Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure

›› 2009, Vol. 17 ›› Issue (6): 1009-1013.

Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure

李新学¹, 徐国民², 王彦伟¹, 胡一江¹

1. Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China;
2. No 4 Oil Production Company, Petrochina Daqing Oilfield, Daqing 163511, China

收稿日期:2009-04-13 修回日期:2009-08-23 出版日期:2009-12-28 发布日期:2009-12-28
通讯作者: LI Xinxue,E-mail:lxx1969@pku.org.cn

Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure

LI Xinxue¹, XU Guomin², WANG Yanwei¹, HU Yijiang¹

1. Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, China;
2. No 4 Oil Production Company, Petrochina Daqing Oilfield, Daqing 163511, China

Received:2009-04-13 Revised:2009-08-23 Online:2009-12-28 Published:2009-12-28

摘要/Abstract

摘要： Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylene glycol monoethyl ether [CH₃CH₂O(CH₂)₂O(CH₂)₂OH]+water from 293.15 to 333.15 K at atmospheric pressure,with a capillary pycnometer and Ubbelohde capillary viscometer respectively.From the experimental data,the excess molar volume V^E,viscosity deviation Δη,and the excess energy of activation for viscous flow ΔG^*E were calculated.These data were correlated by the Redlich-Kister type equations to obtain the coefficients and standard deviations.The results showed a strong molecular interaction between diethylene glycol monoethyl ether and water.

关键词: density, viscosity, diethylene glycol monoethyl ether, binary mixture, excess molar volume, viscosity deviation

Abstract: Densities and viscosities were measured as a function of composition for binary liquid mixture of diethylene glycol monoethyl ether [CH₃CH₂O(CH₂)₂O(CH₂)₂OH]+water from 293.15 to 333.15 K at atmospheric pressure,with a capillary pycnometer and Ubbelohde capillary viscometer respectively.From the experimental data,the excess molar volume V^E,viscosity deviation Δη,and the excess energy of activation for viscous flow ΔG^*E were calculated.These data were correlated by the Redlich-Kister type equations to obtain the coefficients and standard deviations.The results showed a strong molecular interaction between diethylene glycol monoethyl ether and water.

Key words: density, viscosity, diethylene glycol monoethyl ether, binary mixture, excess molar volume, viscosity deviation

李新学, 徐国民, 王彦伟, 胡一江. Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure[J]. , 2009, 17(6): 1009-1013.

LI Xinxue, XU Guomin, WANG Yanwei, HU Yijiang. Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure[J]. , 2009, 17(6): 1009-1013.

参考文献

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Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure

Density,Viscosity,and Excess Properties for Binary Mixture of Diethylene Glycol Monoethyl Ether+Water from 293.15 to 333.15 K at Atmospheric Pressure

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