Phase Behavior of Sodium Dodecyl Sulfate-n-Butanol-Kerosene-Water Microemulsion System

doi:10.1016/S1004-9541(14)60095-1

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (6): 699-705.DOI: 10.1016/S1004-9541(14)60095-1

• 催化、动力学与反应工程 • 上一篇下一篇

Phase Behavior of Sodium Dodecyl Sulfate-n-Butanol-Kerosene-Water Microemulsion System

刘会娥, 张孝坤, 丁传芹, 陈爽, 齐选良

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266555, China

收稿日期:2013-01-13 修回日期:2013-06-08 出版日期:2014-06-28 发布日期:2014-06-06
通讯作者: LIU Huie
基金资助:
Supported by the National Natural Science Foundation of China (21106187), Promotive Research Funds for Excellent Young and Middle-aged Scientists of Shandong Province (BS2011NJ021), the Fundamental Research Funds for the Central Universities (11CX05016A), and the Graduate Innovation Project of CUP 2012 (CX-1214)

Phase Behavior of Sodium Dodecyl Sulfate-n-Butanol-Kerosene-Water Microemulsion System

LIU Huie, ZHANG Xiaokun, DING Chuanqin, CHEN Shuang, QI Xuanliang

State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Qingdao 266555, China

Received:2013-01-13 Revised:2013-06-08 Online:2014-06-28 Published:2014-06-06
Supported by:
Supported by the National Natural Science Foundation of China (21106187), Promotive Research Funds for Excellent Young and Middle-aged Scientists of Shandong Province (BS2011NJ021), the Fundamental Research Funds for the Central Universities (11CX05016A), and the Graduate Innovation Project of CUP 2012 (CX-1214)

摘要/Abstract

摘要： Experiments were carried out to investigate the influences of cation from electrolytes and acidity/alkalinity on the phase behavior of sodium dodecyl sulfate-n-butanol-organics-water (with electrolytes) microemulsion system. The organics used is commercial kerosene. The volume ratio of water to organics is 1:1. The results show that the type and valence of electrolyte cations are important factors influencing the microemulsion behavior. Bivalent Ca²⁺ is more effective than monovalent K⁺ and Na⁺ for the formation of Winsor type III and II microemulsion. For electrolytes with the same monovalent cation Na⁺, #em/em#.e. NaCl and Na₂CO₃, anions in the electrolyte have some effect. Bivalent anion leads to a lower activity of cation Na⁺ than monovalent anion Cl^-. NaOH (or KOH) behaves similar with NaCl (or KCl). When HCl is used as electrolyte, its acidity plays an important role. Phase inversion of microemulsion from type III (or II) to type I is observed through precipitation of Ca²⁺ using Na₂CO₃, neutralization of HCl by NaOH, and addition of water to the system, which releases the oil from the microemulsion.

关键词: microemulsion, sodium dodecyl sulfate, kerosene, phase inversion

Abstract: Experiments were carried out to investigate the influences of cation from electrolytes and acidity/alkalinity on the phase behavior of sodium dodecyl sulfate-n-butanol-organics-water (with electrolytes) microemulsion system. The organics used is commercial kerosene. The volume ratio of water to organics is 1:1. The results show that the type and valence of electrolyte cations are important factors influencing the microemulsion behavior. Bivalent Ca²⁺ is more effective than monovalent K⁺ and Na⁺ for the formation of Winsor type III and II microemulsion. For electrolytes with the same monovalent cation Na⁺, #em/em#.e. NaCl and Na₂CO₃, anions in the electrolyte have some effect. Bivalent anion leads to a lower activity of cation Na⁺ than monovalent anion Cl^-. NaOH (or KOH) behaves similar with NaCl (or KCl). When HCl is used as electrolyte, its acidity plays an important role. Phase inversion of microemulsion from type III (or II) to type I is observed through precipitation of Ca²⁺ using Na₂CO₃, neutralization of HCl by NaOH, and addition of water to the system, which releases the oil from the microemulsion.

Key words: microemulsion, sodium dodecyl sulfate, kerosene, phase inversion

引用本文

刘会娥, 张孝坤, 丁传芹, 陈爽, 齐选良. Phase Behavior of Sodium Dodecyl Sulfate-n-Butanol-Kerosene-Water Microemulsion System[J]. Chinese Journal of Chemical Engineering, 2014, 22(6): 699-705.

LIU Huie, ZHANG Xiaokun, DING Chuanqin, CHEN Shuang, QI Xuanliang . Phase Behavior of Sodium Dodecyl Sulfate-n-Butanol-Kerosene-Water Microemulsion System[J]. Chin.J.Chem.Eng., 2014, 22(6): 699-705.

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[1]	Chaobo Zhang, Xiaoyong Yang, Jian Dai, Wenxia Liu, Hang Yang, Zhishan Bai. Efficient extraction of phenol from wastewater by ionic micro-emulsion method: Anionic and cationic[J]. 中国化学工程学报, 2023, 58(6): 137-145.
[2]	Jule Ma, Peiwen Xiao, Pingmei Wang, Xue Han, Jianhui Luo, Ruifang Shi, Xuan Wang, Xianyu Song, Shuangliang Zhao. Molecular dynamics simulation study on π-π stacking of Gemini surfactants in oil/water systems[J]. 中国化学工程学报, 2022, 50(10): 335-346.
[3]	Bay Van Tran, Son Ich Ngo, Young-Il Lim, Keon Bae, Dong Hyun Lee, Kang-Seok Go, Nam-Sun Nho. Hydrodynamics of air-kerosene bubble column under elevated pressure in homogeneous flow regime[J]. 中国化学工程学报, 2021, 33(5): 190-202.
[4]	Yanhong Wang, Yingnan Lu, Sufen Li, Ming Dong. Numerical study on non-uniform heat transfer deterioration of supercritical RP-3 aviation kerosene in a horizontal tube[J]. 中国化学工程学报, 2020, 28(6): 1542-1557.
[5]	Sk. Md. Ali Ahsan, Md. Ruhul Amin, Shamim Mahbub, Mohammad Robel Molla, Shahina Aktar, Malik Abdul Rub, Md. Anamul Hoque, Muhammad Nadeem Arshad, Mohammed Abdullah Khan. Interaction of ciprofloxacin hydrochloride with sodium dodecyl sulfate in aqueous/electrolytes solution at different temperatures and compositions[J]. 中国化学工程学报, 2020, 28(1): 216-223.
[6]	Hongyue Zhu, Ying Li, Hongrui Ren, Dan Zhou, Jianzhong Yin. Molecular dynamics simulation of supercritical CO₂ microemulsion with ionic liquid domains: Structures and properties[J]. 中国化学工程学报, 2019, 27(11): 2653-2658.
[7]	Xiao Wang, Gaojie Xu, Qingfu Wang, Chenglong Lu, Chengzhong Zong, Jianjun Zhang, Liping Yue, Guanglei Cui. A phase inversion based sponge-like polysulfonamide/SiO₂ composite separator for high performance lithium-ion batteries[J]. Chinese Journal of Chemical Engineering, 2018, 26(6): 1292-1299.
[8]	Ahmed Bhran, Abeer Shoaib, Doaa Elsadeq, Ayman El-gendi, Heba Abdallah. Preparation of PVC/PVP composite polymer membranes via phase inversion process for water treatment purposes[J]. Chinese Journal of Chemical Engineering, 2018, 26(4): 715-722.
[9]	Kibrom Alebel Gebru, Chandan Das. Effects of solubility parameter differences among PEG,PVP and CA on the preparation of ultrafiltration membranes:Impacts of solvents and additives on morphology,permeability and fouling performances[J]. , 2017, 25(7): 911-923.
[10]	Dan Huang, Bo Ruan, Xiaoyu Wu, Wei Zhang, Guoqiang Xu, Zhi Tao, Peixue Jiang, Lianxiang Ma, Wei Li. Experimental study on heat transfer of aviation kerosene in a vertical upward tube at supercritical pressures[J]. , 2015, 23(2): 425-434.
[11]	周智勇, 秦炜, 费维扬, 李以圭. A Study on Stoichiometry of Complexes of Tributyl Phosphate and Methyl Isobutyl Ketone with Lithium in the Presence of FeCl₃[J]. , 2012, 20(1): 36-39.
[12]	韩爱军, 廖娟娟, 叶明泉, 李燕, 彭新华. Preparation of Nano-MnFe₂O₄ and Its Catalytic Performance of Thermal Decomposition of Ammonium Perchlorate[J]. , 2011, 19(6): 1047-1051.
[13]	吴洪, 李宪实, 聂明成, 李犇, 姜忠义. Integral PVA-PES Composite Membranes by Surface Segregation Method for Pervaporation Dehydration of Ethanol[J]. , 2011, 19(5): 855-862.
[14]	罗明良, 温庆志, 刘佳林, 刘洪见, 贾自龙. Fabrication of SPES/Nano-TiO₂ Composite Ultrafiltration Membrane and Its Anti-fouling Mechanism[J]. , 2011, 19(1): 45-51.
[15]	Asghar Molaei Dehkordi, Mohammad Amin Sobati, Mohammad Ali Nazem. Oxidative Desulfurization of Non-hydrotreated Kerosene Using Hydrogen Peroxide and Acetic Acid[J]. , 2009, 17(5): 869-874.