Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

Chinese Journal of Chemical Engineering ›› 2012, Vol. 20 ›› Issue (2): 277-283.

• CHEMICAL ENGINEERING THERMODYNAMICS • 上一篇下一篇

Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

谢艳新¹, 侯丽丽², 杨倩³, 蒋登高¹

1. College of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;
2. Department of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
3. Committee of Baoshan Circular Economy Industrial Agglomeration, Hebi 458030, China

收稿日期:2011-11-03 修回日期:2012-03-15 出版日期:2012-04-28 发布日期:2012-05-02
通讯作者: XIE Yanxin

Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

XIE Yanxin¹, HOU Lili², YANG Qian³, JIANG Denggao¹

1. College of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou 450001, China;
2. Department of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
3. Committee of Baoshan Circular Economy Industrial Agglomeration, Hebi 458030, China

Received:2011-11-03 Revised:2012-03-15 Online:2012-04-28 Published:2012-05-02

摘要/Abstract

摘要： AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption efficiency.The adsorptive thermodynamic properties and kinetics of CHD from water onto AB-8 resin were studied.The Langmuir and Freundlich isotherm models were employed to discuss the adsorption behavior.Thermodynamic parameters such as ΔG^θ,ΔH^θ and ΔS^θ were calculated.The results indicate that the equilibrium data are perfectly represented by Langmuir isotherm model.Thermodynamic study reveals that it is an exothermic process in nature and mainly physical adsorption enhanced by chemisorption with a decrease of entropy process.The kinetics of CHD adsorption is well described by the pseudo second-order model.The adsorbed CHD can be eluted from AB-8 resin by 5% ethanol aqueous solution with 100% elution percentage.

关键词: AB-8 resin, trans-1, 2-cyclohexandiol, adsorption, isotherm, thermodynamics, kinetics

Abstract: AB-8 resin was used as an adsorbent for the removal of trans-1,2-cyclohexandiol(CHD) from aqueous solutions.Batch experiments were carried out to investigate the effect of contact time and temperature on sorption efficiency.The adsorptive thermodynamic properties and kinetics of CHD from water onto AB-8 resin were studied.The Langmuir and Freundlich isotherm models were employed to discuss the adsorption behavior.Thermodynamic parameters such as ΔG^θ,ΔH^θ and ΔS^θ were calculated.The results indicate that the equilibrium data are perfectly represented by Langmuir isotherm model.Thermodynamic study reveals that it is an exothermic process in nature and mainly physical adsorption enhanced by chemisorption with a decrease of entropy process.The kinetics of CHD adsorption is well described by the pseudo second-order model.The adsorbed CHD can be eluted from AB-8 resin by 5% ethanol aqueous solution with 100% elution percentage.

Key words: AB-8 resin, trans-1, 2-cyclohexandiol, adsorption, isotherm, thermodynamics, kinetics

谢艳新, 侯丽丽, 杨倩, 蒋登高. Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin[J]. Chinese Journal of Chemical Engineering, 2012, 20(2): 277-283.

XIE Yanxin, HOU Lili, YANG Qian, JIANG Denggao. Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin[J]. Chin.J.Chem.Eng., 2012, 20(2): 277-283.

参考文献

1 Van Hulle,S.W.H.,Audenaert,W.,Decostere,B.,Hogie,J.,Dejans, P.,“Sustainable wastewater treatment of temporary events:the Dranouter Music Festival case study”,Water Sci.Technol.,8(8),1653-1657(2008).
2 Wongsarivej,P.,Tongprem,P.,Swasdisevi,T.,Charinpanitkul,T., “Adsorption and ozonation kinetic model for phenolic wastewater treatment”,Chin.J.Chem.Eng.,19(1),76-82(2011).
3 Polaert,I.,Wilhelm,A.M.,Delmas,H.,“Phenol wastewater treatment by a two-step adsorption-oxidation process on activated carbon”,Chem.Eng.Sci.,57,1585-1590(2002).
4 Yousef,R.,EI-Eswed,B.,AI-Muhtaseb,A.,“Adsorption characteristics of natural zeolites as solid adsorbents for phenol removal from aqueous solutions:kinetics,mechanism and thermodynamics studies”,Chem.Eng.J.,171,1143-1149(2011).
5 Zhang,Q.X.,Chen,J.L.,Xu,Z.Y.,“Application of polymeric resin adsorbent in organic chemical wastewater treatment and resources reuse”,Polymer Bulletin,(4),116-121(2005).
6 Yu,Y.,Zhuang,Y.Y.,Wang,Z.H.,Qiu,M.Q.,“Adsorption of water-soluble dyes onto modified resin”,Chemosphere.,54(3),425-430(2004).
7 Li,A.M.,Zhang,Q.X.,Wu,H.S.,Zhai,Z.C.,“A new amine-modified hyper-cross-linked polymeric adsorbent for removing phenolic compounds from aqueous solutions”,Adsorpt.Sci.Technol.,22(10),
807-819(2004).
8 Fu,L.L.,Jiang,D.G.,Xie,Y.X.,“Synthesis of immobilized quaternary ammonium heteropolyphosphatotungstate catalysts and their activity in the epoxidation of cyclohexene”,Sci.T.J.,(4),52-55 (2010).(in Chinese)
9 Langmuir,I.,“The adsorption of gases on plane surfaces of glass,
11 Han,X.L.,Wang,W.,Ma,X.J.,“Adsorption characteristics of methylene blue onto low cost biomass material lotus leaf”,Chem.Eng. J.,171,1-8(2011).
12 Kumar,K.V.,Kumaran,A.,“Removal of methylene blue by mango seed kernel powder”,Biochem.Eng.J.,27,83-93(2005).
13 Liu,Q.S.,Zheng,T.,Wang,P.,Jiang,J.P.,“Adsorption isotherm,kinetic and mechanism studies of some substituted phenols on activated fibers”,Chem.Eng.J.,157,348-356(2010).
14 Liu,Y.,“Is the free energy change of adsorption correctly calculated?”J.Chem.Eng.Data,54,1981-1985(2009).
15 Li,Y.H.,Di,Z.,Ding,J.,Wu,D.,Luan,Z.,Zhu,Y.,“Adsorption thermodynamic,kinetic and desorption studies of Pb²⁺ on carbon nanotubes”,Water Res.,39,605-609(2005).
16 Tan,I.A.W.,Ahmad,A.L.,Hameed,B.H.,“Biosorption isotherms, kinetics,thermodynamics and desorption studies of 2,4,6-trichlorophenol on oil palm empty fruit bunch-based activated carbon”,J.Hazard.Mater.,164,473-482(2009).
17 Ho,Y.S.,McKay,G.,“Sorption of dye from aqueous solution by peat”,Chem.Eng.J.,70,115-124(1998).
18 Tutem,E.,Apak,R.,Unal,C.F.,“Adsorption removal of chlorophenols from water by bituminous shale”,Water.Res.,32,2315-2324 (1998).
19 McKay,G.,Ho,Y.S.,“Pseudo second-order model for sorption processes”,Process.Biochem.,34,451-465(1999).
20 Yang,X.,Al-Duri,B.,“Kinetic modeling of liquid-phase adsorption of reactive dyes on activated carbon”,J.Colloid Interface Sci.,287,25-34(2005).
21 Weber,W.J.,Morris,J.C.,“Kinetics of adsorption on carbon from solution”,J.Sanit.Eng.Div.Am.Soc.Civ.Eng.,89,31-59(1963).

[1]	Yingli Li, Zhishuncheng Li, Guangfei Qu, Rui Li, Shuaiyu Liang, Junhong Zhou, Wei Ji, Huiming Tang. Mechanism, behaviour and application of iron nitrate modified carbon nanotube composites for the adsorption of arsenic in aqueous solutions[J]. 中国化学工程学报, 2023, 60(8): 26-36.
[2]	Jing Huang, Honghui Cai, Qian Zhao, Yunpeng Zhou, Haibo Liu, Jing Wang. Dual-functional pyrene implemented mesoporous silicon material used for the detection and adsorption of metal ions[J]. 中国化学工程学报, 2023, 60(8): 108-117.
[3]	Xingjuan Liang, Dehua Xu, Zhengjuan Yan, Jingxu Yang, Xinlong Wang, Zhiye Zhang, Jingli Wu, Honggang Zhen. Solid-liquid phase equilibrium for the system ammonium polyphosphate-urea ammonium nitrate-potassium chloride-water at 273.2 K[J]. 中国化学工程学报, 2023, 60(8): 131-142.
[4]	Eileen Katherine Coronado-Aldana, Cindy Lizeth Ferreira-Salazar, Nubia Yineth Piñeros-Castro, Rubén Vázquez-Medina, Felipe A. Perdomo. Thermodynamic analysis, synthesis, characterization, and evaluation of 1-ethyl-3-methylimidazolium chloride: Study of its effect on pretreated rice husk[J]. 中国化学工程学报, 2023, 60(8): 143-154.
[5]	Lingli Chen, Yueting Shi, Sijun Xu, Junle Xiong, Fang Gao, Shengtao Zhang, Hongru Li. Enhanced adsorption of target branched compounds including antibiotic norfloxacin frameworks on mild steel surface for efficient protection: An experimental and molecular modelling study[J]. 中国化学工程学报, 2023, 60(8): 212-227.
[6]	Xiaolin Guo, Zhaoyang Zhang, Pengfei Xing, Shuai Wang, Yibing Guo, Yanxin Zhuang. Kinetic mechanism of copper extraction from methylchlorosilane slurry residue using hydrogen peroxide as oxidant[J]. 中国化学工程学报, 2023, 60(8): 228-234.
[7]	Alexander Nti Kani, Evans Dovi, Aaron Albert Aryee, Runping Han, Zhaohui Li, Lingbo Qu. Mechanisms and reusability potentials of zirconium-polyaziridine-engineered tiger nut residue towards anionic pollutants[J]. 中国化学工程学报, 2023, 60(8): 275-292.
[8]	Yuan Liu, Hanting Xiong, Jingwen Chen, Shixia Chen, Zhenyu Zhou, Zheling Zeng, Shuguang Deng, Jun Wang. One-step ethylene separation from ternary C₂ hydrocarbon mixture with a robust zirconium metal-organic framework[J]. 中国化学工程学报, 2023, 59(7): 9-15.
[9]	Hui Jiang, Zijian Zhao, Ning Yu, Yi Qin, Zhengwei Luo, Wenhua Geng, Jianliang Zhu. Synthesis, characterization, and performance comparison of boron using adsorbents based on N-methyl-D-glucosamine[J]. 中国化学工程学报, 2023, 59(7): 16-31.
[10]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.
[11]	Runze Chen, Yuran Chen, Xuemin Liang, Yapeng Kong, Yangyang Fan, Quan Liu, Zhenyu Yang, Feiying Tang, Johnny Muya Chabu, Maru Dessie Walle, Liqiang Wang. Oxidative exfoliation of spent cathode carbon: A two-in-one strategy for its decontamination and high-valued application[J]. 中国化学工程学报, 2023, 59(7): 262-269.
[12]	Junyang Liu, Luming Wang, Yuhang Bian, Chunshan Li, Zengxi Li, Jie Li. Liquid-phase esterification of methacrylic acid with methanol catalyzed by cation-exchange resin in a fixed bed reactor: Experimental and kinetic studies[J]. 中国化学工程学报, 2023, 58(6): 1-10.
[13]	Wei Wang, Romain Lemaire, Ammar Bensakhria, Denis Luart. Thermogravimetric analysis and kinetic modeling of the co-pyrolysis of a bituminous coal and poplar wood[J]. 中国化学工程学报, 2023, 58(6): 53-68.
[14]	Shanghong Ma, Haitao Zhang, Jianbo Qu, Xiuzhong Zhu, Qingfei Hu, Jianyong Wang, Peng Ye, Futao Sai, Shiwei Chen. Preparation of waterborne polyurethane/β-cyclodextrin composite nanosponge by ion condensation method and its application in removing of dyes from wastewater[J]. 中国化学工程学报, 2023, 58(6): 124-136.
[15]	Bing Liu, Yingjiao Li, Moses Arowo, Guangwen Chu, Yong Luo, Liangliang Zhang, Haikui Zou, Baochang Sun. Sulfonation of 1, 4-diaminoanthraquinone leuco by chlorosulfonic acid: Kinetics and process intensification[J]. 中国化学工程学报, 2023, 58(6): 163-169.

Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

Adsorptive Thermodynamic Properties and Kinetics of trans-1,2-Cyclohexandiol onto AB-8 Resin

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价