One-step synthesis of Ni@Pd/NH2-Fe3O4 nanoparticles as affordable catalyst for formic acid dehydrogenation

doi:10.1016/j.cjche.2020.07.067

摘要/Abstract

摘要： Currently, one of the critical issues in the world is finding an appropriate green alternative to fossil fuels due to the concerns about global warming. As a hydrogen source, formic acid has been given particular attention owing to the attractive features such as high-energy density, no toxicity, high stability at ambient temperature and high hydrogen content. Introducing an affordable and highly efficient catalyst with easy recovery from the reaction mixture for selective dehydrogenation of formic acid is still demanding. In this report, we used a simple one-step process to synthesize Ni@Pd core shell nanoparticles on 3-aminopropyltriethoxysilane modified Fe₃O₄ nanoparticles. The existence of Ni and Pd results in a synergic effect on the catalytic activity. The -NH₂ groups play an important role for obtaining well-dispersed ultrafine particles with high surface area and active sites. In addition, Fe₃O₄ lead to convenient magnetic recovery of the catalyst from reaction mixture. Our results indicate that the as-prepared catalyst give the superb turnover frequency of 5367.8 h^-1 with no additive, which is higher than most of the previously reported catalysts.

关键词: Core-shell, Fe₃O₄, Catalysis, Dehydrogenation, Formic acid

Abstract: Currently, one of the critical issues in the world is finding an appropriate green alternative to fossil fuels due to the concerns about global warming. As a hydrogen source, formic acid has been given particular attention owing to the attractive features such as high-energy density, no toxicity, high stability at ambient temperature and high hydrogen content. Introducing an affordable and highly efficient catalyst with easy recovery from the reaction mixture for selective dehydrogenation of formic acid is still demanding. In this report, we used a simple one-step process to synthesize Ni@Pd core shell nanoparticles on 3-aminopropyltriethoxysilane modified Fe₃O₄ nanoparticles. The existence of Ni and Pd results in a synergic effect on the catalytic activity. The -NH₂ groups play an important role for obtaining well-dispersed ultrafine particles with high surface area and active sites. In addition, Fe₃O₄ lead to convenient magnetic recovery of the catalyst from reaction mixture. Our results indicate that the as-prepared catalyst give the superb turnover frequency of 5367.8 h^-1 with no additive, which is higher than most of the previously reported catalysts.

Key words: Core-shell, Fe₃O₄, Catalysis, Dehydrogenation, Formic acid

Mohammad Reza Nabid, Yasamin Bide, Mahsa Jafari. One-step synthesis of Ni@Pd/NH₂-Fe₃O₄ nanoparticles as affordable catalyst for formic acid dehydrogenation[J]. 中国化学工程学报, 2021, 32(4): 168-174.

Mohammad Reza Nabid, Yasamin Bide, Mahsa Jafari. One-step synthesis of Ni@Pd/NH₂-Fe₃O₄ nanoparticles as affordable catalyst for formic acid dehydrogenation[J]. Chinese Journal of Chemical Engineering, 2021, 32(4): 168-174.

参考文献

[1] A. Kumar, R. Prasad, Y.C. Sharma, Ethanol steam reforming study over ZSM-5 supported cobalt versus nickel catalyst for renewable hydrogen generation, Chin. J. Chem. Eng. 27(2019) 677-684.
[2] S. Prabu, Electrodeposition of aluminum on needle cathode using AlCl₃/Urea molten salts at low-temperature and its application to hydrogen generation, Chin. J. Chem. Eng. 28(3) (2020) 854-863.
[3] J. Meng, Y. Li, A high H₂ evolution rate under visible light of a CdS/TiO₂@NiS catalyst due to a directional electron transfer between the phases, Chin. J. Chem. Eng. 27(2019) 544-548.
[4] A.F. Dalebrook, W. Gan, M. Grasemann, S. Moret, G. Laurenczy, Hydrogen storage:Beyond conventional methods, Chem. Commun. 49(2013) 8735-8751.
[5] C. Fink, L. Chen, G. Laurenczy, Homogeneous catalytic formic acid dehydrogenation in aqueous solution using ruthenium arene phosphine catalysts, Zeitschrift für anorganische und allgemeine Chemie 644(2018) 740-744.
[6] D. Teichmann, W. Arlt, P. Wasserscheid, R. Freymann, A future energy supply based on liquid organic hydrogen carriers (LOHC), Energy Environ. Sci. 4(2011) 2767-2773.
[7] M. Hattori, D. Shimamoto, H. Ago, M. Tsuji, AgPd@Pd/TiO₂ nanocatalyst synthesis by microwave heating in aqueous solution for efficient hydrogen production from formic acid, J. Mater. Chem. A 3(2015) 10666-10670.
[8] M.R. Nabid, Y. Bide, B. Etemadi, Ag@Pd nanoparticles immobilized on a nitrogen-doped graphene carbon nanotube aerogel as a superb catalyst for the dehydrogenation of formic acid, New J. Chem. 41(2017) 10773-10779.
[9] W. Zhou, Z. Wei, A. Spannenberg, H. Jiao, K. Junge, H. Junge, M. Beller, Cobaltcatalyzed aqueous dehydrogenation of formic acid, Chem.-Europ. J. 25(36) (2019) 8459-8464.
[10] A. Agapova, E. Alberico, A. Kammer, H. Junge, M. Beller, Catalytic dehydrogenation of formic acid with ruthenium-PNP-pincer complexes:comparing N-methylated and NH-ligands, ChemCatChem 11(2019) 1910-1914.
[11] Y. Huang, X. Zhou, M. Yin, C. Liu, W. Xing, Novel PdAu@Au/C core-shell catalyst:Superior activity and selectivity in formic acid decomposition for hydrogen generation, Chem. Mater. 22(2010) 5122-5128.
[12] S.J. Li, Y. Ping, J.M. Yan, H.L. Wang, M. Wu, Q. Jiang, Facile synthesis of AgAuPd/graphene with high performance for hydrogen generation from formic acid, J. Mater. Chem. A 3(2015) 14535-14538.
[13] Y. Bide, M.R. Nabid, B. Etemadi, Facile synthesis and catalytic application of selenium doped graphene/CoFe₂O₄ for highly efficient and noble metal free dehydrogenation of formic acid, Int. J. Hydrogen Energy 41(2016) 20147-20155.
[14] S.J. Li, Y.T. Zhou, X. Kang, D.X. Liu, L. Gu, Q.H. Zhang, J.M. Yan, Q. Jiang, A simple and effective principle for a rational design of heterogeneous catalysts for dehydrogenation of formic acid, Adv. Mater. 31(2019) 1806781.
[15] A. Chen, P. Holt-Hindle, Platinum-based nanostructured materials:synthesis, properties, and applications, Chem. Rev. 110(2010) 3767-3804.
[16] K. Jiang, K. Xu, S. Zou, W.-B. Cai, B-Doped Pd catalyst:boosting roomtemperature hydrogen production from formic acid-formate solutions, J. Am. Chem. Soc. 136(2014) 4861-4864.
[17] Q. Zhang, Z. Zhu, X. Zhang, P. Li, Y. Huang, X. Luo, Z. Liang, Aminefunctionalized sepiolite:Toward highly efficient palladium nanocatalyst for dehydrogenation of additive-free formic acid, Int. J. Hydrogen Energy 44(2019) 16707-16717.
[18] Y.L. Qin, J. Wang, F.-Z. Meng, L.M. Wang, X.B. Zhang, Efficient PdNi and PdNi@Pd-catalyzed hydrogen generation via formic acid decomposition at room temperature, Chem. Commun. 49(2013) 10028-10030.
[19] J.M. Yan, S.J. Li, S.S. Yi, B.R. Wulan, W.T. Zheng, Q. Jiang, Anchoring and upgrading ultrafine NiPd on room-temperature-synthesized bifunctional NH₂-N-rGO toward low-cost and highly efficient catalysts for selective formic acid dehydrogenation, Adv. Mater. 30(2018) 1703038.
[20] M. Abbas, Y. Xue, J. Zhang, J. Chen, Ultrasound induced morphology-controlled synthesis of Au nanoparticles decorated on Fe₂O₃/ZrO₂ catalyst and their catalytic performance in Fischer-Tropsch synthesis, Fuel Process. Technol. 187(2019) 63-72.
[21] V.P. Vicentini, C. Ratnasamy, J. Braden, M.R. Purcell, M.K. Born, M.A. Logli, Iron oxide absorbent compositions, US Patent App. 15/701469, 2018.
[22] H. Shokrollahi, A review of the magnetic properties, synthesis methods and applications of maghemite, J. Magn. Magn. Mater. 426(2017) 74-81.
[23] C. Yu, X. Dong, L. Guo, J. Li, F. Qin, L. Zhang, J. Shi, D. Yan, Template-free preparation of mesoporous Fe₂O₃ and its application as absorbents, J. Phys. Chem. C 112(2008) 13378-13382.
[24] F. Nador, M.A. Volpe, F. Alonso, A. Feldhoff, A. Kirschning, G. Radivoy, Copper nanoparticles supported on silica coated maghemite as versatile, magnetically recoverable and reusable catalyst for alkyne coupling and cycloaddition reactions, Appl. Catal. A 455(2013) 39-45.
[25] Ö. Metin, S. Ho, C. Alp, H. Can, M. Mankin, M. Gültekin, M. Chi, S. Sun, Nano Res., 2013, 6, 10-18; (e) G, J. Chen, H.C. Ma, W.L. Xin, X.B. Li, F.Z. Jin, J.S. Wang, M.Y. Liu and Y.B. Dong, Inorg. Chem 56(2017) 654-660.
[26] M. Zhang, Y. Li, Z. Yan, J. Jing, J. Xie, M. Chen, Improved catalytic activity of cobalt core-platinum shell nanoparticles supported on surface functionalized graphene for methanol electro-oxidation, Electrochim. Acta 158(2015) 81-88.
[27] F.Y. Cheng, C.H. Su, Y.S. Yang, C.S. Yeh, C.Y. Tsai, C.L. Wu, M.T. Wu, D.B. Shieh, Characterization of aqueous dispersions of Fe₃O₄ nanoparticles and their biomedical applications, Biomaterials 26(2005) 729-738.
[28] K. Gopalsamy, J. Balamurugan, T.D. Thanh, N.H. Kim, D. Hui, J.H. Lee, Surfactant-free synthesis of NiPd nanoalloy/graphene bifunctional nanocomposite for fuel cell, Compos. B Eng. 114(2017) 319-327.
[29] Y. Koskun, A. Şavk, B. Şen, F. Şen, Highly sensitive glucose sensor based on monodisperse palladium nickel/activated carbon nanocomposites, Anal. Chim. Acta 1010(2018) 37-43.
[30] B. Sen, S. Kuzu, E. Demir, S. Akocak, F. Sen, Monodisperse palladium-nickel alloy nanoparticles assembled on graphene oxide with the high catalytic activity and reusability in the dehydrogenation of dimethylamine-borane, Int. J. Hydrogen Energy 42(2017) 23276-23283.
[31] H. Zhang, G. Zhu, One-step hydrothermal synthesis of magnetic Fe₃O₄ nanoparticles immobilized on polyamide fabric, Appl. Surf. Sci. 258(2012) 4952-4959.
[32] S. Ali, S.A. Khan, J. Eastoe, S.R. Hussaini, M.A. Morsy, Z.H. Yamani, Synthesis, characterization, and relaxometry studies of hydrophilic and hydrophobic superparamagnetic Fe₃O₄ nanoparticles for oil reservoir applications, Colloids Surf., A 543(2018) 133-143.
[33] L. Yang, X. Hua, J. Su, W. Luo, S. Chen, G. Cheng, Highly efficient hydrogen generation from formic acid-sodium formate over monodisperse AgPd nanoparticles at room temperature, Appl. Catal. B 168(2015) 423-428.
[34] K. Mandal, D. Bhattacharjee, S. Dasgupta, Synthesis of nanoporous PdAg nanoalloy for hydrogen generation from formic acid at room temperature, Int. J. Hydrogen Energy 40(2015) 4786-4793.
[35] Y.Y. Cai, X.H. Li, Y.N. Zhang, X. Wei, K.X. Wang, J.S. Chen, Highly efficient dehydrogenation of formic acid over a palladium-nanoparticle-based mottschottky photocatalyst, Angew. Chem. Int. Ed. 52(2013) 11822-11825.
[36] K. Koh, J.-E. Seo, J. Lee, A. Goswami, C. Yoon, T. Asefa, Ultrasmall palladium nanoparticles supported on amine-functionalized SBA-15 efficiently catalyze hydrogen evolution from formic acid, J. Mater. Chem. A 2(2014) 20444-20449.
[37] Z.-L. Wang, Y. Ping, J.-M. Yan, H.-L. Wang, Q. Jiang, Hydrogen generation from formic acid decomposition at room temperature using a NiAuPd alloy nanocatalyst, Int. J. Hydrogen Energy 39(2014) 4850-4856.
[38] Z.L. Wang, J.M. Yan, Y. Ping, H.L. Wang, W.T. Zheng, Q. Jiang, An efficient CoAuPd/C catalyst for hydrogen generation from formic acid at room temperature, Angew. Chem. Int. Ed. 52(2013) 4406-4409.
[39] X. Zhang, N. Shang, H. Shang, T. Du, X. Zhou, C. Feng, S. Gao, C. Wang, Z. Wang, Nitrogen-decorated porous carbon supported AgPd nanoparticles for boosting hydrogen generation from formic acid, Energy Technol. 7(2019) 140-145.

One-step synthesis of Ni@Pd/NH₂-Fe₃O₄ nanoparticles as affordable catalyst for formic acid dehydrogenation

One-step synthesis of Ni@Pd/NH₂-Fe₃O₄ nanoparticles as affordable catalyst for formic acid dehydrogenation

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