SCI和EI收录∣中国化工学会会刊

›› 2009, Vol. 17 ›› Issue (5): 773-780.

• • 上一篇    下一篇

Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins

屈一新, 彭少君, 王水, 张志强, 王际东   

  1. Beijing Key Laboratory of Bioprocess, Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • 收稿日期:2009-03-19 修回日期:2009-07-12 出版日期:2009-10-28 发布日期:2009-10-28
  • 通讯作者: WANG Jidong,E-mail:jidongwang1963@yahoo.com.cn
  • 基金资助:
    Supported by the National Basic Research Program of China (2007CB714300)

Kinetic Study of Esterification of Lactic Acid with Isobutanol and n-Butanol Catalyzed by Ion-exchange Resins

QU Yixin, PENG Shaojun, WANG Shui, ZHANG Zhiqiang, WANG Jidong   

  1. Beijing Key Laboratory of Bioprocess, Department of Chemical Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • Received:2009-03-19 Revised:2009-07-12 Online:2009-10-28 Published:2009-10-28
  • Supported by:
    Supported by the National Basic Research Program of China (2007CB714300)

摘要: The esterification reactions of lactic acid with isobutanol and n-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009.The influences of catalyst loading,stirrer speed,catalyst particle size,initial reactant molar ratio and temperature on the reaction rate have been examined.Experimental kinetic data were correlated by using the Pseudo-homogeneous,Langmuir-Hinshelwood and Eley-Rideal models.Nonideality of the liquid phase was taken into account by using activities instead of molar fractions.The activity coefficients were calculated according to the group contribution method UNIFAC.Provided that the nonideality of the liquid is taken into account,the esterification kinetics of lactic acid with isobutanol and n-butanol catalyzed by the acid ion-exchange resin can be described using all three models with reasonable errors.

关键词: kinetics, esterification, lactic acid, isobutanol, n-butanol, ion exchange resin

Abstract: The esterification reactions of lactic acid with isobutanol and n-butanol have been studied in the presence of acid ion-exchange resin Weblyst D009.The influences of catalyst loading,stirrer speed,catalyst particle size,initial reactant molar ratio and temperature on the reaction rate have been examined.Experimental kinetic data were correlated by using the Pseudo-homogeneous,Langmuir-Hinshelwood and Eley-Rideal models.Nonideality of the liquid phase was taken into account by using activities instead of molar fractions.The activity coefficients were calculated according to the group contribution method UNIFAC.Provided that the nonideality of the liquid is taken into account,the esterification kinetics of lactic acid with isobutanol and n-butanol catalyzed by the acid ion-exchange resin can be described using all three models with reasonable errors.

Key words: kinetics, esterification, lactic acid, isobutanol, n-butanol, ion exchange resin