observed by QCM-D and AFM, Langmuir 32(2016) 3365-3374.
[9] P.H.H. Duong, J. Zuo, T.S. Chung, Highly crosslinked layer-by-layer polyelectrolyte FO membranes:Understanding effects of salt concentration and deposition time on FO performance, J. Membr. Sci. 427(2013) 411-421.
[10] A.W. Mohammad, Y.H. Teow, W.L. Ang, et al., Nanofiltration membranes review:Recent advances and future prospects, Desalination 356(2015) 226-254.
[11] C. Bartels, M. Wilf, W. Casey, et al., New generation of low fouling nanofiltration membranes, Desalination 221(2008) 158-167.
[12] K. Wang, A.A. Abdalla, M.A. Khaleel, et al., Mechanical properties of water desalination and wastewater treatment membranes, Desalination 401(2017) 190-205.
[13] G. Han, T.S. Chung, M. Weber, et al., Low-pressure nanofiltration hollow fiber membranes for effective fractionation of dyes and inorganic salts in textile wastewater, Environ. Sci. Technol. 52(2018) 3676-3684.
[14] W.J. Lau, A.F. Ismail, N. Misdan, et al., A recent progress in thin film composite membrane:A review, Desalination 287(2012) 190-199.
[15] M. Paul, S.D. Jons, Chemistry and fabrication of polymeric nanofiltration membranes:A review, Polymer 103(2016) 417-456.
[16] G.R. Xu, X.Y. Liu, J.M., et al., High flux nanofiltration membranes based on layer-bylayer assembly modified electrospun nanofibrous substrate, Appl. Surf. Sci. 434(2018) 573-581.
[17] J.Y. Zhou, Z.P. Qin, Y.H. Lu, et al., MoS₂/polyelectrolytes hybrid nanofiltration (NF) membranes with enhanced permselectivity, J. Taiwan Inst. Chem. Eng. 84(2018) 196-202.
[18] S.B. Darling, Perspective:Interfacial materials at the interface of energy and water, J. Appl. Phys. 124(2018) 030901.
[19] A. Quinn, E. Tjipto, A.M. Yu, et al., Polyelectrolyte blend multilayer films:Surface morphology, wettability, and protein adsorption characteristics, Langmuir 23(2007) 4944-4949.
[20] H.Y. Zhen, T.T. Wang, R. Jia, et al., Preparation and performance of antibacterial layer-by-layer polyelectrolyte nanofiltration membranes based on metal-ligand coordination interactions, RSC Adv. 5(2015) 86784-86794.
[21] M. Strawski, L.H. Granicka, M. Szklarczyk, Redox properties of polyelectrolyte multilayer modified electrodes:A significant effect of the interactions between the polyelectrolyte layers in the films, Electrochim. Acta 226(2017) 121-131.
[22] Y.F. Huang, J.J. Sun, D.H. Wu, et al., Layer-by-layer self-assembled chitosan/PAA nanofiltration membranes, Sep. Purif. Technol. 207(2018) 142-150.
[23] J. de Grooth, D.M. Reurink, J. Ploegmakers, et al., Charged micropollutant removal with hollow fiber nanofiltration membranes based on polycation/polyzwitterion/polyanion multilayers, ACS Appl. Mater. Interfaces 6(2014) 17009-17017.
[24] L.D. Shen, C. Cheng, X.F. Yu, et al., Low pressure UV-cured CS-PEO-PTEGDMA/PAN thin film nanofibrous composite nanofiltration membranes for anionic dye separation, J. Mater. Chem. A 4(2016) 15575-15588.
[25] R.J. Petersen, Composite reverse osmosis and nanofiltration membranes, J. Membr. Sci. 83(1993) 81-150.
[26] R.R. Choudhury, J.M. Gohil, S. Mohanty, et al., Antifouling, fouling release and antimicrobial materials for surface modification of reverse osmosis and nanofiltration membranes, J. Mater. Chem. A 6(2018) 313-333.
[27] M. Ulbricht, Advanced functional polymer membranes, Polymer 47(2006) 2217-2262.
[28] C. Ursino, R. Castro-Munoz, E. Drioli, et al., Progress of nanocomposite membranes for water treatment, Membranes (Basel) 8(2018) 2-40.
[29] N. Dizge, R. Epsztein, W. Cheng, et al., Biocatalytic and salt selective multilayer polyelectrolyte nanofiltration membrane, J. Membr. Sci. 549(2018) 357-365.
[30] O. Tekinalp, S. Alsoy Altinkaya, Development of high flux nanofiltration membranes through single bilayer polyethyleneimine/alginate deposition, J. Colloid Interface Sci. 537(2019) 215-227.
[31] Z. Lin, Q. Zhang, Y. Qu, et al., LBL assembled polyelectrolyte nanofiltration membranes with tunable surface charges and high permeation by employing a nanosheet sacrificial layer, J. Mater. Chem. A 5(2017) 14819-14827.
[32] S. Karan, Z. Jiang, A.G. Livingston, Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation, Science 348(2015) 1347-1351.
[33] J. Li, M.J. Wei, Y. Wang, Substrate matters:The influences of substrate layers on the performances of thin-film composite reverse osmosis membranes, Chin. J. Chem. Eng. 25(2017) 1676-1684.
[34] S.C. Hess, A.X. Kohll, R.A. Raso, et al., Template-particle stabilized bicontinuous emulsion yielding controlled assembly of hierarchical high-flux filtration membranes, ACS Appl. Mater. Interfaces 7(2015) 611-617.
[35] L. Guo, Y. Yang, F. Xu, et al., Design of gradient nanopores in phenolics for ultrafast water permeation, Chem. Sci. 10(2019) 2093-2100.
[36] Q. Lan, Y. Yang, L. Guo, et al., Gradient nanoporous phenolics filled in macroporous substrates for highly permeable ultrafiltration, J. Membr. Sci. 576(2019) 123-130.
[37] G.J. Zhang, H.H. Yan, S.L. Ji, et al., Self-assembly of polyelectrolyte multilayer pervaporation membranes by a dynamic layer-by-layer technique on a hydrolyzed polyacrylonitrile ultrafiltration membrane, J. Membr. Sci. 292(2007) 1-8.
[38] L.Z. Zheng, L.Y. Xiong, Layer-by-layer assembly of PA-EDTA/PAH multilayer films and their potential-switchable electrochemistry, Colloids Surf. A Physicochem. Eng. Asp. 289(2006) 179-184.
[39] R.R. Gonzales, M.J. Park, L. Tijing, et al., Modification of nanofiber support layer for thin film composite forward osmosis membranes via layer-by-layer polyelectrolyte deposition, Membranes (Basel) 8(2018) 1-15.
[40] K. Hong, S.H. Kim, C. Yang, et al., Photopatternable poly(4-styrene sulfonic acid)-wrapped MWNT thin-film source/drain electrodes for use in organic field-effect transistors, ACS Appl. Mater. Interfaces 3(2011) 74-79.
[41] S.L. Chen, J.B. Benziger, A.B. Bocarsly, et al., Photo-cross-linking of sulfonated styrene-ethylene-butylene copolymer membranes for fuel cells, Ind. Eng. Chem. Res. 44(2005) 7701-7705.
[42] S. Wang, J. Cai, W. Ding, et al., Bio-inspired aquaporinz containing double-skinned forward osmosis membrane synthesized through layer-by-layer assembly, Membranes (Basel) 5(2015) 369-384.
[43] Y. Tian, Q. He, C. Tao, et al., Fabrication of fluorescent nanotubes basel on layer-bylayer assembly via covalent bond, Langmuir 22(2006) 360-362.
[44] M.R. Teixeira, M.J. Rosa, M. Nystrom, The role of membrane charge on nanofiltration performance, J. Membr. Sci. 265(2005) 160-166.
[45] X. Shi, R. Wang, A. Xiao, et al., Layer-by-layer synthesis of covalent organic frameworks on porous substrates for fast molecular separations, ACS Appl. Nano. Mater. 11(2018) 6320-6326.
[46] P. Shi, X.K. Hu, Y.T. Wang, et al., A PEG-tannic acid decorated microfiltration membrane for the fast removal of Rhodamine B from water, Sep. Purif. Technol. 207(2018) 443-450.

Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes

Gradient nanoporous phenolics as substrates for high-flux nanofiltration membranes by layer-by-layer assembly of polyelectrolytes

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 11

编辑推荐

Metrics

本文评价

[1]	Haike Li, Xindong Li, Guozai Ouyang, Lang Li, Zhaohuang Zhong, Meng Cai, Wenhao Li, Wanfu Huang. Tannic acid/Fe³⁺ interlayer for preparation of high-permeability polyetherimide organic solvent nanofiltration membranes for organic solvent separation[J]. 中国化学工程学报, 2023, 57(5): 17-29.
[2]	Shujie Guo, Jiao Du, Fangzheng Yan, Zhi Wang, Jixiao Wang. Fabrication of anti-fouling polyamide nanofiltration membrane by incorporating streptomycin as a novel co-monomer[J]. 中国化学工程学报, 2022, 50(10): 185-196.
[3]	Yahua Lu, Zhenping Qin, Naixin Wang, Hongxia Guo, Quanfu An, Yucang Liang. TiO₂-incorporated polyelectrolyte composite membrane with transformable hydrophilicity/hydrophobicity for nanofiltration separation[J]. 中国化学工程学报, 2020, 28(10): 2533-2541.
[4]	Chunli Liu, Weihui Bi, Dongliang Chen, Suobo Zhang, Hongchao Mao. Positively charged nanofiltration membrane fabricated by poly(acid-base) complexing effect induced phase inversion method forheavy metal removal[J]. Chinese Journal of Chemical Engineering, 2017, 25(11): 1685-1694.
[5]	Zhuan Yi, Fa-dong Wu, Yong Zhou, Cong-jie Gao. Novel nanofiltration membranes with tunable permselectivity by polymer mediated phase separation in polyamide selective layer[J]. Chinese Journal of Chemical Engineering, 2016, 24(11): 1533-1540.
[6]	Yanni Wang, Hairong Yu, Rui Xie, Kuangmin Zhao, Xiaojie Ju, WeiWang, Zhuang Liu, Liangyin Chu. An easily recoverable thermo-sensitive polyelectrolyte as draw agent for forward osmosis process[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 86-93.
[7]	Yong Zhou, Zhenan Dai, Ding Zhai, Congjie Gao. Surface modification of polypiperazine-amide membrane by self-assembled method for dye wastewater treatment[J]. Chinese Journal of Chemical Engineering, 2015, 23(6): 912-918.
[8]	刘杰凤, 任意然, 姚善泾. Repeated-batch Cultivation of Encapsulated Monascus purpureus by Polyelectrolyte Complex for Natural Pigment Production[J]. , 2010, 18(6): 1013-1017.
[9]	苗晶, 李玲玲, 陈国华, 高从堦, 董声雄. Preparation of N,O-carboxymethyl Chitosan Composite Nanofiltration Membrane and Its Rejection Performance for the Fermentation Effluent from a Wine Factory[J]. , 2008, 16(2): 209-213.
[10]	徐毅, 冯剑, 尚亚卓, 刘洪来. 连接基团与尾链长度对阳离子Gemini表面活性剂与阴离子聚电解质复合物影响的分子动力学模拟[J]. , 2007, 15(4): 560-565.
[11]	张波, 蔡钧, 刘洪来, 胡英. 含盐聚电解质溶液的分子热力学模型[J]. , 2002, 10(3): 311-315.