Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products

doi:10.1016/j.cjche.2024.08.012

中国化学工程学报 ›› 2024, Vol. 76 ›› Issue (12): 135-146.DOI: 10.1016/j.cjche.2024.08.012

Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products

Rongqi Chen, Yongzheng Zhang, Yanli Wang, Chunyin Shen, Liang Zhan, Licheng Ling

State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

收稿日期:2024-06-12 修回日期:2024-08-03 接受日期:2024-08-28 出版日期:2024-12-28 发布日期:2024-10-16
通讯作者: Yongzheng Zhang,E-mail:zhangyongzheng@ecust.edu.cn;Yanli Wang,E-mail:ylwang@ecust.edu.cn;Liang Zhan,E-mail:zhanliang@ecust.edu.cn
基金资助:
This work was financially supported by the National Natural Science Foundation of China (22075081, 52372045 and U1710252), the Fundamental Research Funds for the Central Universities (JKD01231701), China Postdoctoral Science Foundation (2023M731084), Shanghai Sailing Program of China (23YF1408900).

Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products

Rongqi Chen, Yongzheng Zhang, Yanli Wang, Chunyin Shen, Liang Zhan, Licheng Ling

State Key Laboratory of Green Chemical Engineering and Industrial Catalysis, Key Laboratory of Specially Functional Polymeric Materials and Related Technology (Ministry of Education), Shanghai Key Laboratory of Multiphase Materials Chemical Engineering, State Key Laboratory of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China

Received:2024-06-12 Revised:2024-08-03 Accepted:2024-08-28 Online:2024-12-28 Published:2024-10-16
Contact: Yongzheng Zhang,E-mail:zhangyongzheng@ecust.edu.cn;Yanli Wang,E-mail:ylwang@ecust.edu.cn;Liang Zhan,E-mail:zhanliang@ecust.edu.cn
Supported by:
This work was financially supported by the National Natural Science Foundation of China (22075081, 52372045 and U1710252), the Fundamental Research Funds for the Central Universities (JKD01231701), China Postdoctoral Science Foundation (2023M731084), Shanghai Sailing Program of China (23YF1408900).

摘要/Abstract

摘要： Ethylene tar is a prospective precursor for preparing carbonaceous materials, which is regarded as a representative soft carbon material after carbonization. However, the introduction of oxygen can influence the morphology of the final carbonaceous materials. For the introduction of oxygen, dealkylation and dehydrogenation will be promoted and the molecules can be linked more effectively. For the subsequent carbonization, the biphenyl structures caused by the deoxygenation via the elimination of CO₂, as well as the reserved aromatic ether bonds, can facilitate the strong cross-linking, which will restrain the movement of the carbon layers and the formation of the graphitic structures. After the graphitization treatment at 2800 ℃, the oxidized pitch can lead to short-range ordered and long-range unordered structures, while the sample without oxidation can result in long-range ordered graphitic structures. It can be proved that a simple oxidation-carbonization treatment can transform ethylene tar into hard carbon structures.

关键词: Fuel, Oxidation, Ethylene tar pitch, Carbonization, Hard carbon, Chemical processes

Abstract: Ethylene tar is a prospective precursor for preparing carbonaceous materials, which is regarded as a representative soft carbon material after carbonization. However, the introduction of oxygen can influence the morphology of the final carbonaceous materials. For the introduction of oxygen, dealkylation and dehydrogenation will be promoted and the molecules can be linked more effectively. For the subsequent carbonization, the biphenyl structures caused by the deoxygenation via the elimination of CO₂, as well as the reserved aromatic ether bonds, can facilitate the strong cross-linking, which will restrain the movement of the carbon layers and the formation of the graphitic structures. After the graphitization treatment at 2800 ℃, the oxidized pitch can lead to short-range ordered and long-range unordered structures, while the sample without oxidation can result in long-range ordered graphitic structures. It can be proved that a simple oxidation-carbonization treatment can transform ethylene tar into hard carbon structures.

Key words: Fuel, Oxidation, Ethylene tar pitch, Carbonization, Hard carbon, Chemical processes

Rongqi Chen, Yongzheng Zhang, Yanli Wang, Chunyin Shen, Liang Zhan, Licheng Ling. Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products[J]. 中国化学工程学报, 2024, 76(12): 135-146.

Rongqi Chen, Yongzheng Zhang, Yanli Wang, Chunyin Shen, Liang Zhan, Licheng Ling. Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products[J]. Chinese Journal of Chemical Engineering, 2024, 76(12): 135-146.

参考文献

[1] Z.F. Li, Y.C. Chen, Z.L. Jian, H. Jiang, J.J. Razink, W.F. Stickle, J.C. Neuefeind, X.L. Ji, Defective hard carbon anode for Na-ion batteries, Chem. Mater. 30 (14) (2018) 4536-4542.
[2] H. Fujimoto, K. Tokumitsu, A. Mabuchi, N. Chinnasamy, T. Kasuh, The anode performance of the hard carbon for the lithium ion battery derived from the oxygen-containing aromatic precursors, J. Power Sources 195 (21) (2010) 7452-7456.
[3] Z.H. Guo, C.Y. Wang, M.M. Chen, M.W. Li, Hard carbon derived from coal tar pitch for use as the anode material in lithium ion batteries, Int. J. Electrochem. Sci. 8 (2) (2013) 2702-2709.
[4] E. Irisarri, A. Ponrouch, M.R. Palacin, Review-hard carbon negative electrode materials for sodium-ion batteries, J. Electrochem. Soc. 162 (14) (2015) A2476-A2482.
[5] D.Q. Chen, W. Zhang, K.Y. Luo, Y. Song, Y.J. Zhong, Y.X. Liu, G.K. Wang, B.H. Zhong, Z.G. Wu, X.D. Guo, Hard carbon for sodium storage: mechanism and optimization strategies toward commercialization, Energy Environ. Sci. 14 (4) (2021) 2244-2262.
[6] Y. Morikawa, S.I. Nishimura, R.I. Hashimoto, M. Ohnuma, A. Yamada, Mechanism of sodium storage in hard carbon: an X-ray scattering analysis, Adv. Energy Mater. 10 (3) (2020) 1903176.
[7] C.Z. Ge, Z.H. Fan, J. Zhang, Y.M. Qiao, J.M. Wang, L.C. Ling, Novel hard carbon/graphite composites synthesized by a facile in situ anchoring method as high-performance anodes for lithium-ion batteries, RSC Adv. 8 (60) (2018) 34682-34689.
[8] T. Zheng, J.S. Xue, J.R. Dahn, Lithium insertion in hydrogen-containing carbonaceous materials, Chem. Mater. 8 (2) (1996) 389-393.
[9] L.F. Zhao, Z. Hu, W.H. Lai, Y. Tao, J. Peng, Z.C. Miao, Y.X. Wang, S.L. Chou, H.K. Liu, S.X. Dou, Hard carbon anodes: fundamental understanding and commercial perspectives for Na-ion batteries beyond Li-ion and K-ion counterparts, Adv. Energy Mater. 11 (1) (2021) 2002704.
[10] Y.Y. Yu, Q. Wei, F. Wang, S.H. Jiao, Z.P. Qiu, L.L. Wang, H. Liu, K. Chen, A.J. Guo, Carbonization characteristics of ethylene tar narrow fractions, J. Fuel Chem. Technol. 50 (3) (2022) 376-384.
[11] Y.Y. Yu, F. Wang, B. Wiafe Biney, K.Q. Li, S.H. Jiao, K. Chen, H. Liu, A.J. Guo, Co-carbonization of ethylene tar and fluid catalytic cracking decant oil: development of high-quality needle coke feedstock, Fuel 322 (2022) 124170.
[12] C.Z. Ge, Z.L. Sun, H.X. Yang, D.H. Long, W.M. Qiao, L.C. Ling, Preparation and characterization of high softening point and homogeneous isotropic pitches produced from distilled ethylene tar by a novel bromination method, N. Carbon Mater. 33 (1) (2018) 71-81.
[13] C.Z. Ge, H.X. Yang, J.T. Wang, W.M. Qiao, D.H. Long, L.C. Ling, Highly effective utilization of ethylene tar for mesophase development via a molecular fractionation process, RSC Adv. 6 (1) (2016) 796-804.
[14] K. Shi, J.X. Yang, C. Ye, H.B. Liu, X.K. Li, A comparison of ethylene-tar-derived isotropic pitches prepared by air blowing and nitrogen distillation methods and their carbon fibers, Materials 12 (2) (2019) 305.
[15] M.B. Wu, Y.Y. Shi, S.B. Li, N. Guo, Y.W. Wang, J.T. Zheng, J.S. Qiu, Synthesis and characterization of condensed poly-nuclear aromatic resin using heavy distillate from ethylene tar, N. Carbon Mater. 27 (6) (2012) 469-475.
[16] J.C. Liu, X.J. Chen, Q. Xie, D.C. Liang, Controllable synthesis of isotropic pitch precursor for general purpose carbon fiber using waste ethylene tar via bromination-dehydrobromination, J. Clean. Prod. 271 (2020) 122498.
[17] R. Menendez, M. Granda, J.J. Fernandez, A. Figueiras, J. Bermejo, J. Bonhomme, J. Belzunce, Influence of pitch air-blowing and thermal treatment on the microstructure and mechanical properties of carbon/carbon composites, J. Microsc. 185 (2) (1997) 145-156.
[18] C. Blanco, R. Santamaria, J. Bermejo, R. Menendez, A comparative study of air-blown and thermally treated coal-tar pitches, Carbon 38 (4) (2000) 517-523.
[19] S. Otani, Mechanism of the carbonization of MP carbon fiber at the low temperature range, Carbon 5 (3) (1967) 219-225.
[20] S.M. Zeng, T. Maeda, K. Tokumitsu, J. Mondori, I. Mochida, Preparation of isotropic pitch precursors for general purpose carbon fibers (GPCF) by air blowing-II. air blowing of coal tar, hydrogenated coal tar, and petroleum pitches, Carbon 31 (3) (1993) 413-419.
[21] T. Maeda, S.M. Zeng, K. Tokumitsu, J. Mondori, I. Mochida, Preparation of isotropic pitch precursors for general purpose carbon fibers (GPCF) by air blowing-I. preparation of spinnable isotropic pitch precursor from coal tar by air blowing, Carbon 31 (3) (1993) 407-412.
[22] J.B. Barr, I.C. Lewis, Chemical changes during the mild air oxidation of pitch, Carbon 16 (6) (1978) 439-444.
[23] H. Niu, P.P. Zuo, W.Z. Shen, S.J. Qu, A comprehensive investigation on the chemical structure character of spinnable pitch for improving and optimizing the oxidative stabilization of coal tar pitch-based fiber, Polymer 224 (2021) 123737.
[24] B.J. Yu, C.Y. Wang, M.M. Chen, J.M. Zheng, J. Qi, Two-step chemical conversion of coal tar pitch to isotropic spinnable pitch, Fuel Process. Technol. 104 (2012) 155-159.
[25] I.C. Lewis, Thermal polymerization of aromatic hydrocarbons, Carbon 18 (3) (1980) 191-196.
[26] M. S. Hosseini, P. Chartrand, Critical assessment of thermodynamic properties of important polycyclic aromatic hydrocarbon compounds (PAHs) in coal tar pitch at typical temperature ranges of the carbonization process, Calphad 74 (2021) 102278.
[27] J. Wang, L. Yan, B.H. Liu, Q.J. Ren, L.L. Fan, Z.Q. Shi, Q.Y. Zhang, A solvothermal pre-oxidation strategy converting pitch from soft carbon to hard carbon for enhanced sodium storage, Chin. Chem. Lett. 34 (4) (2023) 107526.
[28] D. Liu, B. Lou, G.K. Chang, Y.D. Zhang, R. Yu, Z.H. Li, C.C. Wu, M. Li, Q.T. Chen, Study on effect of cross-linked structures induced by oxidative treatment of aromatic hydrocarbon oil on subsequent carbonized behaviors, Fuel 231 (2018) 495-506.
[29] R. Xu, Z.L. Yi, M.X. Song, J.P. Chen, X.X. Wei, F.Y. Su, L.Q. Dai, G.H. Sun, F. Yang, L.J. Xie, C.M. Chen, Boosting sodium storage performance of hard carbons by regulating oxygen functionalities of the cross-linked asphalt precursor, Carbon 206 (2023) 94-104.
[30] Y.X. Lu, C.L. Zhao, X.G. Qi, Y.R. Qi, H. Li, X.J. Huang, L.Q. Chen, Y.S. Hu, Pre-oxidation-tuned microstructures of carbon anodes derived from pitch for enhancing Na storage performance, Adv. Energy Mater. 8 (27) (2018) 1800108.
[31] L.C. Ji, Y. Zhao, L.J. Cao, Y. Li, C.L. Ma, X.G. Qi, Z.P. Shao, A fundamental understanding of structure evolution in the synthesis of hard carbon from coal tar pitch for high-performance sodium storage, J. Mater. Chem. A 11 (48) (2023) 26727-26741.
[32] I. Mochida, C.H. Ku, Y. Korai, Anodic performance and insertion mechanism of hard carbons prepared from synthetic isotropic pitches, Carbon 39 (3) (2001) 399-410.
[33] P.Y. Zhao, J.J. Tang, C.Y. Wang, A low-cost attempt to improve electrochemical performances of pitch-based hard carbon anodes in lithium-ion batteries by oxidative stabilization, J. Solid State Electrochem. 21 (2) (2017) 555-562.
[34] R.Q. Chen, Y.C. Guo, Y.Z. Zhang, C.Y. Shen, Y.L. Wang, L. Zhan, Reaction mechanism of ethylene tar in the air atmosphere, Fuel 353 (2023) 129146.
[35] T.R. Guo, R.Q. Chen, W. Gao, Y.L. Wang, L. Zhan, The oxidation reaction mechanism and its kinetics for a carbonaceous precursor prepared from ethylene tar for use as an anode material for lithium-ion batteries, N. Carbon Mater. 39 (2) (2024) 354-366.
[36] W.J. Zhang, T.H. Li, M. Lu, C.L. Hou, A comparative study of the characteristics and carbonization behaviors of three modified coal tar pitches, N. Carbon Mater. 28 (2) (2013) 140-144.
[37] Y.S. Peng, J.X. Yang, K. Shi, J.G. Guo, H. Zhu, X.K. Li, Effects of the degree of oxidation of pitch fibers on their stabilization and carbonization behaviors, N. Carbon Mater. 35 (6) (2020) 722-730.
[38] H.Y. Guo, Y.Y. Li, C.L. Wang, L. He, C. Li, Y.Q. Guo, Y. Zhou, Effect of the air oxidation stabilization of pitch on the microstructure and sodium storage of hard carbons, N. Carbon Mater. 36 (6) (2021) 1073-1078.
[39] H.A. Akrami, M.F. Yardim, A. Akar, E. Ekinci, FT-i.r. characterization of pitches derived from Avgamasya asphaltite and Raman-Dincer heavy crude, Fuel 76 (14-15) (1997) 1389-1394.
[40] B. Muik, B. Lendl, A. Molina-Diaz, M.J. Ayora-Canada, Direct monitoring of lipid oxidation in edible oils by Fourier transform Raman spectroscopy, Chem. Phys. Lipids 134 (2) (2005) 173-182.
[41] J.J. Fernandez, A. Figueiras, M. Granda, J. Bermejo, R. Menendez, Modification of coal-tar pitch by air-blowing-I. variation of pitch composition and properties, Carbon 33 (3) (1995) 295-307.
[42] K. Yanagisawa, T. Suzuki, Carbonization of oxidized mesophase pitches originating from petroleum and coal tar, Fuel 72 (1) (1993) 25-30.
[43] J. Alcaniz-Monge, D. Cazorla-Amoros, A. Linares-Solano, Characterisation of coal tar pitches by thermal analysis, infrared spectroscopy and solvent fractionation, Fuel 80 (1) (2001) 41-48.
[44] B.H. Kim, J.H. Kim, J.G. Kim, M.J. Bae, J.S. Im, C.W. Lee, S. Kim, Electrochemical and structural properties of lithium battery anode materials by using a molecular weight controlled pitch derived from petroleum residue, J. Ind. Eng. Chem. 41 (2016) 1-9.
[45] S. Yoon, H. Kim, S.M. Oh, Surface modification of graphite by coke coating for reduction of initial irreversible capacity in lithium secondary batteries, J. Power Sources 94 (1) (2001) 68-73.
[46] S. Ko, J.E. Choi, C.W. Lee, Y.P. Jeon, Modified oxidative thermal treatment for the preparation of isotropic pitch towards cost-competitive carbon fiber, J. Ind. Eng. Chem. 54 (2017) 252-261.
[47] B. Petrova, T. Budinova, N. Petrov, M.F. Yardim, E. Ekinci, M. Razvigorova, Effect of different oxidation treatments on the chemical structure and properties of commercial coal tar pitch, Carbon 43 (2) (2005) 261-267.
[48] G.M. Yuan, X.K. Li, X.Q. Xiong, Z.J. Dong, A. Westwood, B.L. Li, C. Ye, G.Z. Ma, Z.W. Cui, Y. Cong, J. Zhang, Y.J. Li, A comprehensive study on the oxidative stabilization of mesophase pitch-based tape-shaped thick fibers with oxygen, Carbon 115 (2017) 59-76.
[49] F. Fanjul, M. Granda, R. Santamaria, R. Menendez, On the chemistry of the oxidative stabilization and carbonization of carbonaceous mesophase, Fuel 81 (16) (2002) 2061-2070.
[50] H. Ghaedi, M. Ayoub, S. Sufian, B. Lal, Y. Uemura, Thermal stability and FT-IR analysis of Phosphonium-based deep eutectic solvents with different hydrogen bond donors, J. Mol. Liq. 242 (2017) 395-403.
[51] T. Kondratenko, O. Ovchinnikov, I. Grevtseva, M. Smirnov, O. Erina, V. Khokhlov, B. Darinsky, E. Tatianina, Thioglycolic acid FTIR spectra on Ag₂S quantum dots interfaces, Materials 13 (4) (2020) 909.
[52] G.M.S. El-Bahy, FTIR and Raman spectroscopic study of Fenugreek (Trigonella foenum graecum L.) seeds, J. Appl. Spectrosc. 72 (1) (2005) 111-116.
[53] M.D. Guillen, C. Diaz, C.G. Blanco, Characterization of coal tar pitches with different softening points by 1 H NMR Role of the different kinds of protons in the thermal process, Fuel Process. Technol. 58 (1) (1998) 1-15.
[54] C. Diaz, C.G. Blanco, NMR: a powerful tool in the characterization of coal tar pitch, Energy Fuels 17 (4) (2003) 907-913.
[55] S.J. Lee, M. Nishizawa, I. Uchida, Fabrication of mesophase pitch carbon thin film electrodes and the effect of heat treatment on electrochemical lithium insertion and extraction, Electrochim. Acta 44 (14) (1999) 2379-2383.
[56] L.B. Ebert, J.C. Scanlon, D.R. Mills, X-ray diffraction of n-paraffins and stacked aromatic molecules: insights into the structure of petroleum asphaltenes, Liq. Fuel. Technol. 2 (3) (1984) 257-286.
[57] H.L. Zhang, S.H. Liu, F. Li, S. Bai, C. Liu, J. Tan, H.M. Cheng, Electrochemical performance of pyrolytic carbon-coated natural graphite spheres, Carbon 44 (11) (2006) 2212-2218.
[58] B.H. Kim, J.H. Kim, J.G. Kim, J.S. Im, C.W. Lee, S. Kim, Controlling the electrochemical properties of an anode prepared from pitch-based soft carbon for Li-ion batteries, J. Ind. Eng. Chem. 45 (2017) 99-104.
[59] N. Shimodaira, M.S. A, Raman spectroscopic investigations of activated carbon materials, 92 (2) (2002) 902-909.
[60] S. Potgieter-Vermaak, N. Maledi, N. Wagner, J.H.P. Van Heerden, R. Van Grieken, J.H. Potgieter, Raman spectroscopy for the analysis of coal: a review, J. Raman Spectrosc. 42 (2) (2011) 123-129.
[61] C.D. Sheng, Char structure characterised by Raman spectroscopy and its correlations with combustion reactivity, Fuel 86 (15) (2007) 2316-2324.
[62] A. Sadezky, H. Muckenhuber, H. Grothe, R. Niessner, U. Poschl, Raman microspectroscopy of soot and related carbonaceous materials: spectral analysis and structural information, Carbon 43 (8) (2005) 1731-1742.
[63] Y. Wang, D.C. Alsmeyer, R.L. McCreery, Raman spectroscopy of carbon materials: structural basis of observed spectra, Chem. Mater. 2 (5) (1990) 557-563.
[64] J. Xu, H. Tang, S. Su, J.W. Liu, K. Xu, K. Qian, Y. Wang, Y.B. Zhou, S. Hu, A.C. Zhang, J. Xiang, A study of the relationships between coal structures and combustion characteristics: the insights from micro-Raman spectroscopy based on 32 kinds of Chinese coals, Appl. Energy 212 (2018) 46-56.
[65] O. Beyssac, B. Goffe, J.P. Petitet, E. Froigneux, M. Moreau, J.N. Rouzaud, On the characterization of disordered and heterogeneous carbonaceous materials by Raman spectroscopy, Spectrochim. Acta Mol. Biomol. Spectrosc. 59 (10) (2003) 2267-2276.
[66] Y.A. Abdu, Raman micro-spectroscopy of nanodiamonds from the Kapoeta meteorite, Diam. Relat. Mater. 118 (2021) 108536.
[67] T. Lopez-Rios, E. Sandre, S. Leclercq, E. Sauvain, Polyacetylene in diamond films evidenced by surface enhanced Raman scattering, Phys. Rev. Lett. 76 (26) (1996) 4935-4938.
[68] A. C. Ferrari, J. Robertson, Origin of the 1150-cm-1 Raman mode in nanocrystalline diamond, Phys. Rev. B 63 (12) (2001) 121405.
[69] X.J. Li, J.I. Hayashi, C.Z. Li, FT-Raman spectroscopic study of the evolution of char structure during the pyrolysis of a Victorian brown coal, Fuel 85 (12-13) (2006) 1700-1707.
[70] J. Xu, X.R. Xiang, K. Xu, L.M. He, H.D. Han, S. Su, Y. Wang, S. Hu, J. Xiang, Developing micro-Raman spectroscopy for char structure characterization in the scale of micro- and bulk: a case study of Zhundong coal pyrolysis, Fuel 291 (2021) 120168.
[71] M. Shi, Y.Z. Chen, H. Wen, Y.N. Liu, One-step heat treatment to process semi-coke powders as an anode material with superior rate performance for Li-ion batteries, RSC Adv. 8 (72) (2018) 41207-41217.
[72] I.C. Lewis, Chemistry of pitch carbonization, Fuel 66 (11) (1987) 1527-1531.
[73] L. Bokobza, J.L. Bruneel, M. Couzi, Raman spectroscopic investigation of carbon-based materials and their composites. Comparison between carbon nanotubes and carbon black, Chem. Phys. Lett. 590 (2013) 153-159.
[74] B. Lou, D. Liu, Y.J. Duan, X.L. Hou, Y.D. Zhang, Z.H. Li, Z.W. Wang, M. Li, Structural modification of petroleum pitch induced by oxidation treatment and its relevance to carbonization behaviors, Energy Fuels 31 (9) (2017) 9052-9066.
[75] E.R. Vorpagel, J.G. Lavin, Most stable configurations of polynuclear aromatic hydrocarbon molecules in pitches via molecular modelling, Carbon 30 (7) (1992) 1033-1040.
[76] I. Mochida, S.H. Yoon, Y. Korai, Mesoscopic structure and properties of liquid crystalline mesophase pitch and its transformation into carbon fiber, Chem. Rec. 2 (2) (2002) 81-101.
[77] P.C. Chen, S. Fatayer, B. Schuler, J.N. Metz, L. Gross, N. Yao, Y.L. Zhang, The role of methyl groups in the early stage of thermal polymerization of polycyclic aromatic hydrocarbons revealed by molecular imaging, Energy Fuels 35 (3) (2021) 2224-2233.
[78] L. Zhang, C.J. Liu, Y. Jia, Y.D. Mu, Y. Yan, P.C. Huang, Pyrolytic modification of heavy coal tar by multi-polymer blending: preparation of ordered carbonaceous mesophase, Polymers 16 (1) (2024) 161.
[79] A. Jana, L.T. Kearney, A.K. Naskar, J.C. Grossman, N. Ferralis, Effect of methyl groups on formation of ordered or layered graphitic materials from aromatic molecules, Small 19 (43) (2023) e2302985.
[80] A. Annamraju, G.S. Jung, S. Bhagia, J.T. Damron, M.R. Ryder, M.A. Arnould, E. Cakmak, F. Vautard, R.M. Paul, S. Irle, N.C. Gallego, E.L. Curzio, On the role of methyl groups in the molecular architectures of mesophase pitches, Fuel 357 (2024) 129976.
[81] R. E. Franklin, Crystallite growth in graphitizing and non-graphitizing carbons, Proc. Roy. Soc. Lond. A 209 (1097) (1951) 196-218.

Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products

Effect of introducing oxygen into ethylene tar pitches on their carbonaceous products

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[15]	Amonrat Thangthong, Wuttichai Roschat, Phongsakorn Pholsupho, Aekkaphon Thammayod, Sunti Phewphong, Tappagorn Leelatam, Preecha Moonsin, Boonyawan Yoosuk, Pathompong Janetaisong, Vinich Promarak. Physicochemical properties of lard oil and rubber seed oil blends and their comprehensive characterization[J]. 中国化学工程学报, 2024, 75(11): 1-13.