Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system

doi:10.1016/j.cjche.2019.04.014

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (10): 2472-2480.DOI: 10.1016/j.cjche.2019.04.014

Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system

Edgar N. Tec-Caamal¹, Refugio Rodríguez-Vázquez¹, Luis G. Torres-Bustillos², Ricardo Aguilar-López¹

1 Center for Research and Advanced Studies of the National Polytechnic Institute, Av. Instituto Politécnico Nacional No. 2508, Colonia San Pedro Zacatenco, C. P. 07360 Ciudad de México D. F., Mexico;
2 Interdisciplinary Professional Unit of Biotechnology-National Polytechnic Institute(UPIBI-IPN), Acueducto s/n, La Laguna Ticomán, Gustavo A. Madero, 07340, Ciudad de México, Mexico

收稿日期:2018-11-23 修回日期:2019-04-24 出版日期:2019-10-28 发布日期:2020-01-17
通讯作者: Ricardo Aguilar-López

Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system

Edgar N. Tec-Caamal¹, Refugio Rodríguez-Vázquez¹, Luis G. Torres-Bustillos², Ricardo Aguilar-López¹

1 Center for Research and Advanced Studies of the National Polytechnic Institute, Av. Instituto Politécnico Nacional No. 2508, Colonia San Pedro Zacatenco, C. P. 07360 Ciudad de México D. F., Mexico;
2 Interdisciplinary Professional Unit of Biotechnology-National Polytechnic Institute(UPIBI-IPN), Acueducto s/n, La Laguna Ticomán, Gustavo A. Madero, 07340, Ciudad de México, Mexico

Received:2018-11-23 Revised:2019-04-24 Online:2019-10-28 Published:2020-01-17
Contact: Ricardo Aguilar-López

摘要/Abstract

摘要： This paper analyses the oxidation of ferrous iron via chemical and biological means in a class of Sequential Batch Reactors (SBR-type). For this, a kinetic model for the study of iron oxidation system is proposed, followed by a parametric sensitivity analysis and a bifurcation analysis, which allow selecting the most influential kinetic parameters in order to ensure a suitable prediction capacity of the mathematical structure. The system consists of two SBR bioreactors, the first being used to produce hydrogen peroxide (H₂O₂) that is fed to a second reactor where the iron oxidation is carried out by chemical-biological processes. Model predictions were compared with experimental data for the production of H₂O₂ and for ferrous iron oxidation, finding suitable correlation coefficients (r²> 0.98) for each state variable. The bifurcation analysis showed the trajectories of the main variables, such as, biomass, H₂O₂ and ferrous iron, under the change of the most influential kinetic parameters. This analysis demonstrates the usefulness of the constructed model to predict the kinetic behaviour of the SBR-type process.

关键词: Bifurcation analysis, Hydrogen peroxide, Iron oxidation, Modeling, Simulation

Abstract: This paper analyses the oxidation of ferrous iron via chemical and biological means in a class of Sequential Batch Reactors (SBR-type). For this, a kinetic model for the study of iron oxidation system is proposed, followed by a parametric sensitivity analysis and a bifurcation analysis, which allow selecting the most influential kinetic parameters in order to ensure a suitable prediction capacity of the mathematical structure. The system consists of two SBR bioreactors, the first being used to produce hydrogen peroxide (H₂O₂) that is fed to a second reactor where the iron oxidation is carried out by chemical-biological processes. Model predictions were compared with experimental data for the production of H₂O₂ and for ferrous iron oxidation, finding suitable correlation coefficients (r²> 0.98) for each state variable. The bifurcation analysis showed the trajectories of the main variables, such as, biomass, H₂O₂ and ferrous iron, under the change of the most influential kinetic parameters. This analysis demonstrates the usefulness of the constructed model to predict the kinetic behaviour of the SBR-type process.

Key words: Bifurcation analysis, Hydrogen peroxide, Iron oxidation, Modeling, Simulation

Edgar N. Tec-Caamal, Refugio Rodríguez-Vázquez, Luis G. Torres-Bustillos, Ricardo Aguilar-López. Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system[J]. 中国化学工程学报, 2019, 27(10): 2472-2480.

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Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system

Kinetic analysis via mathematical modeling for ferrous iron oxidation in a class of SBR-type system

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