SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (11): 2783-2787.DOI: 10.1016/j.cjche.2019.06.001

• Energy, Resources and Environmental Technology • 上一篇    下一篇

Characterization of nitrogen-containing aromatics in Baiyinhua lignite and its soluble portions from thermal dissolution

Yangyang Zhang1, Xianyong Wei1,2, Jinghui Lü3, Hao Jiang1, Fangjing Liu1, Guanghui Liu1, Zhimin Zong1   

  1. 1 Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China;
    2 State Key Laboratory of High-efficiency Utilization and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China;
    3 Department of Chemical Engineering, College of Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
  • 收稿日期:2018-08-12 修回日期:2019-02-05 出版日期:2019-11-28 发布日期:2020-01-19
  • 通讯作者: Xianyong Wei
  • 基金资助:
    Supported by the Key Project of Joint Fund from National Natural Science Foundation of China and the Government of Xinjiang Uygur Autonomous Region (U1503293), the National Key Research and Development Program of China (2018YFB0604602), and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

Characterization of nitrogen-containing aromatics in Baiyinhua lignite and its soluble portions from thermal dissolution

Yangyang Zhang1, Xianyong Wei1,2, Jinghui Lü3, Hao Jiang1, Fangjing Liu1, Guanghui Liu1, Zhimin Zong1   

  1. 1 Key Laboratory of Coal Processing and Efficient Utilization, Ministry of Education, China University of Mining & Technology, Xuzhou 221116, China;
    2 State Key Laboratory of High-efficiency Utilization and Green Chemical Engineering, Ningxia University, Yinchuan 750021, China;
    3 Department of Chemical Engineering, College of Chemical Engineering, Henan Polytechnic University, Jiaozuo 454003, China
  • Received:2018-08-12 Revised:2019-02-05 Online:2019-11-28 Published:2020-01-19
  • Contact: Xianyong Wei
  • Supported by:
    Supported by the Key Project of Joint Fund from National Natural Science Foundation of China and the Government of Xinjiang Uygur Autonomous Region (U1503293), the National Key Research and Development Program of China (2018YFB0604602), and the Priority Academic Program Development of Jiangsu Higher Education Institutions.

摘要: Soluble portions (SPs) 1-4 (SP1-SP4) were afforded from sequentially dissolution and alkanolyses of Baiyinhua lignite (BL) in cyclohexane, CH3OH, CH3CH2OH, and (CH3)2CHOH at 300℃. They were analyzed with a gas chromatograph/mass spectrometer and quadrupole exactive orbitrap mass spectrometer (QEOTMS) with an atmosphere pressure chemical ionization source in positive-ion mode, while BL was characterized with an X-ray photoelectron spectrometer (XRPES). The results show that the yields of SP2 and SP3 are much higher than those of SP1 and SP4, and the total SP yield is ca. 39.0%. According to the analysis with XRPES, pyrrolic nitrogen atoms are the most abundant nitrogen existing forms in BL. Thousands of nitrogen-containing aromatics (NCAs) were resolved with QEOTMS and their molecular masses are mainly in the range of 200-450 u. The main NCAs are N1O1 and N1O2 class species with double bond equivalent values of 4-18 and carbon numbers of 7-30. The nitrogen atoms appear in pyridines, quinolines, benzoquinolines or acridine, and dibenzoquinolines or naphthoquinolines, while the oxygen atoms exist in methoxy and furan rings.

关键词: Lignite, Sequential thermal dissolution and alkanolyses, Nitrogen-containing aromatics

Abstract: Soluble portions (SPs) 1-4 (SP1-SP4) were afforded from sequentially dissolution and alkanolyses of Baiyinhua lignite (BL) in cyclohexane, CH3OH, CH3CH2OH, and (CH3)2CHOH at 300℃. They were analyzed with a gas chromatograph/mass spectrometer and quadrupole exactive orbitrap mass spectrometer (QEOTMS) with an atmosphere pressure chemical ionization source in positive-ion mode, while BL was characterized with an X-ray photoelectron spectrometer (XRPES). The results show that the yields of SP2 and SP3 are much higher than those of SP1 and SP4, and the total SP yield is ca. 39.0%. According to the analysis with XRPES, pyrrolic nitrogen atoms are the most abundant nitrogen existing forms in BL. Thousands of nitrogen-containing aromatics (NCAs) were resolved with QEOTMS and their molecular masses are mainly in the range of 200-450 u. The main NCAs are N1O1 and N1O2 class species with double bond equivalent values of 4-18 and carbon numbers of 7-30. The nitrogen atoms appear in pyridines, quinolines, benzoquinolines or acridine, and dibenzoquinolines or naphthoquinolines, while the oxygen atoms exist in methoxy and furan rings.

Key words: Lignite, Sequential thermal dissolution and alkanolyses, Nitrogen-containing aromatics