Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins

摘要/Abstract

摘要： Since the production cost of biodiesel is now the main hurdle limiting their applicability in some areas, catalytic cracking reactions represent an alternative route to utilization of vegetable oils and animal fats. Hence, catalytic transformation of oils and fats was carried out in a laboratory-scale two-stage riser fluid catalytic cracking (TSRFCC) unit in this work. The results show that oils and fats can be used as FCC feed singly or co-feeding with vacuum gas oil (VGO), which can give high yield (by mass)of liquefied petroleum gas (LPG), C₂-C₄ olefins, for example 45% LPG, 47% C₂-C₄ olefins, and 77.6% total liquid yield produced with palm oil cracking. Co-feeding with VGO gives a high yield of LPG (39.1%) and propylene (18.1%). And oxygen element content is very low (about 0.5%) in liquid products, hence, oxygen is removed in the form of H₂O, CO and CO₂. At the same time, high concentration of aromatics (C₇-C₉ aromatics predominantly) in the gasoline fraction is obtained after TSRFCC reaction of palm oil, as a result of large amount of hydrogen-transfer, cyclization and aromatization reactions. Additionally, most of properties of produced gasoline and diesel oil fuel meet the requirements of national standards, containing little sulfur. So TSRFCC technology is thought to be an alternative processing technology leading to production of clean fuels and light olefins.

关键词: vegetable oil, animal fat, renewable resource, biodiesel, two-stage riser fluid catalytic cracking technology

Abstract: Since the production cost of biodiesel is now the main hurdle limiting their applicability in some areas, catalytic cracking reactions represent an alternative route to utilization of vegetable oils and animal fats. Hence, catalytic transformation of oils and fats was carried out in a laboratory-scale two-stage riser fluid catalytic cracking (TSRFCC) unit in this work. The results show that oils and fats can be used as FCC feed singly or co-feeding with vacuum gas oil (VGO), which can give high yield (by mass)of liquefied petroleum gas (LPG), C₂-C₄ olefins, for example 45% LPG, 47% C₂-C₄ olefins, and 77.6% total liquid yield produced with palm oil cracking. Co-feeding with VGO gives a high yield of LPG (39.1%) and propylene (18.1%). And oxygen element content is very low (about 0.5%) in liquid products, hence, oxygen is removed in the form of H₂O, CO and CO₂. At the same time, high concentration of aromatics (C₇-C₉ aromatics predominantly) in the gasoline fraction is obtained after TSRFCC reaction of palm oil, as a result of large amount of hydrogen-transfer, cyclization and aromatization reactions. Additionally, most of properties of produced gasoline and diesel oil fuel meet the requirements of national standards, containing little sulfur. So TSRFCC technology is thought to be an alternative processing technology leading to production of clean fuels and light olefins.

Key words: vegetable oil, animal fat, renewable resource, biodiesel, two-stage riser fluid catalytic cracking technology

田华, 李春义, 杨朝合, 山红红. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. , 2008, 16(3): 394-400.

TIAN Hua, LI Chunyi, YANG Chaohe, SHAN Honghong. Alternative Processing Technology for Converting Vegetable Oils and Animal Fats to Clean Fuels and Light Olefins[J]. , 2008, 16(3): 394-400.

参考文献

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