In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors

doi:10.1016/j.cjche.2024.11.023

中国化学工程学报 ›› 2025, Vol. 80 ›› Issue (4): 315-327.DOI: 10.1016/j.cjche.2024.11.023

In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors

Yahui Gao^1,2, Gendi Song¹, Yanjie Xu^1,2, Yuyu Sun¹, Yong Feng¹, Huijun Tan³, Wenjie Tian^1,2

1 School of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang 471023, China;
2 Henan Key Laboratory of Green Building Materials Manufacturing and Intelligent Equipment, Luoyang 471023, China;
3 School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

收稿日期:2024-08-08 修回日期:2024-09-30 接受日期:2024-11-27 出版日期:2025-04-28 发布日期:2025-03-04
通讯作者: Yahui Gao,E-mail:gaoyahui68@163.com;Gendi Song,E-mail:songgendi@lit.edu.cn;Huijun Tan,E-mail:sophie93@sjtu.edu.cn;Wenjie Tian,E-mail:twj7210@126.com
基金资助:
The work was supported by the National Natural Science Foundation of China (31900005), the Fund of Science and Technology Department of Henan Province (242102231001, 242102320362, 242102320157), the Fund of Program for Innovative Research Team (in Science and Technology) in University of Henan Province (23IRTSTHN009), Fund of Key Scientific Research Projects of Higher Education Institutions in Henan Province (22A150048).

In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors

Yahui Gao^1,2, Gendi Song¹, Yanjie Xu^1,2, Yuyu Sun¹, Yong Feng¹, Huijun Tan³, Wenjie Tian^1,2

1 School of Environmental Engineering and Chemistry, Luoyang Institute of Science and Technology, Luoyang 471023, China;
2 Henan Key Laboratory of Green Building Materials Manufacturing and Intelligent Equipment, Luoyang 471023, China;
3 School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Received:2024-08-08 Revised:2024-09-30 Accepted:2024-11-27 Online:2025-04-28 Published:2025-03-04
Contact: Yahui Gao,E-mail:gaoyahui68@163.com;Gendi Song,E-mail:songgendi@lit.edu.cn;Huijun Tan,E-mail:sophie93@sjtu.edu.cn;Wenjie Tian,E-mail:twj7210@126.com
Supported by:
The work was supported by the National Natural Science Foundation of China (31900005), the Fund of Science and Technology Department of Henan Province (242102231001, 242102320362, 242102320157), the Fund of Program for Innovative Research Team (in Science and Technology) in University of Henan Province (23IRTSTHN009), Fund of Key Scientific Research Projects of Higher Education Institutions in Henan Province (22A150048).

摘要/Abstract

摘要： By enhancing surface interaction between metal oxide particles and carbon-based materials, it can effectively improve Faraday capacitance and conductivity, ultimately achieving high energy density with sufficient redox reactions in supercapacitors. Through a gentle biomineralization process and subsequent thermal reduction strategy, we successfully prepared the graphene oxide (GO) wrapping mixed-valence manganese oxides (MnO_x) and S, P self-codoped carbon matrix porous composite (MnO_x@SPC@reduced graphene oxide (RGO)). During the biomineralization process of engineered Pseudomonas sp. (M1) cells, GO nanosheets functioned as the ‘soil’ to adsorb Mn²⁺ ion and uniformly disperse biogenic Mn oxides (BMO). After undergoing annealing, the MnO_x nanoparticles were evenly wrapped with graphene, resulting in the creation of the MnO_x@SPC@RGO3 composite. This composite possesses strong C—O—Mn bond interfaces, numerous electroactive sites, and a uniform pore structure. By optimizing the synergistic interaction between the highly conductive graphene and the remarkable surface capacitance of MnO_x, the MnO_x@SPC@RGO3 electrode, with its intercalation Faraday reactions mechanism of Mn²⁺ ⇌ Mn³⁺ and Mn³⁺ ⇌ Mn⁴⁺ transformations, exhibits an outstanding specific capacity (448.3 F·g^-1 at 0.5 A·g^-1), multiplying performance (340.5 F·g^-1 at 10 A·g^-1), and cycling stability (93.8% retention after 5000 cycles). Moreover, the asymmetric all-solid-state supercapacitors of MnO_x@SPC@RGO3//PC exhibit an exceptional energy density of 64.8 W·h·kg^-1 and power density of 350 W·kg^-1, as well as a long lifespan with capacitance retention of 92.5% after 10000 cycles. In conclusion, the synthetic route utilizing biomineralization and thermal reduction exhibits significant potential for exploiting high-performance electrode materials in all-solid-state supercapacitor applications.

关键词: Electrochemistry, Biological engineering, Nanomaterials, Graphene oxide, Manganese oxides, Supercapacitors

Abstract: By enhancing surface interaction between metal oxide particles and carbon-based materials, it can effectively improve Faraday capacitance and conductivity, ultimately achieving high energy density with sufficient redox reactions in supercapacitors. Through a gentle biomineralization process and subsequent thermal reduction strategy, we successfully prepared the graphene oxide (GO) wrapping mixed-valence manganese oxides (MnO_x) and S, P self-codoped carbon matrix porous composite (MnO_x@SPC@reduced graphene oxide (RGO)). During the biomineralization process of engineered Pseudomonas sp. (M1) cells, GO nanosheets functioned as the ‘soil’ to adsorb Mn²⁺ ion and uniformly disperse biogenic Mn oxides (BMO). After undergoing annealing, the MnO_x nanoparticles were evenly wrapped with graphene, resulting in the creation of the MnO_x@SPC@RGO3 composite. This composite possesses strong C—O—Mn bond interfaces, numerous electroactive sites, and a uniform pore structure. By optimizing the synergistic interaction between the highly conductive graphene and the remarkable surface capacitance of MnO_x, the MnO_x@SPC@RGO3 electrode, with its intercalation Faraday reactions mechanism of Mn²⁺ ⇌ Mn³⁺ and Mn³⁺ ⇌ Mn⁴⁺ transformations, exhibits an outstanding specific capacity (448.3 F·g^-1 at 0.5 A·g^-1), multiplying performance (340.5 F·g^-1 at 10 A·g^-1), and cycling stability (93.8% retention after 5000 cycles). Moreover, the asymmetric all-solid-state supercapacitors of MnO_x@SPC@RGO3//PC exhibit an exceptional energy density of 64.8 W·h·kg^-1 and power density of 350 W·kg^-1, as well as a long lifespan with capacitance retention of 92.5% after 10000 cycles. In conclusion, the synthetic route utilizing biomineralization and thermal reduction exhibits significant potential for exploiting high-performance electrode materials in all-solid-state supercapacitor applications.

Key words: Electrochemistry, Biological engineering, Nanomaterials, Graphene oxide, Manganese oxides, Supercapacitors

Yahui Gao, Gendi Song, Yanjie Xu, Yuyu Sun, Yong Feng, Huijun Tan, Wenjie Tian. In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors[J]. 中国化学工程学报, 2025, 80(4): 315-327.

参考文献

[1] P. Lamba, P. Singh, P. Singh, P. Singh, Bharti, A. Kumar, M. Gupta, Y. Kumar, Recent advancements in supercapacitors based on different electrode materials: Classifications, synthesis methods and comparative performance, J. Energy Storage 48 (2022) 103871.
[2] H.W. Hu, C. Yang, F.Y. Chen, J.H. Li, X.L. Jia, Y.T. Wang, X.L. Zhu, Z.M. Man, G. Wu, W.X. Chen, High-entropy engineering reinforced surface electronic states and structural defects of hierarchical metal Oxides@Graphene fibers toward high-performance wearable supercapacitors, Adv. Mater. 36 (35) (2024) e2406483.
[3] M.N. Sakib, S. Ahmed, S.M. Sultan Mahmud Rahat, S.B. Shuchi, A review of recent advances in manganese-based supercapacitors, J. Energy Storage 44 (2021) 103322.
[4] S. Li, L.L. Yu, Y.T. Shi, J. Fan, R.B. Li, G.D. Fan, W.L. Xu, J.T. Zhao, Greatly enhanced faradic capacities of 3D porous Mn₃O₄/G composites as lithium-ion anodes and supercapacitors by C-O-Mn bonding, ACS Appl. Mater. Interfaces 11 (10) (2019) 10178-10188.
[5] L. Shan, Y. Zhang, Y. Xu, M.J. Gao, T. Xu, C.L. Si, Wood-based hierarchical porous nitrogen-doped carbon/manganese dioxide composite electrode materials for high-rate supercapacitor, Adv. Compos. Hybrid Mater. 6 (5) (2023) 174.
[6] Y. Ding, Y.C. Li, L. Wang, X.H. Han, L.J. Zhu, S.R. Wang, A novel approach for preparing nitrogen-doped porous nanocomposites for supercapacitors, Fuel 304 (2021) 121449.
[7] Y.H. Lin, T.Y. Wei, H.C. Chien, S.Y. Lu, Manganese oxide/carbon aerogel composite: an outstanding supercapacitor electrode material, Adv. Energy Mater. 1 (5) (2011) 901-907.
[8] H.N. Jia, Z.Y. Wang, C. Li, X.Q. Si, X.H. Zheng, Y.F. Cai, J.H. Lin, H.Y. Liang, J.L. Qi, J. Cao, J.C. Feng, W.D. Fei, Designing oxygen bonding between reduced graphene oxide and multishelled Mn₃O₄ hollow spheres for enhanced performance of supercapacitors, J. Mater. Chem. A 7 (12) (2019) 6686-6694.
[9] B.S. Singu, E.S. Goda, K.R. Yoon, Carbon Nanotube-Manganese oxide nanorods hybrid composites for high-performance supercapacitor materials, J. Ind. Eng. Chem. 97 (2021) 239-249.
[10] S.F. Zhang, L. Li, Y.L. Liu, Q.L. Li, Nanocellulose/carbon nanotube/manganese dioxide composite electrodes with high mass loadings for flexible supercapacitors, Carbohydr. Polym. 326 (2024) 121661.
[11] M.Y. Wang, Y. Huang, N. Zhang, K. Wang, X.F. Chen, X. Ding, A facile synthesis of controlled Mn₃O₄ hollow polyhedron for high-performance lithium-ion battery anodes, Chem. Eng. J. 334 (2018) 2383-2391.
[12] M.X. Liu, M.C. Shi, W.J. Lu, D.Z. Zhu, L.C. Li, L.H. Gan, Core-shell reduced graphene oxide/MnOx @carbon hollow nanospheres for high performance supercapacitor electrodes, Chem. Eng. J. 313 (2017) 518-526.
[13] D. Malavekar, S. Pujari, S. Jang, S. Bachankar, J.H. Kim, Recent development on transition metal oxides-based core-shell structures for boosted energy density supercapacitors, Small 20 (31) (2024) e2312179.
[14] W. Guo, C. Yu, S.F. Li, Z. Wang, J.H. Yu, H.W. Huang, J.S. Qiu, Strategies and insights towards the intrinsic capacitive properties of MnO₂ for supercapacitors: Challenges and perspectives, Nano Energy 57 (2019) 459-472.
[15] C.A. Romano, M.W. Zhou, Y. Song, V.H. Wysocki, A.C. Dohnalkova, L. Kovarik, L. Pasa-Tolic, B.M. Tebo, Biogenic manganese oxide nanoparticle formation by a multimeric multicopper oxidase Mnx, Nat. Commun. 8 (1) (2017) 746.
[16] S. Comert, O. Tepe, Production and characterization of biogenic manganese oxides by manganese-adapted Pseudomonas putida NRRL B-14878, geomicrobiol j 37 (8) (2020) 753-763.
[17] R.Q. Wu, H.B. Wu, X.B. Jiang, J.Y. Shen, M. Faheem, X.Y. Sun, J.S. Li, W.Q. Han, L.J. Wang, X.D. Liu, The key role of biogenic manganese oxides in enhanced removal of highly recalcitrant 1, 2, 4-triazole from bio-treated chemical industrial wastewater, Environ. Sci. Pollut. Res. Int. 24 (11) (2017) 10570-10583.
[18] Z. Zhang, Z.M. Zhang, H. Chen, J. Liu, C. Liu, H. Ni, C.S. Zhao, M. Ali, F. Liu, L. Li, Surface Mn(II) oxidation actuated by a multicopper oxidase in a soil bacterium leads to the formation of manganese oxide minerals, Sci. Rep. 5 (2015) 10895.
[19] S. Namgung, C.M. Chon, G. Lee, Formation of diverse Mn oxides: a review of bio/geochemical processes of Mn oxidation, Geosci. J. 22 (2) (2018) 373-381.
[20] J. Liu, T. Gu, L. Li, L. Li, Synthesis of MnO/C/NiO-doped porous Multiphasic composites for lithium-ion batteries by biomineralized Mn oxides from engineered Pseudomonas putida cells, Nanomaterials 11 (2) (2021) 361.
[21] B.P. Hahn, J.W. Long, D.R. Rolison, Something from nothing: enhancing electrochemical charge storage with cation vacancies, Acc. Chem. Res. 46 (5) (2013) 1181-1191.
[22] S. Yi, L. Wang, X. Zhang, C. Li, W.J. Liu, K. Wang, X.Z. Sun, Y.N. Xu, Z.X. Yang, Y. Cao, J. Sun, Y.W. Ma, Cationic intermediates assisted self-assembly two-dimensional Ti₃C₂T_x/rGO hybrid nanoflakes for advanced lithium-ion capacitors, Sci. Bull. 66 (9) (2021) 914-924.
[23] P.H. Chen, W.Y. Zhou, Z.J. Xiao, S.Q. Li, H.L. Chen, Y.C. Wang, Z.B. Wang, W. Xi, X.G. Xia, S.S. Xie, In situ anchoring MnO nanoparticles on self-supported 3D interconnected graphene scroll framework: a fast kinetics boosted ultrahigh-rate anode for Li-ion capacitor, Energy Storage Mater. 33 (2020) 298-308.
[24] G.Z. Jin, X.X. Xiao, S. Li, K.M. Zhao, Y.Z. Wu, D. Sun, F. Wang, Strongly coupled graphene/Mn₃O₄ composite with enhanced electrochemical performance for supercapacitor electrode, Electrochim. Acta 178 (2015) 689-698.
[25] F.C. Boogerd, J.P. de Vrind, Manganese oxidation by leptothrix Discophora, J. Bacteriol. 169 (2) (1987) 489-494.
[26] Y.H. Gao, L. Wang, F. Wang, Y.Y. Sun, Y.J. Xu, J. Li, L. Wang, Z.S. Lu, Ball milling combined with activation preparation of honeycomb-like porous carbon derived from peony seed shell for high-performance supercapacitors, J. Mater. Sci. Mater. Electron. 33 (16) (2022) 13023-13039.
[27] D. Li, M.B. Muller, S. Gilje, R.B. Kaner, G.G. Wallace, Processable aqueous dispersions of graphene nanosheets, Nat. Nanotechnol. 3 (2) (2008) 101-105.
[28] G.N. Liang, Y. Yang, S.M. Wu, Y.H. Jiang, Y.F. Xu, The generation of biogenic manganese oxides and its application in the removal of As(III) in groundwater, Environ. Sci. Pollut. Res. Int. 24 (21) (2017) 17935-17944.
[29] Y. Ding, L.X. Dai, R. Wang, H.X. Wang, H.B. Zhang, W. Jiang, J. Tang, S.Q. Zang, Bio-inspired Mn₃O₄@N, P-doped carbon cathode for 2.6 V flexible aqueous asymmetric supercapacitors, Chem. Eng. J. 407 (2021) 126874.
[30] F.M. Wu, J.P. Gao, X.G. Zhai, M.H. Xie, Y. Sun, H.Y. Kang, Q. Tian, H.X. Qiu, Hierarchical porous carbon microrods derived from albizia flowers for high performance supercapacitors, Carbon 147 (2019) 242-251.
[31] W.J. Liu, X. Zhang, Y.N. Xu, L. Wang, Z. Li, C. Li, K. Wang, X.Z. Sun, Y.B. An, Z.S. Wu, Y.W. Ma, 2D graphene/MnO heterostructure with strongly stable interface enabling high-performance flexible solid-state lithium-ion capacitors, Adv. Funct. Mater. 32 (30) (2022) 2202342.
[32] C.N. Butterfield, A.V. Soldatova, S.W. Lee, T.G. Spiro, B.M. Tebo, Mn(II, III) oxidation and MnO₂ mineralization by an expressed bacterial multicopper oxidase, Proc. Natl. Acad. Sci. USA 110 (29) (2013) 11731-11735.
[33] Y.L. Qin, B.W. Wang, S.P. Jiang, Q.S. Jiang, C.H. Huang, H.C. Chen, Strongly anchored MnO nanoparticles on graphene as high-performance anode materials for lithium-ion batteries, Ionics 26 (7) (2020) 3315-3323.
[34] Y. Zhang, P.H. Chen, X. Gao, B. Wang, H. Liu, H. Wu, H.K. Liu, S.X. Dou, Nitrogen-doped graphene ribbon assembled core-sheath MnO@Graphene scrolls as hierarchically ordered 3D porous electrodes for fast and durable lithium storage, Adv. Funct. Mater. 26 (43) (2016) 7754-7765.
[35] Q.L. Fang, X.F. Zhou, W. Deng, Y.W. Liu, Z. Zheng, Z.P. Liu, Nitrogen-doped graphene nanoscroll foam with high diffusion rate and binding affinity for removal of organic pollutants, Small 13 (14) (2017) 1603779.
[36] T. Sharifi, E. Gracia-Espino, H. Reza Barzegar, X.E. Jia, F. Nitze, G.Z. Hu, P. Nordblad, C.W. Tai, T. Wagberg, Formation of nitrogen-doped graphene nanoscrolls by adsorption of magnetic γ-Fe₂O₃ nanoparticles, Nat. Commun. 4 (2013) 2319.
[37] N. Okibe, M. Maki, K. Sasaki, T. Hirajima, Mn(II)-oxidizing activity of Pseudomonas sp. strain MM1 is involved in the formation of massive Mn sediments around sambe hot springs in Japan, Mater. Trans. 54 (10) (2013) 2027-2031.
[38] M.Y. Gao, X.F. Wu, H.F. Qiu, Q.F. Zhang, K.K. Huang, S.H. Feng, Y. Yang, T.T. Wang, B. Zhao, Z.L. Liu, Reduced graphene oxide-mediated synthesis of Mn₃O₄ nanomaterials for an asymmetric supercapacitor cell, RSC Adv. 8 (37) (2018) 20661-20668.
[39] J. Yao, S.S. Yao, F. Gao, L.M. Duan, M.T. Niu, J.H. Liu, Reduced graphene oxide/Mn₃O₄ nanohybrid for high-rate pseduocapacitive electrodes, J. Colloid Interface Sci. 511 (2018) 434-439.
[40] J.F. Shi, M.X. Sun, H.M. Hu, One-step combustion synthesis of C-Mn₃O₄/MnO composites with high electrochemical performance for supercapacitor, Mater. Res. Express 6 (3) (2019) 035511.
[41] A. Gangwar, T. Das, S.K. Shaw, N.K. Prasad, Nanocomposite of (α-Mn₃O₄/MnO)@rGO as a high performance electrode material for supercapacitors, Electrochim. Acta 390 (2021) 138823.
[42] P.R. Garces Goncalves Jr, H.A. De Abreu, H.A. Duarte, Stability, structural, and electronic properties of hausmannite (Mn₃O₄) surfaces and their interaction with water, J. Phys. Chem. C 122 (36) (2018) 20841-20849.
[43] S.P. Rong, P.Y. Zhang, F. Liu, Y.J. Yang, Engineering crystal facet of α-MnO₂ nanowire for highly efficient catalytic oxidation of carcinogenic airborne formaldehyde, ACS Catal. 8 (4) (2018) 3435-3446.
[44] G.X. Zhu, W. Zhu, Y. Lou, J. Ma, W.Q. Yao, R.L. Zong, Y.F. Zhu, Encapsulate α-MnO₂ nanofiber within graphene layer to tune surface electronic structure for efficient ozone decomposition, Nat. Commun. 12 (1) (2021) 4152.
[45] E. Sohouli, K. Adib, B. Maddah, M. Najafi, Preparation of a supercapacitor electrode based on carbon nano-Onions/manganese dioxide/iron oxide nanocomposite, J. Energy Storage 52 (2022) 104987.
[46] M. Yang, D.S. Kim, S.B. Hong, J.W. Sim, J. Kim, S.S. Kim, B.G. Choi, MnO₂ nanowire/biomass-derived carbon from hemp stem for high-performance supercapacitors, Langmuir 33 (21) (2017) 5140-5147.
[47] A. Sumboja, C.Y. Foo, X. Wang, P.S. Lee, Large areal mass, flexible and free-standing reduced graphene oxide/manganese dioxide paper for asymmetric supercapacitor device, Adv. Mater. 25 (20) (2013) 2809-2815.
[48] Y.Z. Zhang, T. Cheng, Y. Wang, W.Y. Lai, H. Pang, W. Huang, A simple approach to boost capacitance: flexible supercapacitors based on manganese Oxides@MOFs via chemically induced in situ self-transformation, Adv. Mater. 28 (26) (2016) 5242-5248.
[49] Y.T. Hu, C. Guan, G.X. Feng, Q.Q. Ke, X.L. Huang, J. Wang, Flexible asymmetric supercapacitor based on structure-optimized Mn₃O₄/reduced graphene oxide nanohybrid paper with high energy and power density, Adv. Funct. Mater. 25 (47) (2015) 7291-7299.
[50] Y.S. Wu, R. Feng, C.J. Song, S.T. Xing, Y.Z. Gao, Z.C. Ma, Effect of reducing agent on the structure and activity of manganese oxide octahedral molecular sieve (OMS-2) in catalytic combustion of o-xylene, Catal. Today 281 (2017) 500-506.
[51] F. Gao, J.Y. Qu, Z.B. Zhao, Q. Zhou, B.B. Li, J.S. Qiu, A green strategy for the synthesis of graphene supported Mn₃O₄ nanocomposites from graphitized coal and their supercapacitor application, Carbon 80 (2014) 640-650.
[52] G.Z. Zhao, Y.J. Li, G. Zhu, J.Y. Shi, T. Lu, L.K. Pan, Biomass-based N, P, and S self-doped porous carbon for high-performance supercapacitors, ACS Sustainable Chem. Eng. (2019) acssuschemeng.9b00725.
[53] D.V. Lam, D.T. Dung, E. Roh, J.H. Kim, H. Kim, S.M. Lee, Metal-organic framework-templated graphitic carbon confining MnO/Mn₃O₄ nanoparticles via direct laser printing for electrocatalysis and supercapacitor, Adv. Mater. Interfaces 8 (22) (2021) 2101599.
[54] D. Zhou, H.M. Lin, F. Zhang, H. Niu, L.R. Cui, Q. Wang, F.Y. Qu, Freestanding MnO₂ nanoflakes/porous carbon nanofibers for high-performance flexible supercapacitor electrodes, Electrochim. Acta 161 (2015) 427-435.
[55] N.N. Song, Y. Wu, W.C. Wang, D. Xiao, H.J. Tan, Y.P. Zhao, Layer-by-layer in situ growth flexible polyaniline/graphene paper wrapped by MnO₂ nanoflowers for all-solid-state supercapacitor, Mater. Res. Bull. 111 (2019) 267-276.
[56] Y. Wang, W.H. Lai, N. Wang, Z. Jiang, X.Y. Wang, P.C. Zou, Z.Y. Lin, H.J. Fan, F.Y. Kang, C.P. Wong, C. Yang, A reduced graphene oxide/mixed-valence manganese oxide composite electrode for tailorable and surface mountable supercapacitors with high capacitance and super-long life, Energy Environ. Sci. 10 (4) (2017) 941-949.
[57] N. Zhao, L.B. Deng, D.W. Luo, P.X. Zhang, One-step fabrication of biomass-derived hierarchically porous carbon/MnO nanosheets composites for symmetric hybrid supercapacitor, Appl. Surf. Sci. 526 (2020) 146696.
[58] A.T. Chidembo, S.H. Aboutalebi, K. Konstantinov, C.J. Jafta, H.K. Liu, K.I. Ozoemena, In situ engineering of urchin-like reduced graphene oxide-Mn₂O₃-Mn₃O₄ nanostructures for supercapacitors, RSC Adv. 4 (2) (2014) 886-892.

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In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors

In-situ synthesis of mixed-valence manganese oxide@S, P self-codoped carbon@reduced graphene oxide composites by enhanced surface interaction for high-performance all-solid-state supercapacitors

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