Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans

doi:10.1016/j.cjche.2021.10.009

中国化学工程学报 ›› 2022, Vol. 41 ›› Issue (1): 457-465.DOI: 10.1016/j.cjche.2021.10.009

• Biotechnology and Bioengineering • 上一篇下一篇

Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans

Chunxiao Zhao, Baojun Yang, Rui Liao, Maoxin Hong, Shichao Yu, Jun Wang, Guanzhou Qiu

Key Laboratory of Biohydrometallurgy of Ministry of Education, School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China

收稿日期:2021-06-30 修回日期:2021-09-18 出版日期:2022-01-28 发布日期:2022-02-25
通讯作者: Jun Wang,E-mail address:wjwq2000@126.com
基金资助:
This work was supported by the National Natural Science Foundation of China (51774332, 51934009, U1932129), Fundamental Research Funds for the Central Universities of Central South University (2021zzts0299) and the college students innovations special project funded by Hunan province (S2021105330471).

Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans

Chunxiao Zhao, Baojun Yang, Rui Liao, Maoxin Hong, Shichao Yu, Jun Wang, Guanzhou Qiu

Key Laboratory of Biohydrometallurgy of Ministry of Education, School of Minerals Processing & Bioengineering, Central South University, Changsha 410083, China

Received:2021-06-30 Revised:2021-09-18 Online:2022-01-28 Published:2022-02-25
Contact: Jun Wang,E-mail address:wjwq2000@126.com
Supported by:
This work was supported by the National Natural Science Foundation of China (51774332, 51934009, U1932129), Fundamental Research Funds for the Central Universities of Central South University (2021zzts0299) and the college students innovations special project funded by Hunan province (S2021105330471).

摘要/Abstract

摘要： The bioleaching of chalcopyrite is low cost and environmentally friendly, but the leaching rate is low. To explore the mechanism of chalcopyrite bioleaching and improve its leaching rate, the effect and mechanism of manganese ions (Mn²⁺) and visible light on chalcopyrite mediated by Acidithiobacillus ferrooxidans (A. ferrooxidans) were discussed. Bioleaching experiments showed that when both Mn²⁺ and visible light were present, the copper extraction was 14.38% higher than that of the control system (without Mn²⁺ and visible light). Moreover, visible light and Mn²⁺ promoted the growth of A. ferrooxidans. Scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) analysis revealed that Mn²⁺ promoted the formation of extracellular polymeric substance (EPS) on the surface of chalcopyrite, changed the morphology of A. ferrooxidans, enhanced the adsorption of bacteria on chalcopyrite surface with light illumination, and thus promoted the bioleaching of chalcopyrite. UV–vis absorbance spectra indicated that Mn²⁺ promoted the response of chalcopyrite to visible light and enhanced the catalytic effect of visible light on chalcopyrite bioleaching. Based on X-ray photoelectron spectroscopy (XPS), the relevant sulfur speciation of chalcopyrite before and after bioleaching were analyzed and the results revealed that visible light and Mn²⁺ promoted chalcopyrite bioleaching by reducing the formation of passivation layer (S_n^2-/S⁰). Investigation into electrochemical results further indicated that Mn²⁺ and visible light improved the electrochemical activity of chalcopyrite, thus increasing the bioleaching rate.

关键词: Acidithiobacillus ferrooxidans, Mn²⁺, Electrochemistry, Catalysis, Dissolution

Abstract: The bioleaching of chalcopyrite is low cost and environmentally friendly, but the leaching rate is low. To explore the mechanism of chalcopyrite bioleaching and improve its leaching rate, the effect and mechanism of manganese ions (Mn²⁺) and visible light on chalcopyrite mediated by Acidithiobacillus ferrooxidans (A. ferrooxidans) were discussed. Bioleaching experiments showed that when both Mn²⁺ and visible light were present, the copper extraction was 14.38% higher than that of the control system (without Mn²⁺ and visible light). Moreover, visible light and Mn²⁺ promoted the growth of A. ferrooxidans. Scanning electron microscopy (SEM) and energy dispersive spectrometer (EDS) analysis revealed that Mn²⁺ promoted the formation of extracellular polymeric substance (EPS) on the surface of chalcopyrite, changed the morphology of A. ferrooxidans, enhanced the adsorption of bacteria on chalcopyrite surface with light illumination, and thus promoted the bioleaching of chalcopyrite. UV–vis absorbance spectra indicated that Mn²⁺ promoted the response of chalcopyrite to visible light and enhanced the catalytic effect of visible light on chalcopyrite bioleaching. Based on X-ray photoelectron spectroscopy (XPS), the relevant sulfur speciation of chalcopyrite before and after bioleaching were analyzed and the results revealed that visible light and Mn²⁺ promoted chalcopyrite bioleaching by reducing the formation of passivation layer (S_n^2-/S⁰). Investigation into electrochemical results further indicated that Mn²⁺ and visible light improved the electrochemical activity of chalcopyrite, thus increasing the bioleaching rate.

Key words: Acidithiobacillus ferrooxidans, Mn²⁺, Electrochemistry, Catalysis, Dissolution

Chunxiao Zhao, Baojun Yang, Rui Liao, Maoxin Hong, Shichao Yu, Jun Wang, Guanzhou Qiu. Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans[J]. 中国化学工程学报, 2022, 41(1): 457-465.

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Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans

Catalytic mechanism of manganese ions and visible light on chalcopyrite bioleaching in the presence of Acidithiobacillus ferrooxidans

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