Vanadium(V) reduction by using a by-product of the yellow phosphorus industry

doi:10.1016/j.cjche.2023.04.010

中国化学工程学报 ›› 2023, Vol. 62 ›› Issue (10): 150-158.DOI: 10.1016/j.cjche.2023.04.010

• Full Length Article • 上一篇下一篇

Vanadium(V) reduction by using a by-product of the yellow phosphorus industry

Baibin Yang¹, Shihong Chen¹, Haowen Ren¹, Yang Qiu¹, Chong Chen¹, Yong Guo¹, Chunhui Luo¹, Qiang Zhao¹, Wei Yang²

1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. State Key Laboratory of Hydraulics and Mountain River Engineering, College of Water Resource & Hydropower, Sichuan University, Chengdu 610065, China

收稿日期:2022-12-21 修回日期:2023-04-05 出版日期:2023-10-28 发布日期:2023-12-23
通讯作者: Qiang Zhao,E-mail:scuzq@scu.edu.cn;Wei Yang,E-mail:wei_yang@scu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation for Young Scientists of China (22108185, 51906168, 52276208).

Vanadium(V) reduction by using a by-product of the yellow phosphorus industry

Baibin Yang¹, Shihong Chen¹, Haowen Ren¹, Yang Qiu¹, Chong Chen¹, Yong Guo¹, Chunhui Luo¹, Qiang Zhao¹, Wei Yang²

1. School of Chemical Engineering, Sichuan University, Chengdu 610065, China;
2. State Key Laboratory of Hydraulics and Mountain River Engineering, College of Water Resource & Hydropower, Sichuan University, Chengdu 610065, China

Received:2022-12-21 Revised:2023-04-05 Online:2023-10-28 Published:2023-12-23
Contact: Qiang Zhao,E-mail:scuzq@scu.edu.cn;Wei Yang,E-mail:wei_yang@scu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation for Young Scientists of China (22108185, 51906168, 52276208).

摘要/Abstract

摘要： Release of vanadium(V) from industry has threatened the environment and human health. In this paper, a removal method of vanadium(V) is proposed using a by-product of the yellow phosphorus industry (phosphorus-iron) as a reducing agent. The thermodynamics analysis shows that the Gibbs free energy is always negative from 0 to 100 ℃, indicating a spontaneous process. Effect of the phosphorus-iron slag/sulfuric acid dosage and temperature on the removal efficiency is comprehensively studied, and the kinetics parameters are calculated based on a quasi-first order reaction kinetics model. Results indicate that vanadium(V) can be entirely reduced by using phosphorus-iron slag, the frequency factor and apparent activation energy are 3.23×10⁹ min^-1 and 64.50 kJ·mol^-1 for vanadium(V) reduction. Based on above results, a lab-scale reactor is constructed and achieves a removal efficiency of ~100% and a treatment capacity of 200 ml vanadium(V) solution (2 g·L^–1) within 3 h. This work demonstrates the feasibility of vanadium(V) reduction using phosphorus-iron slag as a reducing agent in applications.

关键词: Vanadium, Phosphorus-iron slag, Thermodynamics, Kinetics, Reduction

Abstract: Release of vanadium(V) from industry has threatened the environment and human health. In this paper, a removal method of vanadium(V) is proposed using a by-product of the yellow phosphorus industry (phosphorus-iron) as a reducing agent. The thermodynamics analysis shows that the Gibbs free energy is always negative from 0 to 100 ℃, indicating a spontaneous process. Effect of the phosphorus-iron slag/sulfuric acid dosage and temperature on the removal efficiency is comprehensively studied, and the kinetics parameters are calculated based on a quasi-first order reaction kinetics model. Results indicate that vanadium(V) can be entirely reduced by using phosphorus-iron slag, the frequency factor and apparent activation energy are 3.23×10⁹ min^-1 and 64.50 kJ·mol^-1 for vanadium(V) reduction. Based on above results, a lab-scale reactor is constructed and achieves a removal efficiency of ~100% and a treatment capacity of 200 ml vanadium(V) solution (2 g·L^–1) within 3 h. This work demonstrates the feasibility of vanadium(V) reduction using phosphorus-iron slag as a reducing agent in applications.

Key words: Vanadium, Phosphorus-iron slag, Thermodynamics, Kinetics, Reduction

Baibin Yang, Shihong Chen, Haowen Ren, Yang Qiu, Chong Chen, Yong Guo, Chunhui Luo, Qiang Zhao, Wei Yang. Vanadium(V) reduction by using a by-product of the yellow phosphorus industry[J]. 中国化学工程学报, 2023, 62(10): 150-158.

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Vanadium(V) reduction by using a by-product of the yellow phosphorus industry

Vanadium(V) reduction by using a by-product of the yellow phosphorus industry

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