Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

doi:10.1016/j.cjche.2023.08.002

中国化学工程学报 ›› 2024, Vol. 65 ›› Issue (1): 1-7.DOI: 10.1016/j.cjche.2023.08.002

• Full Length Article • 下一篇

Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

Risheng Shen¹, Shilong Li¹, Yuqing Sun¹, Yuan Bai², Jian Lu¹, Wenheng Jing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 National Energy Group Science and Technology Research Institute Co., Ltd., Nanjing 210023, China

收稿日期:2023-04-03 修回日期:2023-08-15 出版日期:2024-01-28 发布日期:2024-04-17
通讯作者: Wenheng Jing,E-mail:jingwh@njtech.edu.cn
基金资助:
We sincerely appreciate the support from the National Key Research and Development Program (2021YFB3801303), the National Natural Science Foundation of China (21838005, 21921006), the State Key Laboratory of Materials-Oriented Chemical Engineering (SKL-MCE-22A03), and the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology (BE2022033-3).

Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

Risheng Shen¹, Shilong Li¹, Yuqing Sun¹, Yuan Bai², Jian Lu¹, Wenheng Jing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 National Energy Group Science and Technology Research Institute Co., Ltd., Nanjing 210023, China

Received:2023-04-03 Revised:2023-08-15 Online:2024-01-28 Published:2024-04-17
Contact: Wenheng Jing,E-mail:jingwh@njtech.edu.cn
Supported by:
We sincerely appreciate the support from the National Key Research and Development Program (2021YFB3801303), the National Natural Science Foundation of China (21838005, 21921006), the State Key Laboratory of Materials-Oriented Chemical Engineering (SKL-MCE-22A03), and the Key Research and Development Program of Jiangsu Provincial Department of Science and Technology (BE2022033-3).

摘要/Abstract

摘要： Membrane technology has become the mainstream process for the production of electronic grade hydrogen peroxide (H₂O₂). But due to the oxidation degradation of the organic membranes (e.g. polyamide) by the strong oxidative radicals (e.g.·OH) generated via the activation of H₂O₂ by iron ions (Fe³⁺), the short effective lifetime of membranes remains a challenge. Inorganic nano tin oxide (SnO₂) has great potential for the removal of Fe³⁺ in strongly oxidative H₂O₂ because of its ability to stabilize H₂O₂ and preferentially adsorb Fe³⁺. Herein, we have designed for the first time a flower-like robust SnO₂ membrane on the ceramic support by in situ template-free one-step hydrothermal method. The three-dimensional loose pore structure in the membrane built by interlacing SnO₂ nanosheets endows the SnO₂ membrane with a high specific surface area and abundant adsorption sites (—OH). Based on the coordination complexation and electrostatic attraction between the SnO₂ surface and Fe³⁺, the membrane shows a high Fe³⁺ removal efficiency (83%) and permeability (24 L·m^-2·h^-1·MPa^-1) in H₂O₂. This study provides an innovative and simple approach to designing robust SnO₂ membranes for highly efficient removal of Fe³⁺ in harsh environments, such as strong oxidation conditions.

关键词: Hydrogen peroxide, SnO₂ membrane, Adsorption, Hydrothermal

Abstract: Membrane technology has become the mainstream process for the production of electronic grade hydrogen peroxide (H₂O₂). But due to the oxidation degradation of the organic membranes (e.g. polyamide) by the strong oxidative radicals (e.g.·OH) generated via the activation of H₂O₂ by iron ions (Fe³⁺), the short effective lifetime of membranes remains a challenge. Inorganic nano tin oxide (SnO₂) has great potential for the removal of Fe³⁺ in strongly oxidative H₂O₂ because of its ability to stabilize H₂O₂ and preferentially adsorb Fe³⁺. Herein, we have designed for the first time a flower-like robust SnO₂ membrane on the ceramic support by in situ template-free one-step hydrothermal method. The three-dimensional loose pore structure in the membrane built by interlacing SnO₂ nanosheets endows the SnO₂ membrane with a high specific surface area and abundant adsorption sites (—OH). Based on the coordination complexation and electrostatic attraction between the SnO₂ surface and Fe³⁺, the membrane shows a high Fe³⁺ removal efficiency (83%) and permeability (24 L·m^-2·h^-1·MPa^-1) in H₂O₂. This study provides an innovative and simple approach to designing robust SnO₂ membranes for highly efficient removal of Fe³⁺ in harsh environments, such as strong oxidation conditions.

Key words: Hydrogen peroxide, SnO₂ membrane, Adsorption, Hydrothermal

Risheng Shen, Shilong Li, Yuqing Sun, Yuan Bai, Jian Lu, Wenheng Jing. Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide[J]. 中国化学工程学报, 2024, 65(1): 1-7.

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Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

Flower-like tin oxide membranes with robust three-dimensional channels for efficient removal of iron ions from hydrogen peroxide

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