SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2021, Vol. 32 ›› Issue (4): 472-484.DOI: 10.1016/j.cjche.2020.09.071

• Materials and Product Engineering • 上一篇    下一篇

Synthesis and optimization of high surface area mesoporous date palm fiber-based nanostructured powder activated carbon for aluminum removal

Alfarooq O. Basheer1, Marlia M. Hanafiah1,2, Mohammed Abdulhakim Alsaadi3,4, Y. Al-Douri3,5,6, Abbas A. Al-Raad1   

  1. 1 Department of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia;
    2 Centre for Tropical Climate Change System, Institute of Climate Change, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor, Malaysia;
    3 Nanotechnology and Catalysis Research Center(NANOCAT), University of Malaya, 50603 Kuala Lumpur, Malaysia;
    4 National Chair of Materials Science and Metallurgy, University of Nizwa, 611 Nizawa, Oman;
    5 University Research Center, Cihan University Sulaimaniya, Sulaymaniyah 46002, Iraq;
    6 Department of Mechatronics Engineering, Faculty of Engineering and Natural Sciences, Bahcesehir University, 34349 Besiktas, Istanbul, Turkey
  • 收稿日期:2020-05-15 修回日期:2020-09-07 出版日期:2021-04-28 发布日期:2021-06-19
  • 通讯作者: Alfarooq O. Basheer, Y. Al-Douri
  • 基金资助:
    The authors gratefully acknowledge Universiti Kebangsaan Malaysia and Universiti of Malaya for technical measurements support.

Synthesis and optimization of high surface area mesoporous date palm fiber-based nanostructured powder activated carbon for aluminum removal

Alfarooq O. Basheer1, Marlia M. Hanafiah1,2, Mohammed Abdulhakim Alsaadi3,4, Y. Al-Douri3,5,6, Abbas A. Al-Raad1   

  1. 1 Department of Earth Sciences and Environment, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia;
    2 Centre for Tropical Climate Change System, Institute of Climate Change, Universiti Kebangsaan Malaysia, Bangi 43600, Selangor, Malaysia;
    3 Nanotechnology and Catalysis Research Center(NANOCAT), University of Malaya, 50603 Kuala Lumpur, Malaysia;
    4 National Chair of Materials Science and Metallurgy, University of Nizwa, 611 Nizawa, Oman;
    5 University Research Center, Cihan University Sulaimaniya, Sulaymaniyah 46002, Iraq;
    6 Department of Mechatronics Engineering, Faculty of Engineering and Natural Sciences, Bahcesehir University, 34349 Besiktas, Istanbul, Turkey
  • Received:2020-05-15 Revised:2020-09-07 Online:2021-04-28 Published:2021-06-19
  • Contact: Alfarooq O. Basheer, Y. Al-Douri
  • Supported by:
    The authors gratefully acknowledge Universiti Kebangsaan Malaysia and Universiti of Malaya for technical measurements support.

摘要: Date palm fiber (DPF) derived from agrowaste was utilized as a new precursor for the optimized synthesis of a cost-effective, nanostructured, powder-activated carbon (nPAC) for aluminum (Al3+) removal from aqueous solutions using carbonization, KOH activation, response surface methodology (RSM) and central composite design (CCD). The optimum synthesis condition, activation temperature, time and impregnation ratio were found to be 650℃, 1.09 hour and 1:1, respectively. Furthermore, the optimum conditions for removal were 99.5% and 9.958 mg·g-1 in regard to uptake capacity. The optimum conditions of nPAC was analyzed and characterized using XRD, FTIR, FESEM, BET, TGA and Zeta potential. Moreover, the adsorption of the Al3+ conditions was optimized with an integrated RSM-CCD experimental design. Regression results revealed that the adsorption kinetics data was well fitted by the pseudo-second order model, whereas the adsorption isotherm data was best represented by the Freundlich isotherm model. Optimum activated carbon indicated that DPF can serve as a cost-effective precursor adsorbent for Al3+ removal.

关键词: Agricultural waste, Nanocomposites, Wastewater treatment, Industrial applications

Abstract: Date palm fiber (DPF) derived from agrowaste was utilized as a new precursor for the optimized synthesis of a cost-effective, nanostructured, powder-activated carbon (nPAC) for aluminum (Al3+) removal from aqueous solutions using carbonization, KOH activation, response surface methodology (RSM) and central composite design (CCD). The optimum synthesis condition, activation temperature, time and impregnation ratio were found to be 650℃, 1.09 hour and 1:1, respectively. Furthermore, the optimum conditions for removal were 99.5% and 9.958 mg·g-1 in regard to uptake capacity. The optimum conditions of nPAC was analyzed and characterized using XRD, FTIR, FESEM, BET, TGA and Zeta potential. Moreover, the adsorption of the Al3+ conditions was optimized with an integrated RSM-CCD experimental design. Regression results revealed that the adsorption kinetics data was well fitted by the pseudo-second order model, whereas the adsorption isotherm data was best represented by the Freundlich isotherm model. Optimum activated carbon indicated that DPF can serve as a cost-effective precursor adsorbent for Al3+ removal.

Key words: Agricultural waste, Nanocomposites, Wastewater treatment, Industrial applications