Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

›› 2011, Vol. 19 ›› Issue (1): 163-168.

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

舒庆^1,2, 高继贤¹, 廖玉会¹, 王金福¹

1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2. School of Material and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

收稿日期:2010-06-21 修回日期:2010-12-01 出版日期:2011-02-28 发布日期:2011-02-28
通讯作者: E-mail: wangjf@flotu.org

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

SHU Qing^1,2, GAO Jixian¹, LIAO Yuhui¹, WANG Jinfu¹

1. Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
2. School of Material and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

Received:2010-06-21 Revised:2010-12-01 Online:2011-02-28 Published:2011-02-28

摘要/Abstract

摘要： The kinetics of simultaneous transesterification and esterification with a carbon-based solid acid catalyst was studied.Two solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt.These catalysts were characterized on the basis of elemental analysis,acidity site concentration,the Brunauer-Emmett-Teller(BET)surface area and pore size.The kinetic parameters with the two catalysts were determined,and the reaction system can be described as a pseudo homogeneous catalyzed reaction.All the forward and reverse reactions follow second order kinetics.The calculated concentration values from the kinetic equations are in good agreement with experimental values.

关键词: biodiesel, carbon-based solid acid catalyst, heterogeneous catalysis, simultaneous transesterification and esterification reaction, kinetics

Abstract: The kinetics of simultaneous transesterification and esterification with a carbon-based solid acid catalyst was studied.Two solid acid catalysts were prepared by the sulfonation of carbonized vegetable oil asphalt and petroleum asphalt.These catalysts were characterized on the basis of elemental analysis,acidity site concentration,the Brunauer-Emmett-Teller(BET)surface area and pore size.The kinetic parameters with the two catalysts were determined,and the reaction system can be described as a pseudo homogeneous catalyzed reaction.All the forward and reverse reactions follow second order kinetics.The calculated concentration values from the kinetic equations are in good agreement with experimental values.

Key words: biodiesel, carbon-based solid acid catalyst, heterogeneous catalysis, simultaneous transesterification and esterification reaction, kinetics

舒庆, 高继贤, 廖玉会, 王金福. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. , 2011, 19(1): 163-168.

SHU Qing, GAO Jixian, LIAO Yuhui, WANG Jinfu. Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst[J]. , 2011, 19(1): 163-168.

参考文献

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Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

Reaction Kinetics of Biodiesel Synthesis from Waste Oil Using a Carbon-based Solid Acid Catalyst

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