Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids

Chinese Journal of Chemical Engineering ›› 2012, Vol. 20 ›› Issue (1): 130-139.

Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids

郑勇^1,2, 张锁江¹, 吕兴梅¹, 王倩¹, 左勇¹, 刘恋^1,2

1. Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing 100049, China

收稿日期:2011-11-18 修回日期:2011-12-12 出版日期:2012-02-28 发布日期:2012-05-03
通讯作者: ZHANG Suojiang,sjzhang@home.ipe.ac.cn
基金资助:
Supported by the National Basic Research Program of China (2009CB219901);the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (2012BAF03B01);the National Natural Science Foundation of China (20906096,20873152);the Open-end Fund of State Key Laboratory of Multiphase Complex Systems (MPCS-2011-D-06)

Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids

ZHENG Yong^1,2, ZHANG Suojiang¹, Lü Xingmei¹, WANG Qian¹, ZUO Yong¹, LIU Lian^1,2

1. Beijing Key Laboratory of Ionic Liquids Clean Process, State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China;
2. College of Chemistry and Chemical Engineering, Graduate University of Chinese Academy of Sciences, Beijing 100049, China

Received:2011-11-18 Revised:2011-12-12 Online:2012-02-28 Published:2012-05-03
Supported by:
Supported by the National Basic Research Program of China (2009CB219901);the National Key Technology Research and Development Program of the Ministry of Science and Technology of China (2012BAF03B01);the National Natural Science Foundation of China (20906096,20873152);the Open-end Fund of State Key Laboratory of Multiphase Complex Systems (MPCS-2011-D-06)

摘要/Abstract

摘要： Lewis acidic 1-allyl-3-methylimidazolium chloroaluminate ionic liquids were used as promising electrolytes in the low-temperature electrodeposition of aluminium.Systematic studies on deposition process have been performed by cyclic voltammetry and chronoamperometry.The surface morphology and X-ray diffraction(XRD) patterns of deposits prepared at different experimental conditions were also investigated.It was shown that the nu-cleation density and growth rate of crystallites had a great effect on the structure of aluminium deposited.The crys-tallographic orientation of deposits was mainly influenced by temperature and current density.Smooth,dense and well adherent aluminium coatings were obtained on copper substrates at 10-25 mA·cm^-2 and 313.2-353.2 K.More-over,the current efficiency of deposition and purity of aluminium have been significantly improved,demonstrating that the ionic liquids tested have a prospectful potential in electroplating and electrorefining of aluminium.

关键词: ionic liquid, low temperature, electroplating, electrodeposition, deposits

Abstract: Lewis acidic 1-allyl-3-methylimidazolium chloroaluminate ionic liquids were used as promising electrolytes in the low-temperature electrodeposition of aluminium.Systematic studies on deposition process have been performed by cyclic voltammetry and chronoamperometry.The surface morphology and X-ray diffraction(XRD) patterns of deposits prepared at different experimental conditions were also investigated.It was shown that the nu-cleation density and growth rate of crystallites had a great effect on the structure of aluminium deposited.The crys-tallographic orientation of deposits was mainly influenced by temperature and current density.Smooth,dense and well adherent aluminium coatings were obtained on copper substrates at 10-25 mA·cm^-2 and 313.2-353.2 K.More-over,the current efficiency of deposition and purity of aluminium have been significantly improved,demonstrating that the ionic liquids tested have a prospectful potential in electroplating and electrorefining of aluminium.

Key words: ionic liquid, low temperature, electroplating, electrodeposition, deposits

中图分类号:

O614.31

郑勇, 张锁江, 吕兴梅, 王倩, 左勇, 刘恋. Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids[J]. Chinese Journal of Chemical Engineering, 2012, 20(1): 130-139.

ZHENG Yong, ZHANG Suojiang, Lü Xingmei, WANG Qian, ZUO Yong, LIU Lian. Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids[J]. Chin.J.Chem.Eng., 2012, 20(1): 130-139.

参考文献

1 Wang,D.Q.,Shi,Z.Y.,"Aluminizing and oxidation treatment of 1Cr18Ni9 stainless steel",Appl.Surf.Sci.,227,255-260(2004).
2 Paredes,R.S.C.,Amico,S.C.,d'Oliveira,A.S.C.M.,"The effect of roughness and pre-heating of the substrate on the morphology of aluminium coatings deposited by thermal spraying",Surf.Coat. Technol.,200,3049-3055(2006).
3 Boogaard,A.,van den Broek,J.J.,"Crystallisation and electrical resistivity of sputter-deposited aluminium-germanium alloy films",Thin Solid Films,401,1-6(2001).
4 Yang,D.,Jonnalagadda,R.,Rogers,B.R.,Hillman,J.T.,Foster,R.F.,Cale,T.S.,"Texture and surface roughness of PRCVD aluminum films",Thin Solid Films,332,312-318(1998).
5 Gálová,M.,"Electrodeposition of aluminium from organic aprotic solvents",Surf.Technol.,11,357-369(1980).
6 Zhao,Y.G.,van der Noot,T.J.,"Electrodeposition of aluminium from nonaqueous organic electrolytic systems and room temperature molten salts",Electrochim.Acta,42,3-13(1997).
7 Zhang,M.M.,Kamavaram,V.,Reddy,R.G.,"New electrolytes for aluminum production:ionic liquids",JOM,11,54-57(2003).
8 Legrand,L.,Tranchant,A.,Messina,R.,"Behaviour of aluminium as anode in dimethylsulfone-based electrolytes",Electrochim.Acta,39,1427-1431(1994).
9 Jiang,T.,Chollier Brym,M.J.,Dubé,G.,Lasia,A.,Brisard,G.M.,"Studies on the AlCl₃/dimethylsulfone(DMSO₂)electrolytes for the aluminum deposition processes",Surf.Coat.Technol.,201,6309-6317 (2007).
10 Connor,J.H.,Brenner,A.,"Electrodeposition of metals from organic solutions",J.Electrochem.Soc.,103,657-662(1956).
11 Li,J.C.,Nan,S.H.,Jiang,Q.,"Study of the electrodeposition of Al-Mn amorphous alloys from molten salts",Surf.Coat.Technol.,106,135-139(1998).
12 Jafarian,M.,Mahjani,M.G.,Gobal,F.,Danaee,I.,"Electrodeposition of aluminum from molten AlCl₃-NaCl-KCl mixture",J.Appl. Electrochem.,36,1169-1173(2006).
13 Welton,T.,"Room-temperature ionic liquids.Solvents for synthesis and catalysis",Chem.Rev.,99,2071-2083(1999).
14 Binnemans,K.,"Ionic liquid crystals",Chem.Rev.,105,4148-4204 (2005).
15 Galiński,M.,Lewandowski,A.,Stępniak,I.,"Ionic liquids as electrolytes",Electrochim.Acta,51,5567-5580(2006).
16 Dupont,J.,de Souza,R.F.,Suarez,P.A.Z.,"Ionic liquid(molten salt) phase organometallic catalysis",Chem.Rev.,102,3667-3692 (2002).
17 Buzzeo,M.C.,Evans,R.G.,Compton,R.G.,"Non-haloaluminate room-temperature ionic liquids in electrochemistry-a review",ChemPhysChem,5,1106-1120(2004).
18 Abbott,A.P.,McKenzie,K.J.,"Application of ionic liquids to the electrodeposition of metals",Phys.Chem.Chem.Phys.,8,4265-4279 (2006).
19 Endres,F.,"Ionic liquids:Solvents for the electrodeposition of metals and semiconductors",ChemPhysChem,3,144-154(2002).
20 Endres,F.,MacFarlane,D.,Abbott,A.P.,Electrodeposition from Ionic Liquids,Wiley-VCH,Weinheim(2006).
21 Hurley,F.H.,Wier,T.P.,"The electrodeposition of aluminum from nonaqueous solutions at room temperature",J.Electrochem.Soc.,98,207-212(1951).
22 Yue,G.K.,Zhang,S.J.,Zhu,Y.L.,Lu,X.M.,Li,S.C.,Li,Z.X.,"A promising method for electrodeposition of aluminium on stainless steel in ionic liquid",AIChE J.,55,783-796(2009).
23 Jiang,T.,Chollier Brym,M.J.,Dubé,G.,Lasia,A.,Brisard,G.M.,"Electrodeposition of aluminium from ionic liquids:part I-electrodeposition and surface morphology of aluminium from aluminium chloride(AlCl₃)-1-ethyl-3-methylimidazolium chloride ([EMIm]Cl)ionic liquids",Surf.Coat.Technol.,201,1-9(2006).
24 Liu,Q.X.,Zein El Abedin,S.,Endres,F.,"Electroplating of mild steel by aluminium in a first generation ionic liquid:A green alternative to commercial Al-plating in organic solvents",Surf.Coat. Technol.,201,1352-1356(2006).
25 Lee,J.J.,Bae,I.T.,Scherson,D.A.,Miller,B.,Wheeler,K.A.,"Underpotential deposition of aluminum and alloy formation on polycrystalline gold electrodes from AlCl₃/EMIC room-temperature molten salts",J.Electrochem.Soc.,147,562-566(2000).
26 Abbott,A.P.,Eardley,C.A.,Farley,N.R.S.,Griffith,G.A.,Pratt,A.,"Eletrodeposition of aluminium and aluminium/platinum alloys from AlCl₃/benzyltrimethylammonium chloride room temperature ionic liquids",J.Appl.Electrochem.,31,1345-1350(2001).
27 Liu,Q.,Liu,K.R.,Han,Q.,Tu,G.F.,"Study on electrodeposition of Al from trimethylphenylammonium chloride(TMPAC)-aluminum chloride(AlCl₃)ionic liquids+benzene",Chin.Surf.Eng.,23,34-39(2010).
28 Bardi,U.,Caporali,S.,Craig,M.,Giorgetti,A.,Perissi,I.,Nichlolls,J.R.,"Electrodeposition of aluminium film on P90 Li-Al alloy as protective coating against corrosion",Surf.Coat.Technol.,203,1373-1378(2009).
29 Abbott,A.P.,Qiu,F.L.,Abood,H.M.A.,Rostom Ali,M.,Ryder,K.S.,"Double layer,diluent and anode effects upon the electrodeposition of aluminium from chloroaluminate based ionic liquids",Phys. Chem.Chem.Phys.,12,1862-1872(2010).
30 Atkin,R.,Zein El Abedin,S.,Hayes,R.,Gasparotto,L.H.S.,Borisenko,N.,Endres,F.,"AFM and STM studies on the surface interaction of Figure 14 EDAX spectrum of the aluminium deposits shown in Fig.7(a)Chin.J.Chem.Eng.,Vol.20,No.1,February 2012 139 [BMP]TFSA and[EMIm]TFSA ionic liquids with Au(Ⅲ)",J.Phys. Chem.C,113,13266-13272(2009).
31 Armand,M.,Endres,F.,MacFarlane,D.,Ohno,H.,Scrosati,B.,"Ionic-liquid materials for the electrochemical challenges of the future",Nature Mater.,8,621-629(2009).
32 Zein El Abedin,S.,Moustafa,E.M.,Hempelmann,R.,Natter,H.,Endres,F.,"Additive free electrodeposition of nanocrystalline aluminium in a water and air stable ionic liquid",Electrochem.Commun.,7,1111-1116(2005).
33 Zein El Abedin,S.,Moustafa,E.M.,Hempelmann,R.,Natter,H.,Endres,F.,"Electrodeposition of nano-and microcrystalline aluminium in three different air and water stable ionic liquids",ChemPhysChem,7,1535-1543(2006).
34 Rodopoulos,T.,Smith,L.,Horne,M.D.,Rüther,T.,"Speciation of aluminium in mixtures of the ionic liquids[C3mpip][NTf2]and [C4mpyr][NTf₂]with AlCl₃:An electrochemical and NMR spectroscopy study",Chem.Eur.J.,16,3815-3826(2010).
35 Zhang,H.,Wu,J.,Zhang,J.,He,J.S.,"1-Allyl-3-methylimidazolium chloride room temperature ionic liquid:A new and powerful nonderivatizing solvent for cellulose",Macromolecules,38,8272-8277 (2005).
36 Huddleston,J.G.,Visser,A.E.,Reichert,W.M.,Willauer,H.D.,Broker,G.A.,Rogers,R.D.,"Characterization and comparison of hydrophilic and hydrophobic room temperature ionic liquids incorporating the imidazolium cation",Green Chem.,3,156-164(2001).
37 Bonhôte,P.,Dias,A.,Papageorgiou,N.,Kalyanasundaram,K.,Grätzel,M.,"Hydrophobic,highly conductive ambient-temperature molten salts",Inorg.Chem.,35,1168-1178(1996).
38 Zheng,Y.,Xuan,X.P.,Wang,J.J.,Fan,M.H.,"The enhanced dissolution ofβ-cyclodextrin in some hydrophilic ionic liquids",J.Phys. Chem.A,114,3926-3931(2010).
39 Xuan,X.P.,Guo,M.,Pei,Y.C.,Zheng,Y.,"Theoretical study on cation-anion interaction and vibrational spectra of 1-allyl-3methylimidazolium-based ionic liquids",Spectrochim.Acta A,78,1492-1499(2011).
40 Scharifker,B.,Hills,G.,"Theoretical and experimental studies of multiple nucleation",Electrochim.Acta,28,879-889(1983).
41 Lee,J.J.,Miller,B.,Shi,X.,Kalish,R.,Wheeler,K.A.,"Aluminum deposition and nucleation on nitrogen-incorporated tetrahedral amorphous carbon electrodes in ambient temperature chloroaluminate melts",J.Electrochem.Soc.,147,3370-3376(2000)
42 Tsuda,T.,Boyd,L.E.,Kuwabata,S.,Hussey,C.L.,"Electrochemistry of copper(Ⅰ)oxide in the 66.7-33.3 mol% urea-choline chloride room-temperature eutectic melt",J.Electrochem.Soc.,157,F96-F103 (2010).

[1]	Eileen Katherine Coronado-Aldana, Cindy Lizeth Ferreira-Salazar, Nubia Yineth Piñeros-Castro, Rubén Vázquez-Medina, Felipe A. Perdomo. Thermodynamic analysis, synthesis, characterization, and evaluation of 1-ethyl-3-methylimidazolium chloride: Study of its effect on pretreated rice husk[J]. 中国化学工程学报, 2023, 60(8): 143-154.
[2]	Zhonghao Li, Yuanyuan Yang, Huanong Cheng, Yun Teng, Chao Li, Kangkang Li, Zhou Feng, Hongwei Jin, Xinshun Tan, Shiqing Zheng. Measurement and model of density, viscosity, and hydrogen sulfide solubility in ferric chloride/trioctylmethylammonium chloride ionic liquid[J]. 中国化学工程学报, 2023, 59(7): 210-221.
[3]	Chen Chen, Qiong Tang, Hong Xu, Mingxing Tang, Xuekuan Li, Lei Liu, Jinxiang Dong. Alkyl-tetralin base oils synthesized from coal-based chemicals and evaluation of their lubricating properties[J]. 中国化学工程学报, 2023, 58(6): 20-28.
[4]	Shuangtai Liu, Lei He, Qiuxiang Yao, Xi Li, Linyang Wang, Jing Wang, Ming Sun, Xiaoxun Ma. Separation and analysis of six fractions in low temperature coal tar by column chromatography[J]. 中国化学工程学报, 2023, 58(6): 256-265.
[5]	Yutong Jiang, Yifeng Chen, Fuliu Yang, Jixue Fan, Jun Li, Zhuhong Yang, Xiaoyan Ji. Efficient SO₂ removal using aqueous ionic liquid at low partial pressure[J]. 中国化学工程学报, 2023, 58(6): 355-363.
[6]	Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He. One-pot synthesis of bimetallic CeCu-SAPO-34 for high-efficiency selective catalytic reduction of nitrogen oxides with NH₃ at low temperature[J]. 中国化学工程学报, 2023, 56(4): 193-202.
[7]	Jialei Sha, Chenyi Liu, Zhihong Ma, Weizhong Zheng, Weizhen Sun, Ling Zhao. Understanding the interfacial behaviors of benzene alkylation with butene using chloroaluminate ionic liquid catalyst: A molecular dynamics simulation[J]. 中国化学工程学报, 2023, 54(2): 44-52.
[8]	Yifeng Chen, Hang Yu, Jingjing Chen, Xiaohua Lu, Xiaoyan Ji. Viscous behavior of 1-hexyl-methylimidazolium bis(trifluoromethylsulfonyl)imide/titanium dioxide/polyethylene glycol[J]. 中国化学工程学报, 2023, 54(2): 280-287.
[9]	Mi Feng, Bin He, Xinyan Chen, Junli Xu, Xingmei Lu, Cai Jia, Jian Sun. Separation of chitin from shrimp shells enabled by transition metal salt aqueous solution and ionic liquid[J]. 中国化学工程学报, 2023, 53(1): 133-141.
[10]	Xuan Gao, Zhihui Li, Dongsheng Zhang, Xinqiang Zhao, Yanji Wang. Synthesis and kinetics of 2,5-dicyanofuran in the presence of hydroxylamine ionic liquid salts[J]. 中国化学工程学报, 2023, 53(1): 310-316.
[11]	Xinqiang You, Kai Zhao, Ling Li, Ting Qiu. Ionic liquids as entrainer in extractive distillation for effectively separating 1-propanol–water azeotropic mixture[J]. 中国化学工程学报, 2022, 49(9): 224-233.
[12]	Minjie Shi, Hangtian Zhu, Cheng Yang, Jing Xu, Chao Yan. Chemical reduction-induced fabrication of graphene hybrid fibers for energy-dense wire-shaped supercapacitors[J]. 中国化学工程学报, 2022, 47(7): 1-10.
[13]	Song Hu, Jinlong Li, Qihua Wang, Weisheng Yang. Design and optimization of an integrated process for the purification of propylene oxide and the separation of propylene glycol by-product[J]. 中国化学工程学报, 2022, 45(5): 111-120.
[14]	Linlan Wu, Zhengxin Jiao, Suhang Xun, Minqiang He, Lei Fan, Chao Wang, Wenshu Yang, Wenshuai Zhu, Huaming Li. Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents[J]. 中国化学工程学报, 2022, 44(4): 205-211.
[15]	Zhen He, Yu Zhou, Yuxin Wang, Pingyi Guo, Wensen Jiang, Caizhen Yao, Xin Shu. Preparation and properties of Ni-W-P-TiO₂ nanocomposite coatings developed by a sol-enhanced electroplating method[J]. 中国化学工程学报, 2022, 44(4): 369-376.

Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids

Low-temperature Electrodeposition of Aluminium from Lewis Acidic 1-Allyl-3-methylimidazolium Chloroaluminate Ionic Liquids

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价