A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell

›› 2010, Vol. 18 ›› Issue (6): 988-994.

A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell

包成¹, 苏庆泉¹, 米万良¹, 李志远¹, 毕全¹, 冀中华², 刘志祥³, 毛宗强³

1. Department of Thermal Science and Energy Engineering, School of Mechanical Engineering, University of Science & Technology Beijing, Beijing 100083, China;
2. Hanergy Technology Co., Ltd., Beijing 102209, China;
3. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

收稿日期:2010-04-12 修回日期:2010-06-03 出版日期:2010-12-28 发布日期:2010-12-28
通讯作者: BAO Cheng, E-mail: baocheng@me.ustb.edu.cn
基金资助:
Supported by the Beijing Municipal Major Science & Technology Project(D0406001000091);the National Natural Science Foundation of China(50706019)

A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell

BAO Cheng¹, SU Qingquan¹, MI Wanliang¹, LI Zhiyuan¹, BI Quan¹, JI Zhonghua², LIU Zhixiang³, MAO Zongqiang³

1. Department of Thermal Science and Energy Engineering, School of Mechanical Engineering, University of Science & Technology Beijing, Beijing 100083, China;
2. Hanergy Technology Co., Ltd., Beijing 102209, China;
3. Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Received:2010-04-12 Revised:2010-06-03 Online:2010-12-28 Published:2010-12-28
Supported by:
Supported by the Beijing Municipal Major Science & Technology Project(D0406001000091);the National Natural Science Foundation of China(50706019)

摘要/Abstract

摘要： A 10 kW-scale natural gas fueled proton exchange membrane fuel cell(PEMFC) distributed power plant is presented in this paper,which is designed for cogeneration of power and heat. With homemade catalysts for CO removal in a two-stage methanation process and integrated reactor in the fuel processing system,the reformed fuel with CO molar fraction less than 10^-5 is obtained for the fuel cell stack. Based on Matlab/Simulink/Stateflow and xPC Target platform,a rapid control prototype(RCP) is developed for real-time condition management,signal tracking and parameter tuning,data storing,and man-machine interaction. In a typical running with 4.3 kW stack power,the hydrogen production efficiency,gross power generation efficiency and heat recovery efficiency approach to 76%,41% and 50%,respectively. The peak stack power reaches 7.3 kW. Though there is still considerable distance to long-term operation at 10 kW-scale net power generation,it is a milestone for the PEMFC-based stationary application in China.

关键词: proton exchange membrane fuel cell, natural gas, 10kW-scale, power plant, two-stage methanation, xPC-based rapid control prototype

Abstract: A 10 kW-scale natural gas fueled proton exchange membrane fuel cell(PEMFC) distributed power plant is presented in this paper,which is designed for cogeneration of power and heat. With homemade catalysts for CO removal in a two-stage methanation process and integrated reactor in the fuel processing system,the reformed fuel with CO molar fraction less than 10^-5 is obtained for the fuel cell stack. Based on Matlab/Simulink/Stateflow and xPC Target platform,a rapid control prototype(RCP) is developed for real-time condition management,signal tracking and parameter tuning,data storing,and man-machine interaction. In a typical running with 4.3 kW stack power,the hydrogen production efficiency,gross power generation efficiency and heat recovery efficiency approach to 76%,41% and 50%,respectively. The peak stack power reaches 7.3 kW. Though there is still considerable distance to long-term operation at 10 kW-scale net power generation,it is a milestone for the PEMFC-based stationary application in China.

Key words: proton exchange membrane fuel cell, natural gas, 10kW-scale, power plant, two-stage methanation, xPC-based rapid control prototype

包成, 苏庆泉, 米万良, 李志远, 毕全, 冀中华, 刘志祥, 毛宗强. A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell[J]. , 2010, 18(6): 988-994.

BAO Cheng, SU Qingquan, MI Wanliang, LI Zhiyuan, BI Quan, JI Zhonghua, LIU Zhixiang, MAO Zongqiang. A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell[J]. , 2010, 18(6): 988-994.

参考文献

1 Fuel Cells 2000’s Worldwide Stationary Fuel Cell Installation database, [2010-04-12], http://www.fuelcells.org/info/databasefront.html.
2 Fuel Cells 2000, Fuel Cell Buses, Fuel Cell Cars, [2010-04-12], http://www.fuelcells.org/info/charts/buses.pdf. http://www.fuelcells.org/ info/charts/carchart.pdf.
3 Hou, M., “Status of development of fuel cell technologies”, Chinese J. Power Sources, 32, 649-654(2008).
4 Su, Q.Q, “Development direction of fuel cell in Japan and our thought”, Advanced Materials Industry, 10, 56-61(2005).
5 Gottesfeld, S., Pafford, J., “A new approach to the problem of carbon monoxide poisoning in fuel cells operating at low temperatures”, J. Electrochem. Soc., 135, 265l-2652(1988).
6 Li, Z.Y., Mi, W.L., Liu, S.B., Su, Q.Q., “CO deep removal with a method of two-stage methanation”, Int. J. Hydrogen Energy, 35, 2820-2823(2010).
7 Li, Z.Y., “Study on CO deep removal from natural gas reformate”, Ph.D. Thesis, University of Science and Technology Beijing, Beijing(2009).
8 Bao, C., Zhang, K.X., Ouyang, M.G., Yi, B.L., Ming, P.W., “Dynamic test and real-time control platform of anode recirculation for PEM fuel cell systems”, J. Fuel Cell Sci. Technol., 3, 333-345(2006).
9 The MathWorks, Inc., Stateflow, “Design and simulate state machines and control logic”, [2010-04-12], http://www.mathworks.com/products/ stateflow/.
10 Gasteiger, H.A., Markovic, N.M., Ross, P.N., Cairns, E.J., “CO electrooxidation on well-characterized Pt-Ru alloys”, J. Phys. Chem., 98, 617-625(1994)
11 Liang, Y.M., Zhang, H.M., Zhong, H.X., Zhu, X.B., Tian, Z.Q., Xu, D.Y., Yi, B.L., “Preparation and characterization of carbon-supported PtRulr catalyst with excellent CO-tolerant performance for protonexchange membrane fuel cells”, J. Catalysis, 238, 468-476(2006).
12 Uribe, F.A., Valerio, J.A., Garzon, F.H., Zawodzinski, T.A., “PEMFC reconfigured anodes for enhancing CO tolerance with air bleed”, Electrochemical and Solid State Letters, 7, A376-A379(2004).
13 Yu, H.M., Hou, Z.J., Bao, L.Y., Lin, Z.Y., “Composite anode for CO tolerance proton exchange membrane fuel cells”, J. Power Sources, 105, 52-57(2002).

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A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell

A 10kW-scale Distributed Power Plant of Natural Gas-Proton Exchange Membrane Fuel Cell

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