Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO2 catalytic conversion

doi:10.1016/j.cjche.2020.12.019

中国化学工程学报 ›› 2021, Vol. 40 ›› Issue (12): 124-130.DOI: 10.1016/j.cjche.2020.12.019

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

Bo-Yun Liu¹, Min-Jie Chen², Liang Yang^1,2, Bo Zhao^1,2, Tao Xia², Gang-Gang Chang²

1. School of Power Engineering, Naval University of Engineering, Wuhan 430033, China;
2. School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China

收稿日期:2020-07-14 修回日期:2020-11-22 出版日期:2021-12-28 发布日期:2022-01-14
通讯作者: Bo Zhao,E-mail:1031162667@qq.com;Gang-Gang Chang,E-mail:changgang2016@whut.edu.cn
基金资助:
This work was supported by National Natural Science Foundation of China (21706199, U1662134, 5181101338). This study was also supported by National Key Research and Development Program of China (2017YFC1103800).

Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

Bo-Yun Liu¹, Min-Jie Chen², Liang Yang^1,2, Bo Zhao^1,2, Tao Xia², Gang-Gang Chang²

1. School of Power Engineering, Naval University of Engineering, Wuhan 430033, China;
2. School of Chemistry, Chemical Engineering and Life Science, Wuhan University of Technology, Wuhan 430070, China

Received:2020-07-14 Revised:2020-11-22 Online:2021-12-28 Published:2022-01-14
Contact: Bo Zhao,E-mail:1031162667@qq.com;Gang-Gang Chang,E-mail:changgang2016@whut.edu.cn
Supported by:
This work was supported by National Natural Science Foundation of China (21706199, U1662134, 5181101338). This study was also supported by National Key Research and Development Program of China (2017YFC1103800).

摘要/Abstract

摘要： The engineering of highly efficient and stable heterogeneous catalysts for catalytic conversion of CO₂ to high value-added products is highly desirable but presents a great challenge. Herein, we reported the synthesis of a series of multifunctional IL@H-Zn/Co-ZIF composite catalysts with a unique porous hollow capsule structure and encapsulated amino-functionalized ionic liquids (ILs). The unique hollow capsule structure of IL@H-Zn/Co-ZIF provides sufficient space for loading active ILs ([C₂NH₂Mim⁺][Br^-]) and fast mass transfer of substrate molecules during catalysis. Furthermore, the microporous Zn-ZIF shell can effectively avoid the leaching of active ILs. Benefiting from the unique hollow structure, the resultant IL@H-Zn/Co-ZIF demonstrated excellent catalytic performance (>95% yield), and good recyclability (still remained about 90% activities after 5 cycles) when applied in the CO₂ cycloaddition reaction under solvent and co-catalyst free conditions.

关键词: MOFs, Catalyst, Hollow capsule, CO₂ capture, Ionic liquids

Abstract: The engineering of highly efficient and stable heterogeneous catalysts for catalytic conversion of CO₂ to high value-added products is highly desirable but presents a great challenge. Herein, we reported the synthesis of a series of multifunctional IL@H-Zn/Co-ZIF composite catalysts with a unique porous hollow capsule structure and encapsulated amino-functionalized ionic liquids (ILs). The unique hollow capsule structure of IL@H-Zn/Co-ZIF provides sufficient space for loading active ILs ([C₂NH₂Mim⁺][Br^-]) and fast mass transfer of substrate molecules during catalysis. Furthermore, the microporous Zn-ZIF shell can effectively avoid the leaching of active ILs. Benefiting from the unique hollow structure, the resultant IL@H-Zn/Co-ZIF demonstrated excellent catalytic performance (>95% yield), and good recyclability (still remained about 90% activities after 5 cycles) when applied in the CO₂ cycloaddition reaction under solvent and co-catalyst free conditions.

Key words: MOFs, Catalyst, Hollow capsule, CO₂ capture, Ionic liquids

Bo-Yun Liu, Min-Jie Chen, Liang Yang, Bo Zhao, Tao Xia, Gang-Gang Chang. Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion[J]. 中国化学工程学报, 2021, 40(12): 124-130.

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Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

Hollow MOF capsule encapsulated amino-functionalized ionic liquid for excellent CO₂ catalytic conversion

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