Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO2 electrodes: Preparation, characterization, optimization, application

doi:10.1016/j.cjche.2020.09.044

中国化学工程学报 ›› 2021, Vol. 32 ›› Issue (4): 191-202.DOI: 10.1016/j.cjche.2020.09.044

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO₂ electrodes: Preparation, characterization, optimization, application

Zhen Wei^1,2, Xuanqi Kang¹, Shangyuan Xu¹, Xiaokang Zhou¹, Bo Jia¹, Qing Feng^1,2

1 Xi'an TaiJin Industrial Electrochemical Technology CO., Ltd, Xi'an 710016, China;
2 Key Laboratory of Porous Metal Materials, Shaanxi Institute for Materials Engineering, Northwest Institute for Non-ferrous Metal Research, Xi'an 710016, China

收稿日期:2020-02-07 修回日期:2020-08-29 出版日期:2021-04-28 发布日期:2021-06-19
通讯作者: Zhen Wei, Qing Feng
基金资助:
Thanks to the financial support from the Science and technology project of Shaanxi Province (2017ZDXM-GY-041).

Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO₂ electrodes: Preparation, characterization, optimization, application

Zhen Wei^1,2, Xuanqi Kang¹, Shangyuan Xu¹, Xiaokang Zhou¹, Bo Jia¹, Qing Feng^1,2

1 Xi'an TaiJin Industrial Electrochemical Technology CO., Ltd, Xi'an 710016, China;
2 Key Laboratory of Porous Metal Materials, Shaanxi Institute for Materials Engineering, Northwest Institute for Non-ferrous Metal Research, Xi'an 710016, China

Received:2020-02-07 Revised:2020-08-29 Online:2021-04-28 Published:2021-06-19
Contact: Zhen Wei, Qing Feng
Supported by:
Thanks to the financial support from the Science and technology project of Shaanxi Province (2017ZDXM-GY-041).

摘要/Abstract

摘要： Regulation of the electronic structure and interface property becomes a major strategy in the preparation of electro-catalyst. This paper reports the synthesis of cerium (Ce) and sodium dodecyl benzene sulfonate (SDBS) co-modified Ti/PbO₂ electrodes (Ti/PbO₂-Ce-SDBS). Ce and SDBS could greatly change the electronic structure and interface property of PbO₂. Ti/PbO₂-Ce-SDBS exhibited excellent electrocatalytic activity and stability in Rhodamine B (RhB) electrocatalytic oxidation reaction. The improved electrocatalytic activity associates with the synergistic effect of electronic and interface factors. In the electrochemical degradation of RhB, the removal efficiencies of RhB and COD are about 0.880 and 0.694 respectively after the electrolysis of 220 min with Ti/PbO₂-Ce-4-SDBS-40, which are higher than the contrast Ti/PbO₂ electrodes. In the meantime, the accelerated lifetime of Ti/PbO₂-Ce-4-SDBS-40 is more than 6.2 times than that of Ti/PbO₂.

关键词: Ti/PbO₂ electrodes, Electrocatalytic oxidation

Abstract: Regulation of the electronic structure and interface property becomes a major strategy in the preparation of electro-catalyst. This paper reports the synthesis of cerium (Ce) and sodium dodecyl benzene sulfonate (SDBS) co-modified Ti/PbO₂ electrodes (Ti/PbO₂-Ce-SDBS). Ce and SDBS could greatly change the electronic structure and interface property of PbO₂. Ti/PbO₂-Ce-SDBS exhibited excellent electrocatalytic activity and stability in Rhodamine B (RhB) electrocatalytic oxidation reaction. The improved electrocatalytic activity associates with the synergistic effect of electronic and interface factors. In the electrochemical degradation of RhB, the removal efficiencies of RhB and COD are about 0.880 and 0.694 respectively after the electrolysis of 220 min with Ti/PbO₂-Ce-4-SDBS-40, which are higher than the contrast Ti/PbO₂ electrodes. In the meantime, the accelerated lifetime of Ti/PbO₂-Ce-4-SDBS-40 is more than 6.2 times than that of Ti/PbO₂.

Key words: Ti/PbO₂ electrodes, Electrocatalytic oxidation

Zhen Wei, Xuanqi Kang, Shangyuan Xu, Xiaokang Zhou, Bo Jia, Qing Feng. Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO₂ electrodes: Preparation, characterization, optimization, application[J]. 中国化学工程学报, 2021, 32(4): 191-202.

参考文献

[1] M.M. Wang, Z. Wei, L. Xu, B. Liu, H. Jiao, Two temperature-controlled zinc coordination polymers:ionothermal synthesis, properties, and dye adsorption, Eur. J. Inorg. Chem. 7(2018) 932-939.
[2] Y.F. Cheng, Q. Cao, J. Zhang, T. Wu, R. Che, Efficient photodegradation of dye pollutants using a novel plasmonic AgCl microrods array and photo-optimized surface-enhanced Raman scattering, Appl. Catal. B:Environ. 217(2017) 37-47.
[3] S.S.F. Carvalho, N.M.F. Carvalho, Dye degradation by green heterogeneous Fenton catalysts prepared in presence of Camellia sinensis, J. Environ. Manage. 187(2017) 82-88.
[4] W. Yan, L.J. Han, H.L. Jia, K. Shen, T. Wang, H.G. Zheng, Three highly stable cobalt MOFs based on "Y"-shaped carboxylic acid:Synthesis and absorption of anionic dyes, Inorg. Chem. 55(2016) 8816-8821.
[5] Y. Jia, Y. Wen, X. Han, J. Qi, Z. Liu, S. Zhang, G. Li, Electrocatalytic degradation of rice straw lignin in alkaline solution through oxidation on a Ti/SnO₂-Sb₂O₃/α-PbO₂/β-PbO₂ anode and reduction on an iron or tin doped titanium cathode, Catal. Sci. Technol. 8(2018) 4665-4677.
[6] O. Shmychkova, T. Luk'yanenko, R. Amadelli, A. Velichenko, Electrodeposition of Ce-doped PbO₂, J. Electroanal. Chem. 706(2013) 86-92.
[7] Y. Li, C. Zhao, Enhancing water oxidation catalysis on a synergistic phosphorylated nife hydroxide by adjusting catalyst wettability, ACS. Catal. 7(2017) 2535-2541.
[8] M. Liang, J. Chen, Arylamine organic dyes for dye-sensitized solar cells, Chem. Soc. Rev. 42(2013) 3453-3488.
[9] Q. Qiao, S. Singh, S.L. Lo, Y. Li, J. Jin, L. Wang, Electrochemical oxidation of acid orange 7 dye with Ce, Nd, and Co-modified PbO₂ electrodes:Preparation, characterization, optimization, and mineralization, J. Taiwan. Inst. Chem. E. 84(2018) 110-122.
[10] T.É.S. Santos, R.S. Silva, C.T. Meneses, C.A. Martínez-Huitle, K.I.B. Eguiluz, G.R. Salazar-Banda, Unexpected enhancement of electrocatalytic nature of Ti/(RuO₂)x-(Sb₂O₅)y anodes prepared by the ionic liquid-thermal decomposition method, Ind. En. Chem. Res. 55(2016) 3182-3187.
[11] C.A.M. Inez-Huitle, A.D. Battisti, S. Ferro, S. Reyna, M.O. Cerro-L, M.A. Quiro, Removal of the pesticide methamidophos from aqueous solutions by electrooxidation using Pb-PbO₂, Ti-SnO₂, and Si-BDD electrodes, Environ. Sci. Technol 42(2008) 6929-6935.
[12] C. Zhang, J. Liu, B. Chen, Effect of CeO₂ and graphite powder on the electrochemical performance of Ti/PbO₂ anode for zinc electrowinning, Ceram. Int. 44(2018) 19735-19742.
[13] J. Lyu, H. Han, Q. Wu, H. Ma, C. Ma, X. Dong, Y. Fu, Enhancement of the electrocatalytic oxidation of dyeing wastewater (reactive brilliant blue KN-R) over the Ce-doped Ti-PbO₂ electrode with surface hydrophobicity, J. Solid. State. Chem. 23(2019) 847-859.
[14] X. Duan, F. Xu, Y. Wang, Y. Chen, L. Chang, Fabrication of a hydrophobic SDBSPbO₂ anode for electrochemical degradation of nitrobenzene in aqueous solution, Electrochim. Acta 282(2018) 662-671.
[15] X. Duan, X. Sui, W. Wang, W. Bai, L. Chang, Fabrication of PbO₂/SnO₂ composite anode for electrochemical degradation of 3-chlorophenol in aqueous solution, Appl. Surf. Sci. 494(2019) 211-222.
[16] X. Sui, X. Duan, F. Xu, L. Chang, Fabrication of three-dimensional networked PbO₂ anode for electrochemical oxidation of organic pollutants in aqueous solution, J. Taiwan. Inst. Chem. E 100(2019) 74-84.
[17] F. Xu, L. Chang, X. Duan, W. Bai, X. Sui, X. Zhao, A novel layer-by-layer CNTPbO₂ anode for high-efficiency removal of PCP-Na through combining adsorption-electrosorption and electrocatalysis, Electrochim. Acta 300(2019) 53-66.
[18] Z. Wang, M. Xu, F. Wang, X. Liang, Y. Wei, Y. Hu, C.G. Zhu, W. Fang, Preparation and characterization of a novel Ce doped PbO₂ electrode based on NiO doped Ti/TiO₂NTs substrate for the electrocatalytic degradation of phenol wastewater, Electrochim. Acta 247(2017) 535-547.
[19] X. Hu, Y. Yu, L. Yang, Electrocatalytic activity of Ce-PbO₂/C anode for acid red B reduction in aqueous solution, J. Solid State Electr. 19(2015) 1599-1609.
[20] H.B. Yu, Y.N. Song, B. Zhao, Y. Lu, S.Y. Zhu, J. Qu, X.H. Wang, W.C. Qin, Efficient electrocatalytic degradation of 4-Chlorophenol using a Ti/RuO₂-SnO₂-TiO₂/PbO₂-CeO₂ composite electrode, Electrocatalysis 9(2018) 725-734.
[21] Y.W. Yao, L.M. Jiao, L.H. Cui, N.C. Yu, F. Wei, Z.M. Lu, Preparation and characterization of PbO₂-CeO₂ nanocomposite electrode with high Ce content and its appplication in the electrocatalytic degradation of malachite green, J. Electrochem. Soc. 162(2015) H693-H698.
[22] X. Li, D. Pletcher, F.C. Walsh, Electrodeposited lead dioxide coatings, Chem. Soc. Rev. 40(2011) 3879-3894.
[23] Q. Li, Q. Zhang, H. Cui, L. Ding, Z. Wei, J. Zhai, Fabrication of Ce-doped lead dioxide anode with improved electrocatalytic activity and its application for removal of rhodamine B, Chem. Eng. J. 228(2013) 806-814.
[24] S. Ai, M. Gao, W. Zhang, Q. Wang, Y. Xie, L. Jin, Preparation of Ce-PbO₂ doped electrode and its application in detection of anilines, Talanta 62(2004) 445-450.
[25] C.A. Basha, R. Saravanathamizhan, V. Nandakumar, K. Chitra, C.W. Lee, Copper recovery and simultaneous COD removal from copper phthalocyanine dye effluent using bipolar disc reactor, Chem. Eng. Res. Des. 91(2011) 552-559.
[26] G. Zhao, Y. Zhang, Y. Lei, B. Lv, J. Gao, Y. Zhang, D. Li, Fabrication and electrochemical treatment application of a novel lead dioxide anode with superhydrophobic surfaces, high oxygen evolution potential, and oxidation capability, Environ. Sci. Technol. 44(2010) 1754-1759.

Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO₂ electrodes: Preparation, characterization, optimization, application

Electrochemical oxidation of Rhodamine B with cerium and sodium dodecyl benzene sulfonate co-modified Ti/PbO₂ electrodes: Preparation, characterization, optimization, application

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价