SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 51 ›› Issue (11): 168-177.DOI: 10.1016/j.cjche.2021.12.004

• Full Length Article • 上一篇    下一篇

A generalized CFD model for evaluating catalytic separation process in structured porous materials

Anshi Hong1, Zisheng Zhang1,2, Xingang Li1, Xin Gao1   

  1. 1. School of Chemical Engineering and Technology, National Engineering Research Center of Distillation Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China;
    2. Department of Chemical and Biological Engineering, University of Ottawa, Ottawa K1N 6N5, Canada
  • 收稿日期:2021-09-07 修回日期:2021-12-02 出版日期:2022-11-18 发布日期:2023-01-18
  • 通讯作者: Xin Gao,E-mail:gaoxin@tju.edu.cn
  • 基金资助:
    The authors acknowledge financial support from the National Key Resaerch and Development Program of China (2019YFE0123200) and National Natural Science Foundation of China (21776202). The authors also thank the reviewers for their specific comments and suggestions.

A generalized CFD model for evaluating catalytic separation process in structured porous materials

Anshi Hong1, Zisheng Zhang1,2, Xingang Li1, Xin Gao1   

  1. 1. School of Chemical Engineering and Technology, National Engineering Research Center of Distillation Technology, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin 300072, China;
    2. Department of Chemical and Biological Engineering, University of Ottawa, Ottawa K1N 6N5, Canada
  • Received:2021-09-07 Revised:2021-12-02 Online:2022-11-18 Published:2023-01-18
  • Contact: Xin Gao,E-mail:gaoxin@tju.edu.cn
  • Supported by:
    The authors acknowledge financial support from the National Key Resaerch and Development Program of China (2019YFE0123200) and National Natural Science Foundation of China (21776202). The authors also thank the reviewers for their specific comments and suggestions.

摘要: A hybrid multiphase model is developed to simulate the simultaneous momentum, heat and mass transfer and heterogeneous catalyzed reaction in structured catalytic porous materials. The approach relies on the combination of the volume of fluid (VOF) and Eulerian–Eulerian models, and several plug-in field functions. The VOF method is used to capture the gas–liquid interface motion, and the Eulerian–Eulerian framework solves the temperature and chemical species concentration equations for each phase. The self-defined field functions utilize a single-domain approach to overcome convergence difficulty when applying the hybrid multiphase for a multi-domain problem. The method is then applied to investigate selective removal of specific species in multicomponent reactive evaporation process. The results show that the coupling of catalytic reaction and interface species mass transfer at the phase interface is conditional, and the coupling of catalytic reaction and momentum transfer across fluid–porous interface significantly affects the conversion rate of reactants. Based on the numerical results, a strategy is proposed for matching solid catalyst with operating condition in catalytic distillation application.

关键词: CFD (computational fluid dynamics), Hybrid multiphase model, SiC foam, Mass transfer, Catalytic distillation

Abstract: A hybrid multiphase model is developed to simulate the simultaneous momentum, heat and mass transfer and heterogeneous catalyzed reaction in structured catalytic porous materials. The approach relies on the combination of the volume of fluid (VOF) and Eulerian–Eulerian models, and several plug-in field functions. The VOF method is used to capture the gas–liquid interface motion, and the Eulerian–Eulerian framework solves the temperature and chemical species concentration equations for each phase. The self-defined field functions utilize a single-domain approach to overcome convergence difficulty when applying the hybrid multiphase for a multi-domain problem. The method is then applied to investigate selective removal of specific species in multicomponent reactive evaporation process. The results show that the coupling of catalytic reaction and interface species mass transfer at the phase interface is conditional, and the coupling of catalytic reaction and momentum transfer across fluid–porous interface significantly affects the conversion rate of reactants. Based on the numerical results, a strategy is proposed for matching solid catalyst with operating condition in catalytic distillation application.

Key words: CFD (computational fluid dynamics), Hybrid multiphase model, SiC foam, Mass transfer, Catalytic distillation