Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

doi:10.1016/j.cjche.2021.11.011

中国化学工程学报 ›› 2022, Vol. 41 ›› Issue (1): 480-487.DOI: 10.1016/j.cjche.2021.11.011

• Energy Science and Technology • 上一篇下一篇

Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Tao Zhao, Dazhong Zhong, Genyan Hao, Guang Liu, Jinping Li, Qiang Zhao

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

收稿日期:2021-06-27 修回日期:2021-11-18 出版日期:2022-01-28 发布日期:2022-02-25
通讯作者: Qiang Zhao,E-mail address:zhaoqiang@tyut.edu.cn
基金资助:
The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (21878202, 21975175), and the Natural Science Foundation of Shanxi Province (201801D121052).

Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Tao Zhao, Dazhong Zhong, Genyan Hao, Guang Liu, Jinping Li, Qiang Zhao

Shanxi Key Laboratory of Gas Energy Efficient and Clean Utilization, College of Chemistry and Chemical Engineering, Taiyuan University of Technology, Taiyuan 030024, China

Received:2021-06-27 Revised:2021-11-18 Online:2022-01-28 Published:2022-02-25
Contact: Qiang Zhao,E-mail address:zhaoqiang@tyut.edu.cn
Supported by:
The authors gratefully acknowledge financial support from the National Natural Science Foundation of China (21878202, 21975175), and the Natural Science Foundation of Shanxi Province (201801D121052).

摘要/Abstract

摘要： Metal-organic frameworks (MOFs) exhibit excellent application potential in the field of electrocatalysis. In this study, we first prepare MIL-100 nanosheets on nickel foam (MIL-100/NF) and then successfully anchor Ag nanoparticles (NPs) on the nanosheets (Ag@MIL-100/NF) for oxygen evolution reaction (OER) catalysis. This strategy dramatically improves the conductivity of MIL-100 and the Ag NPs are uniformly dispersed on the nanosheets. The Ag@MIL-100/NF catalyst has excellent electrocatalytic performance and long-term corrosion resistance, with a low overpotential of 207 mV and a long-term stability of at least 100 h at a current density of 50 mA·cm^-2. The experimental results demonstrate that this high OER catalytic performance is due to the improved charge transfer after loading Ag NPs, the combination of nanosheets and highly dispersed Ag NPs that expose more active sites and the adjusted chemical valence states of Fe and Ni in MIL-100. This work provides a surface decoration approach for the preparation of excellent catalysts directly used in the OER.

关键词: Ag@MIL-100/NF, Metal–organic frameworks, Catalysis, Kinetics, Overpotential, Electrochemistry

Abstract: Metal-organic frameworks (MOFs) exhibit excellent application potential in the field of electrocatalysis. In this study, we first prepare MIL-100 nanosheets on nickel foam (MIL-100/NF) and then successfully anchor Ag nanoparticles (NPs) on the nanosheets (Ag@MIL-100/NF) for oxygen evolution reaction (OER) catalysis. This strategy dramatically improves the conductivity of MIL-100 and the Ag NPs are uniformly dispersed on the nanosheets. The Ag@MIL-100/NF catalyst has excellent electrocatalytic performance and long-term corrosion resistance, with a low overpotential of 207 mV and a long-term stability of at least 100 h at a current density of 50 mA·cm^-2. The experimental results demonstrate that this high OER catalytic performance is due to the improved charge transfer after loading Ag NPs, the combination of nanosheets and highly dispersed Ag NPs that expose more active sites and the adjusted chemical valence states of Fe and Ni in MIL-100. This work provides a surface decoration approach for the preparation of excellent catalysts directly used in the OER.

Key words: Ag@MIL-100/NF, Metal–organic frameworks, Catalysis, Kinetics, Overpotential, Electrochemistry

Tao Zhao, Dazhong Zhong, Genyan Hao, Guang Liu, Jinping Li, Qiang Zhao. Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance[J]. 中国化学工程学报, 2022, 41(1): 480-487.

参考文献

[1] X.J. Wei, Y.H. Zhang, H.C. He, D. Gao, J.R. Hu, H.R. Peng, L. Peng, S.H. Xiao, P. Xiao, Carbon-incorporated NiO/Co₃O₄ concave surface microcubes derived from a MOF precursor for overall water splitting, Chem. Commun. 55(46) (2019) 6515–6518.
[2] X. Mao, C.Y. Ling, C. Tang, C. Yan, Z.H. Zhu, A.J. Du, Predicting a new class of metal-organic frameworks as efficient catalyst for bi-functional oxygen evolution/reduction reactions, J. Catal. 367(2018) 206–211.
[3] T. Liu, P. Li, N. Yao, T. Kong, G. Cheng, S. Chen, W. Luo, Self-sacrificial templatedirected vapor-phase growth of MOF assemblies and surface vulcanization for efficient water splitting, Adv. Mater. 31(21) (2019) e1806672.
[4] C.P. Wang, H.Y. Liu, G. Bian, X. Gao, S. Zhao, Y. Kang, J. Zhu, X.H. Bu, Metal-layer assisted growth of ultralong quasi-2D MOF nanoarrays on arbitrary substrates for accelerated oxygen evolution, Small 15(51) (2019) e1906086.
[5] C.F. Zhang, Z.W. Chen, Y.B. Lian, Y.J. Chen, Q. Li, Y.D. Gu, Y.T. Lu, Z. Deng, Y. Peng, Copper-based conductive metal organic framework In-situ grown on copper foam as a bifunctional electrocatalyst, Acta Phys. –Chim. Sin. 35(12) (2019) 1404–1411.
[6] X.X. Li, P.Y. Zhu, Q. Li, Y.X. Xu, Y. Zhao, H. Pang, Nitrogen-, phosphorus-doped carbon-carbon nanotube CoP dodecahedra by controlling zinc content for high-performance electrocatalytic oxygen evolution, Rare Met. 39(6) (2020) 680–687.
[7] D. Wu, Y.C. Wei, X. Ren, X.Q. Ji, Y.W. Liu, X.D. Guo, Z.A. Liu, A.M. Asiri, Q. Wei, X. P. Sun, Co(OH)2 nanoparticle-encapsulating conductive nanowires array: Room-temperature electrochemical preparation for high-performance water oxidation electrocatalysis, Adv. Mater. 30(9) (2018) 1705366.
[8] X.Z. Li, Y.Y. Fang, X.Q. Lin, M. Tian, X.C. An, Y. Fu, R. Li, J. Jin, J.T. Ma, MOF derived Co₃O₄ nanoparticles embedded in N-doped mesoporous carbon layer/MWCNT hybrids: Extraordinary bi-functional electrocatalysts for OER and ORR, J. Mater. Chem. A 3(33) (2015) 17392–17402.
[9] Q. Wang, F.Y. Liu, C.C. Wei, D.D. Li, W.J. Guo, Q. Zhao, High efficiency FeNimetal-organic framework grown in situ on nickel foam for electrocatalytic oxygen evolution, ChemistrySelect 4(19) (2019) 5988–5994.
[10] K. Srinivas, Y.J. Lu, Y.F. Chen, W.L. Zhang, D.X. Yang, FeNi₃–Fe₃O₄ heterogeneous nanoparticles anchored on 2D MOF nanosheets/1D CNT matrix as highly efficient bifunctional electrocatalysts for water splitting, ACS Sustainable Chem. Eng. 8(9) (2020) 3820–3831.
[11] R.W. Liang, F.F. Jing, L.J. Shen, N. Qin, L. Wu, M@MIL-100(Fe) (M = Au, Pd, Pt) nanocomposites fabricated by a facile photodeposition process: Efficient visible-light photocatalysts for redox reactions in water, Nano Res. 8(10) (2015) 3237–3249.
[12] Y.Q. Han, H.T. Xu, Y.Q. Su, Z.L. Xu, K.F. Wang, W.Z. Wang, Noble metal (Pt, Au@Pd) nanoparticles supported on metal organic framework (MOF-74) nanoshuttles as high-selectivity CO₂ conversion catalysts, J. Catal. 370(2019) 70–78.
[13] B. Ye, R.H. Jiang, Z.B. Yu, Y.P. Hou, J. Huang, B.G. Zhang, Y.Y. Huang, Y.L. Zhang, R.Z. Zhang, Pt (11 1) quantum dot engineered Fe-MOF nanosheet arrays with porous core-shell as an electrocatalyst for efficient overall water splitting, J. Catal. 380(2019) 307–317.
[14] X.Y. Li, G.X. Zhu, L.S. Xiao, Y.J. Liu, Z.Y. Ji, X.P. Shen, L.R. Kong, S.A. Shah, Loading of Ag on Fe-Co-S/N-doped carbon nanocomposite to achieve improved electrocatalytic activity for oxygen evolution reaction, J. Alloys Compd. 773(2019) 40–49.
[15] X. Ding, Y. Xia, Q. Li, S. Dong, X. Jiao, D. Chen, Interface engineering of Co(OH)2/Ag/FeP hierarchical superstructure as efficient and robust electrocatalyst for overall water splitting, ACS Appl. Mater. Interfaces 11(8) (2019) 7936–7945.
[16] R.H. Dong, H.R. Du, Y.X. Sun, K.F. Huang, W. Li, B.Y. Geng, Selective reduction–oxidation strategy to the conductivity-enhancing Ag-decorated Co-based 2D hydroxides as efficient electrocatalyst in oxygen evolution reaction, ACS Sustainable Chem. Eng. 6(10) (2018) 13420–13426.
[17] F.Z. Sun, G. Wang, Y.Q. Ding, C. Wang, B.B. Yuan, Y.Q. Lin, NiFe-based metalorganic framework nanosheets directly supported on nickel foam acting as robust electrodes for electrochemical oxygen evolution reaction, Adv. Energy Mater. 8(21) (2018) 1800584.1–1800584.11, https://doi.org/10.1002/aenm.201800584.
[18] H. Dong, X. Zhang, X.C. Yan, Y.X. Wang, X.J. Sun, G.L. Zhang, Y.J. Feng, F.M. Zhang, Mixed-metal-cluster strategy for boosting electrocatalytic oxygen evolution reaction of robust metal-organic frameworks, ACS Appl. Mater. Interfaces 11(48) (2019) 45080–45086.
[19] J.W. Zhang, G.P. Lu, C. Cai, Self-hydrogen transfer hydrogenolysis of b-O-4 linkages in lignin catalyzed by MIL-100(Fe) supported Pd–Ni BMNPs, Green Chem. 19(19) (2017) 4538–4543.
[20] J.J. Duan, S. Chen, C. Zhao, Ultrathin metal-organic framework array for efficient electrocatalytic water splitting, Nat. Commun. 8(1) (2017) 1–7.
[21] Q. Wang, C.C. Wei, D.D. Li, W.J. Guo, D.Z. Zhong, Q. Zhao, FeNi-based bimetallic MIL-101 directly applicable as an efficient electrocatalyst for oxygen evolution reaction, Microporous Mesoporous Mater. 286(2019) 92–97.
[22] L. Yu, J.F. Yang, B.Y. Guan, Y. Lu, X.W.D. Lou, Hierarchical hollow nanoprisms based on ultrathin Ni-Fe layered double hydroxide nanosheets with enhanced electrocatalytic activity towards oxygen evolution, Angew. Chem. Int. Ed. Engl. 57(1) (2018) 172–176.
[23] X.D. Du, X.H. Yi, P. Wang, J.G. Deng, C.C. Wang, Enhanced photocatalytic Cr(VI) reduction and diclofenac sodium degradation under simulated sunlight irradiation over MIL-100(Fe)/g-C₃N₄ heterojunctions, Chin. J. Catal. 40(1) (2019) 70–79.
[24] X.F. Zhang, L. Chang, Z.J. Yang, Y.N. Shi, C. Long, J.Y. Han, B.H. Zhang, X.Y. Qiu, G. D. Li, Z.Y. Tang, Facile synthesis of ultrathin metal-organic framework nanosheets for Lewis acid catalysis, Nano Res. 12(2) (2019) 437–440.
[25] N.N. Zhu, X.H. Liu, T. Li, J.G. Ma, P. Cheng, G.M. Yang, Composite system of Ag nanoparticles and metal–organic frameworks for the capture and conversion of carbon dioxide under mild conditions, Inorg. Chem. 56(6) (2017) 3414–3420.
[26] R. Canioni, C. Roch-Marchal, F. Sécheresse, P. Horcajada, C. Serre, M. Hardi-Dan, G. Férey, J.M. Grenèche, F. Lefebvre, J.S. Chang, Y.K. Hwang, O. Lebedev, S. Turner, G. van Tendeloo, Stable polyoxometalate insertion within the mesoporous metal organic framework MIL-100(Fe), J. Mater. Chem. 21(4) (2011) 1226–1233.
[27] M.F. Qiao, Y. Wang, L. Li, G.Z. Hu, G.A. Zou, X. Mamat, Y.M. Dong, X. Hu, Selftemplated nitrogen-doped mesoporous carbon decorated with double transition-metal active sites for enhanced oxygen electrode catalysis, Rare Met. 39(7) (2020) 824–833.
[28] Z.C. Wu, Z.X. Zou, J.S. Huang, F. Gao, Fe-doped NiO mesoporous nanosheets array for highly efficient overall water splitting, J. Catal. 358(2018) 243–252.
[29] J. Zhang, L. Yu, Y. Chen, X.F. Lu, S. Gao, X.W.D. Lou, Designed formation of double-shelled Ni-Fe layered-double-hydroxide nanocages for efficient oxygen evolution reaction, Adv. Mater. 32(16) (2020) e1906432.
[30] X.Q. Ji, B.P. Liu, X. Ren, X.F. Shi, A.M. Asiri, X.P. Sun, P-doped Ag nanoparticles embedded in N-doped carbon nanoflake: An efficient electrocatalyst for the hydrogen evolution reaction, ACS Sustainable Chem. Eng. 6(4) (2018) 4499–4503.
[31] C.Q. Meng, Y. Cao, Y.L. Luo, F. Zhang, Q.Q. Kong, A.A. Alshehri, K.A. Alzahrani, T. S. Li, Q. Liu, X.P. Sun, A Ni-MOF nanosheet array for efficient oxygen evolution electrocatalysis in alkaline media, Inorg. Chem. Front. 8(2021) 3007–3011.
[32] F.Q. Zheng, D. Xiang, P. Li, Z.W. Zhang, C. Du, Z.H. Zhuang, X.K. Li, W. Chen, Highly conductive bimetallic Ni–Fe metal organic framework as a novel electrocatalyst for water oxidation, ACS Sustainable Chem. Eng. 7(11) (2019) 9743–9749.
[33] Q. Wu, Q.P. Gao, L.M. Sun, H.M. Guo, X.S. Tai, D. Li, L. Liu, C.Y. Ling, X.P. Sun, Facilitating active species by decorating CeO₂ on Ni₃S₂ nanosheets for efficient water oxidation electrocatalysis, Chin. J. Catal. 42(3) (2021) 482–489.
[34] Y. Cao, T. Wang, X. Li, L.C. Zhang, Y.L. Luo, F. Zhang, A.M. Asiri, J.M. Hu, Q. Liu, X. P. Sun, A hierarchical CuO@NiCo layered double hydroxide core–shell nanoarray as an efficient electrocatalyst for the oxygen evolution reaction, Inorg. Chem. Front. 8(2021) 3049–3054.
[35] T. Shinagawa, A.T. Garcia-Esparza, K. Takanabe, Insight on Tafel slopes from a microkinetic analysis of aqueous electrocatalysis for energy conversion, Sci. Rep. 5(1) (2015) 1–21.
[36] J.X. Guo, X.Q. Zhang, Y.F. Sun, L. Tang, Q.Y. Liu, X. Zhang, Loading Pt nanoparticles on metal–organic frameworks for improved oxygen evolution, ACS Sustainable Chem. Eng. 5(12) (2017) 11577–11583.
[37] Y.M. Bi, Z. Cai, D.J. Zhou, Y. Tian, Q. Zhang, Q. Zhang, Y. Kuang, Y.P. Li, X.M. Sun, X. Duan, Understanding the incorporating effect of Co²⁺/Co³⁺ in NiFe-layered double hydroxide for electrocatalytic oxygen evolution reaction, J. Catal. 358(2018) 100–107.
[38] C. Ye, L.C. Zhang, L.C. Yue, B. Deng, Y. Cao, Q. Liu, Y.L. Luo, S.Y. Lu, B.Z. Zheng, X. P. Sun, A NiCo LDH nanosheet array on graphite felt: An efficient 3D electrocatalyst for the oxygen evolution reaction in alkaline media, Inorg. Chem. Front. 12(2021) 3162–3166.
[39] Q. Wu, J. Li, T.W. Wu, L. Ji, R. Zhang, P.F. Jiang, H.Y. Chen, R.B. Zhao, A.M. Asiri, X. P. Sun, One-step preparation of cobalt-nanoparticle-embedded carbon for effective water oxidation electrocatalysis, ChemElectroChem 6(7) (2019) 1996–1999.
[40] J.W. Li, R.Q. Lian, J.Y. Wang, S. He, S.P. Jiang, Z.B. Rui, Oxygen vacancy defects modulated electrocatalytic activity of iron-nickel layered double hydroxide on Ni foam as highly active electrodes for oxygen evolution reaction, Electrochim. Acta 331(2020) 135395..
[41] M.A. Oliver-Tolentino, J. Vázquez-Samperio, A. Manzo-Robledo, R. de Guadalupe González-Huerta, J.L. Flores-Moreno, D. Ramírez-Rosales, A. Guzmán-Vargas, An approach to understanding the electrocatalytic activity enhancement by superexchange interaction toward OER in alkaline media of Ni-Fe LDH, J. Phys. Chem. C 118(39) (2014) 22432–22438.
[42] S. Anantharaj, K. Karthick, M. Venkatesh, T.V.S.V. Simha, A.S. Salunke, L. Ma, H. Liang, S. Kundu, Enhancing electrocatalytic total water splitting at few layer Pt-NiFe layered double hydroxide interfaces, Nano Energy 39(2017) 30–43.

Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

Ag nanoparticles anchored on MIL-100/nickel foam nanosheets as an electrocatalyst for efficient oxygen evolution reaction performance

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