Synthesis of granulated Li1.33Mn1.67O4 via two antisolvent methods for lithium adsorption from gas-produced water

doi:10.1016/j.cjche.2024.01.013

摘要/Abstract

摘要： Gas-produced water is an accompanying wastewater in the natural gas extraction process, and it is a potential liquid lithium resource that contains a considerable amount of lithium. This study investigated the feasibility of using manganese-based ion sieves to adsorb and extract lithium from gas-produced water. And we focused on the applicability of two different granulation methods, extrusion and droplet, in gas-produced water systems. Two types of H_1.33Mn_1.67O₄ particles were prepared by the extrusion method (EHMO) and the droplet method (DHMO). The porosity of DHMO was much higher than that of EHMO, and the adsorption performance of DHMO increased with the decrease of binder concentration. DHMO prepared with a binder concentration of 0.14 g·ml^-1 exhibited the best adsorption performance in gas-produced water, and the Li⁺ adsorption capacity could reach 25.14 mg·g^-1. In gas-produced water, the adsorption equilibrium of DHMO only took 9 h, and the adsorption process conformed to the Langmuir model and pseudo-second-order kinetic model. The pore diffusion model (PDM) could well describe its adsorption process. Besides, DHMO showed a great selectivity to Li⁺, and the selectivity order of DHMO in gas-produced water was Li⁺>Ba²⁺≫Mg²⁺, Ca²⁺, Sr²⁺≫Na⁺≫K⁺. After 20 cycles, the Li⁺ adsorption capacity was still higher than 17.30 mg·g^-1, and the rate of manganese dissolution was less than 1%.

关键词: Gas-produced water, Granulation, Li_1.33Mn_1.67O₄

Abstract: Gas-produced water is an accompanying wastewater in the natural gas extraction process, and it is a potential liquid lithium resource that contains a considerable amount of lithium. This study investigated the feasibility of using manganese-based ion sieves to adsorb and extract lithium from gas-produced water. And we focused on the applicability of two different granulation methods, extrusion and droplet, in gas-produced water systems. Two types of H_1.33Mn_1.67O₄ particles were prepared by the extrusion method (EHMO) and the droplet method (DHMO). The porosity of DHMO was much higher than that of EHMO, and the adsorption performance of DHMO increased with the decrease of binder concentration. DHMO prepared with a binder concentration of 0.14 g·ml^-1 exhibited the best adsorption performance in gas-produced water, and the Li⁺ adsorption capacity could reach 25.14 mg·g^-1. In gas-produced water, the adsorption equilibrium of DHMO only took 9 h, and the adsorption process conformed to the Langmuir model and pseudo-second-order kinetic model. The pore diffusion model (PDM) could well describe its adsorption process. Besides, DHMO showed a great selectivity to Li⁺, and the selectivity order of DHMO in gas-produced water was Li⁺>Ba²⁺≫Mg²⁺, Ca²⁺, Sr²⁺≫Na⁺≫K⁺. After 20 cycles, the Li⁺ adsorption capacity was still higher than 17.30 mg·g^-1, and the rate of manganese dissolution was less than 1%.

Key words: Gas-produced water, Granulation, Li_1.33Mn_1.67O₄

Jun Qiu, Lu-Ri Bao, Wei Guo, Ying Yang, Shu-Ying Sun. Synthesis of granulated Li_1.33Mn_1.67O₄ via two antisolvent methods for lithium adsorption from gas-produced water[J]. 中国化学工程学报, 2024, 69(5): 34-46.

参考文献

[1] B. Swain, Recovery and recycling of lithium: A review, Sep. Purif. Technol. 172(2017)388-403.
[2] Y. Orooji, Z. Nezafat, M. Nasrollahzadeh, N. Shafiei, M. Afsari, K. Pakzad, A. Razmjou, Recent advances in nanomaterial development for lithium ion-sieving technologies, Desalination 529(2022)115624.
[3] P. Xu, J. Hong, X.M. Qian, Z.W. Xu, H. Xia, X.C. Tao, Z.Z. Xu, Q.Q. Ni, Materials for lithium recovery from salt lake brine, J. Mater. Sci. 56(1)(2021)16-63.
[4] L.A. Gil-Alana, M. Monge, Lithium:production and estimated consumption. Evidence of persistence, Resour. Policy 60(2019)198-202.
[5] K. Shehzad, U. Zaman, B.U. Zaman, X.X. Liu, R.A. Jafri, Lithium production, electricity consumption, and greenhouse gas emissions:an imperious role of economic globalization, J. Clean. Prod. 372(2022)133689.
[6] W.L. Xie, X.H. Liu, R. He, Y.L. Li, X.L. Gao, X.H. Li, Z.X. Peng, S.W. Feng, X.N. Feng, S.C. Yang, Challenges and opportunities toward fast-charging of lithium-ion batteries, J. Energy Storage 32(2020)101837.
[7] V. Flexer, C.F. Baspineiro, C.I. Galli, Lithium recovery from brines:a vital raw material for green energies with a potential environmental impact in its mining and processing, Sci. Total Environ. 639(2018)1188-1204.
[8] J. Zhong, S. Lin, J.G. Yu, Li⁺ adsorption performance and mechanism using lithium/aluminum layered double hydroxides in low grade brines, Desalination 505(2021)114983.
[9] K.Y. Ding, G.R. Zhu, C.H. Song, Q. Wang, L. Wang, Z.Q. Wang, C.X. Meng, C.J. Gao, Fabrication of polyacrylonitrile-Li_1.6Mn_1.6O₄ composite nanofiber flat-sheet membranes via electrospinning method as effective adsorbents for Li⁺ recovery from salt-lake brine, Sep. Purif. Technol. 284(2022)120242.
[10] J. Zhong, S. Lin, J.G. Yu, Lithium recovery from ultrahigh Mg²⁺/Li⁺ratio brine using a novel granulated Li/Al-LDHs adsorbent, Sep. Purif. Technol. 256(2021)117780.
[11] H.J. Hong, T. Ryu, I.S. Park, M. Kim, J. Shin, B.G. Kim, K.S. Chung, Highly porous and surface-expanded spinel hydrogen manganese oxide (HMO)/Al₂O₃ composite for effective lithium (Li) recovery from seawater, Chem. Eng. J. 337(2018)455-461.
[12] H.J. Hong, I.S. Park, T. Ryu, J. Ryu, B.G. Kim, K.S. Chung, Granulation of Li_1.33Mn_1.67O₄(LMO) through the use of cross-linked chitosan for the effective recovery of Li⁺ from seawater, Chem. Eng. J. 234(2013)16-22.
[13] G. Zante, D. Trebouet, M. Boltoeva, Solvent extraction of lithium from simulated shale gas produced water with a bifunctional ionic liquid, Appl. Geochem. 123(2020)104783.
[14] A. Seip, S. Safari, D.M. Pickup, A.V. Chadwick, S. Ramos, C.A. Velasco, J.M. Cerrato, D.S. Alessi, Lithium recovery from hydraulic fracturing flowback and produced water using a selective ion exchange sorbent, Chem. Eng. J. 426(2021)130713.
[15] K.Y. Zhao, B.J. Tong, X.P. Yu, Y.F. Guo, Y.X. Xie, T. Deng, Synthesis of porous fiber-supported lithium ion-sieve adsorbent for lithium recovery from geothermal water, Chem. Eng. J. 430(2021)131423.
[16] X.P. Yu, X.B. Fan, Y.F. Guo, T. Deng, Recovery of lithium from underground brine by multistage centrifugal extraction using tri-isobutyl phosphate, Sep. Purif. Technol. 211(2019)790-798.
[17] Y. Zhang, Y.H. Hu, L. Wang, W. Sun, Systematic review of lithium extraction from salt-lake brines via precipitation approaches, Miner. Eng. 139(2019)105868.
[18] J. Li, Q.L. Luo, M.Z. Dong, G.L. Nie, Z. Liu, Z.J. Wu, Synthesis of granulated Li/Al-LDHs adsorbent and application for recovery of Li from synthetic and real salt lake brines, Hydrometallurgy 209(2022)105828.
[19] S.D. Wei, Y.F. Wei, T. Chen, C.B. Liu, Y.H. Tang, Porous lithium ion sieves nanofibers:general synthesis strategy and highly selective recovery of lithium from brine water, Chem. Eng. J. 379(2020)122407.
[20] F. Arroyo, J. Morillo, J. Usero, D. Rosado, H. El Bakouri, Lithium recovery from desalination brines using specific ion-exchange resins, Desalination 468(2019)114073.
[21] A. Khalil, S. Mohammed, R. Hashaikeh, N. Hilal, Lithium recovery from brine:recent developments and challenges, Desalination 528(2022)115611.
[22] J. Zhang, H. Su, W.S. Liu, L.N. Wang, Z.W. Zhu, T. Qi, A new process to produce battery grade lithium carbonate from salt lake brines by purification, synergistic solvent extraction and carbon dioxide stripping, Hydrometallurgy 215(2023)105991.
[23] J.N. Lu, G.W. Stevens, K.A. Mumford, Development of heterogeneous equilibrium model for lithium solvent extraction using organophosphinic acid, Sep. Purif. Technol. 276(2021)119307.
[24] Z.Y. Ji, Q.B. Chen, J.S. Yuan, J. Liu, Y.Y. Zhao, W.X. Feng, Preliminary study on recovering lithium from high Mg²⁺/Li⁺ratio brines by electrodialysis, Sep. Purif. Technol. 172(2017)168-177.
[25] R.R. He, S.S. Xu, R.Y. Wang, B.Y. Bai, S.H. Lin, T. He, Polyelectrolyte-based nanofiltration membranes with exceptional performance in Mg²⁺/Li⁺separation in a wide range of solution conditions, J. Membrane Sci. 633(2022)121027.
[26] G. Yang, H. Shi, W.Q. Liu, W.H. Xing, N.P. Xu, Investigation of Mg²⁺/Li⁺separation by nanofiltration, Chin. J. Chem. Eng. 19(4)(2011)586-591.
[27] D.F. Liu, S.Y. Sun, J.G. Yu, A new high-efficiency process for Li⁺ recovery from solutions based on LiMn₂O₄/λ-MnO₂ materials, Chem. Eng. J. 377(2019)119825.
[28] B. Hu, X.H. Shang, P.F. Nie, B.S. Zhang, J.M. Yang, J.Y. Liu, Lithium ion sieve modified three-dimensional graphene electrode for selective extraction of lithium by capacitive deionization, J. Colloid Interface Sci. 612(2022)392-400.
[29] M. Abe, R. Chitrakar, Synthetic inorganic ion-exchange materials. XLV. Recovery of lithium from seawater and hydrothermal water by titanium (iv) antimonate cation exchanger, Hydrometallurgy 19(1)(1987)117-128.
[30] H. Vikström, S. Davidsson, M. Höök, Lithium availability and future production outlooks, Appl. Energy 110(2013)252-266.
[31] A. Kumar, H. Fukuda, T.A. Hatton, J.H. Lienhard V, Lithium recovery from oil and gas produced water:a need for a growing energy industry, ACS Energy Lett. 4(6)(2019)1471-1474.
[32] W.C. Xie, P. Tang, Q.D. Wu, C. Chen, Z.Y. Song, T. Li, Y.H. Bai, S.H. Lin, A. Tiraferri, B.C. Liu, Solar-driven desalination and resource recovery of shale gas wastewater by on-site interfacial evaporation, Chem. Eng. J. 428(2022)132624.
[33] B. Rebary, M. Raichura, S.R. Mangukia, R. Patidar, Mapping of iodine, lithium and strontium in oilfield water of Cambay Basin, Gujarat, J. Geol. Soc. Ind. 83(6)(2014)669-675.
[34] L.O. Haluszczak, A.W. Rose, L.R. Kump, Geochemical evaluation of flowback brine from Marcellus gas wells in Pennsylvania, USA, Appl. Geochem. 28(2013)55-61.
[35] A. Butkovskyi, H. Bruning, S.A.E. Kools, H.H.M. Rijnaarts, A.P. Van Wezel, Organic pollutants in shale gas flowback and produced waters:identification, potential ecological impact, and implications for treatment strategies, Environ. Sci. Technol. 51(9)(2017)4740-4754.
[36] Y.H. Liu, Q.D. Wu, C. Chen, T. Li, S. Liu, Q.P. He, P. Yang, Y.H. Bai, B.C. Liu, An efficient system of aerogel adsorbent combined with membranes for reuse of shale gas wastewater, Desalination 526(2022)115545.
[37] E. Jang, S. Jeong, E. Chung, Application of three different water treatment technologies to shale gas produced water, Geosyst. Eng. 20(2)(2017)104-110.
[38] Y. Sun, M.H. Wu, T.Z. Tong, P. Liu, P. Tang, Z.W. Gan, P. Yang, Q.P. He, B.C. Liu, Organic compounds in Weiyuan shale gas produced water:identification, detection and rejection by ultrafiltration-reverse osmosis processes, Chem. Eng. J. 412(2021)128699.
[39] W. Orem, C.L. Tatu, M. Varonka, H. Lerch, A. Bates, M. Engle, L. Crosby, J. McIntosh, Organic substances in produced and formation water from unconventional natural gas extraction in coal and shale, Int. J. Coal Geol. 126(2014)20-31.
[40] K.B. Gregory, R.D. Vidic, D.A. Dzombak, Water management challenges associated with the production of shale gas by hydraulic fracturing, Elements 7(3)(2011)181-186.
[41] P. Tang, B.C. Liu, W.C. Xie, P.P. Wang, Q.P. He, J. Bao, Y.L. Zhang, Z.H. Zhang, J. Li, J. Ma, Synergistic mechanism of combined ferrate and ultrafiltration process for shale gas wastewater treatment, J. Membr. Sci. 641(2022)119921.
[42] C.A. Robbins, X.W. Du, T.H. Bradley, J.C. Quinn, T.M. Bandhauer, S.A. Conrad, K.H. Carlson, T.Z. Tong, Beyond treatment technology:understanding motivations and barriers for wastewater treatment and reuse in unconventional energy production, Resour. Conserv. Recycl. 177(2022)106011.
[43] T. Hano, M. Matsumoto, T. Ohtake, N. Egashir, F. Hori, Recovery of lithium from geothermal water by solvent extraction technique, Solvent Extr. Ion Exch. 10(2)(1992)195-206.
[44] H. Kanoh, K. Ooi, Y. Miyai, S. Katoh, Electrochemical recovery of lithium ions in the aqueous phase, Sep. Sci. Technol. 28(1-3)(1993)643-651.
[45] Y. Jang, E. Chung, Adsorption of lithium from shale gas produced water using titanium based adsorbent, Ind. Eng. Chem. Res. 57(25)(2018)8381-8387.
[46] Y. Jang, E. Chung, Influence of alkanes on lithium adsorption and desorption of a H₂TiO₃ ion sieve adsorbent in synthetic shale gas-produced water, Ind. Eng. Chem. Res. 58(48)(2019)21897-21903.
[47] Y. Jang, E. Chung, Lithium adsorptive properties of H₂TiO₃ adsorbent from shale gas produced water containing organic compounds, Chemosphere 221(2019)75-80.
[48] L. Tian, Y.H. Liu, P. Tang, Y.S. Yang, X.R. Wang, T.X. Chen, Y.H. Bai, A. Tiraferri, B.C. Liu, Lithium extraction from shale gas flowback and produced water using H_1.33Mn_1.67O₄ adsorbent, Resour. Conserv. Recycl. 185(2022)106476.
[49] E. Jang, Y. Jang, E. Chung, Lithium recovery from shale gas produced water using solvent extraction, Appl. Geochem. 78(2017)343-350.
[50] J. Lee, E. Chung, Lithium recovery by solvent extraction from simulated shale gas produced water-Impact of organic compounds, Appl. Geochem. 116(2020)104571.
[51] S. Safari, B.G. Lottermoser, D.S. Alessi, Metal oxide sorbents for the sustainable recovery of lithium from unconventional resources, Appl. Mater. Today 19(2020)100638.
[52] Z. Yang, Y. Li, P. Ma, Synthesis of H₂TiO₃-PVC lithium-ion sieves via an antisolvent method and its adsorption performance, Ceramics International 48(20)(2022)30127-30134.
[53] G.T. Zhang, C.X. Hai, Y. Zhou, J.Z. Zhang, Y.H. Liu, J.B. Zeng, Y. Shen, X. Li, Y.X. Sun, Z.W. Wu, W.P. Tang, Synthesis and performance estimation of a granulated PVC/PAN-lithium ion-sieve for Li⁺ recovery from brine, Sep. Purif. Technol. 305(2023)122431.
[54] D.S. Sun, M.J. Meng, Y.J. Yin, Y.Z. Zhu, H.J. Li, Y.S. Yan, Highly selective, regenerated ion-sieve microfiltration porous membrane for targeted separation of Li⁺, J. Porous Mater. 23(6)(2016)1411-1419.
[55] W.J. Ding, J.Y. Zhang, Y.Y. Liu, Y.F. Guo, T.L. Deng, X.P. Yu, Synthesis of granulated H₄Mn₅O₁₂/chitosan with improved stability by a novel cross-linking strategy for lithium adsorption from aqueous solutions, Chem. Eng. J. 426(2021)131689.
[56] J.L. Xiao, X.Y. Nie, S.Y. Sun, X.F. Song, P. Li, J.G. Yu, Lithium ion adsorption-desorption properties on spinel Li₄Mn₅O₁₂ and pH-dependent ion-exchange model, Adv. Powder Technol. 26(2)(2015)589-594.
[57] I. Langmuir, The constitution and fundamental properties of solids and liquids, J. Frankl. Inst. 183(1)(1917)102-105.
[58] R. Saadi, Z. Saadi, R. Fazaeli, et al., Monolayer and multilayer adsorption isotherm models for sorption from aqueous media, Korean J. Chem. Eng. 32(5)(2015)787-799.
[59] T.W. Weber, R.K. Chakravorti, Pore and solid diffusion models for fixed-bed adsorbers, AlChE. J. 20(2)(1974)228-238.
[60] K.Y. Foo, B.H. Hameed, Insights into the modeling of adsorption isotherm systems, Chem. Eng. J. 156(1)(2010)2-10.
[61] H. Freundlich, Over the adsorption in solution, J. Phys. Chem, 57(385471)(1906)1100-1107.
[62] Z. Xu, J.G. Cai, B.C. Pan, Mathematically modeling fixed-bed adsorption in aqueous systems, J. Zhejiang Univ. Sci. A 14(3)(2013)155-176.
[63] L.Y. Tian, W. Ma, M. Han, Adsorption behavior of Li⁺ onto nano-lithium ion sieve from hybrid magnesium/lithium manganese oxide, Chem. Eng. J. 156(1)(2010)134-140.
[64] Q.L. Luo, M.Z. Dong, G.L. Nie, Z. Liu, Z.J. Wu, J. Li, Extraction of lithium from salt lake brines by granulated adsorbents, Colloids Surf. A Physicochem. Eng. Aspects 628(2021)127256.
[65] J. Chen, S. Lin, J.G. Yu, High-selective cyclic adsorption and magnetic recovery performance of magnetic lithium-aluminum layered double hydroxides (MLDHs) in extracting Li⁺ from ultrahigh Mg/Li ratio brines, Sep. Purif. Technol. 255(2021)117710.
[66] M.J. Park, G.M. Nisola, A.B. Beltran, R.E.C. Torrejos, J.G. Seo, S.P. Lee, H. Kim, W.J. Chung, Recyclable composite nanofiber adsorbent for Li⁺ recovery from seawater desalination retentate, Chem. Eng. J. 254(2014)73-81.
[67] F. Yang, S.C. Chen, C.T. Shi, F. Xue, X.X. Zhang, S.G. Ju, W.H. Xing, A facile synthesis of hexagonal spinel λ-MnO₂ ion-sieves for highly selective Li⁺ adsorption, Processes 6(5)(2018)59.
[68] J.C. Ryu, J. Shin, C. Lim, K.H. Kim, T. Ryu, Y.S. Lee, Lithium ion adsorption characteristics of porous Li₁₃₃Mn₁₆₇O₄ adsorbent prepared using petroleum-based pitch as a binder, Hydrometallurgy 209(2022)105837.
[69] L.Y. Zhang, D.L. Zhou, Q.Q. Yao, J.B. Zhou, Preparation of H₂ TiO₃-lithium adsorbent by the sol-gel process and its adsorption performance, Appl. Surf. Sci. 368(2016)82-87.

Synthesis of granulated Li_1.33Mn_1.67O₄ via two antisolvent methods for lithium adsorption from gas-produced water

Synthesis of granulated Li_1.33Mn_1.67O₄ via two antisolvent methods for lithium adsorption from gas-produced water

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 1

编辑推荐

Metrics

本文评价