Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment

doi:10.1016/j.cjche.2020.06.005

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (10): 2600-2606.DOI: 10.1016/j.cjche.2020.06.005

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment

Chunhua Zhang^1,2, Guangxin Yang¹, Hong Jiang¹, Yefei Liu¹, Rizhi Chen¹, Weihong Xing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Changzhou Key Laboratory of Eco-Textile Technology, Changzhou Vocational Institute of Textile and Garment, Changzhou 213164, China

收稿日期:2020-04-08 修回日期:2020-05-26 出版日期:2020-10-28 发布日期:2020-12-03
通讯作者: Rizhi Chen, Weihong Xing
基金资助:
The financial supports from the National Key R&D Program (2016YFB0301503), the National Natural Science Foundation of China (21776127, 21921006), the Jiangsu Province Key R&D Program (BE2018009-2), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the State Key Laboratory of Materials-Oriented Chemical Engineering (ZK201902) of China are gratefully acknowledged.

Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment

Chunhua Zhang^1,2, Guangxin Yang¹, Hong Jiang¹, Yefei Liu¹, Rizhi Chen¹, Weihong Xing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 Changzhou Key Laboratory of Eco-Textile Technology, Changzhou Vocational Institute of Textile and Garment, Changzhou 213164, China

Received:2020-04-08 Revised:2020-05-26 Online:2020-10-28 Published:2020-12-03
Contact: Rizhi Chen, Weihong Xing
Supported by:
The financial supports from the National Key R&D Program (2016YFB0301503), the National Natural Science Foundation of China (21776127, 21921006), the Jiangsu Province Key R&D Program (BE2018009-2), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the State Key Laboratory of Materials-Oriented Chemical Engineering (ZK201902) of China are gratefully acknowledged.

摘要/Abstract

摘要： Selective phenol hydrogenation is a green approach to produce cyclohexanone. It still remains a big challenge to prepare efficient supports of the catalysts for the phenol hydrogenation via a simple and cost-effective approach. Herein, a facile approach was developed, i.e., direct calcination of activated carbon (AC) under argon at high temperature, to improve its structure and surface properties. The modified AC materials were supported with Pd nanoparticles (NPs) to fabricate the Pd/C catalysts. The as-prepared Pd/C600 catalyst exhibits superior catalytic performance in the phenol hydrogenation, and its turnover frequency (TOF) value is 199.2 h^-1, 1.31 times to that of Pd/C-raw. The Pd/C600 catalyst presents both better hydrophobicity and more structural defects, contributing to the improved dispersibility in the reaction solution (phenol-cyclohexane), the better Pd dispersion and the smaller Pd size, which result in the enhancement of the catalytic performance. Furthermore, the as-prepared Pd/C600 catalyst shows a good recyclability.

关键词: Cyclohexanone, Phenol, Hydrogenation, Activated carbon, Catalyst

Abstract: Selective phenol hydrogenation is a green approach to produce cyclohexanone. It still remains a big challenge to prepare efficient supports of the catalysts for the phenol hydrogenation via a simple and cost-effective approach. Herein, a facile approach was developed, i.e., direct calcination of activated carbon (AC) under argon at high temperature, to improve its structure and surface properties. The modified AC materials were supported with Pd nanoparticles (NPs) to fabricate the Pd/C catalysts. The as-prepared Pd/C600 catalyst exhibits superior catalytic performance in the phenol hydrogenation, and its turnover frequency (TOF) value is 199.2 h^-1, 1.31 times to that of Pd/C-raw. The Pd/C600 catalyst presents both better hydrophobicity and more structural defects, contributing to the improved dispersibility in the reaction solution (phenol-cyclohexane), the better Pd dispersion and the smaller Pd size, which result in the enhancement of the catalytic performance. Furthermore, the as-prepared Pd/C600 catalyst shows a good recyclability.

Key words: Cyclohexanone, Phenol, Hydrogenation, Activated carbon, Catalyst

Chunhua Zhang, Guangxin Yang, Hong Jiang, Yefei Liu, Rizhi Chen, Weihong Xing. Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment[J]. 中国化学工程学报, 2020, 28(10): 2600-2606.

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Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment

Phenol hydrogenation to cyclohexanone over palladium nanoparticles loaded on charming activated carbon adjusted by facile heat treatment

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