Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method

doi:10.1016/j.cjche.2019.01.026

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (12): 3017-3026.DOI: 10.1016/j.cjche.2019.01.026

• Energy, Resources and Environmental Technology • 上一篇下一篇

Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method

Lan Yang, Xiang Zhang, Qing Kan, Binran Zhao, Xiaoxun Ma

School of Chemical Engineering, Northwest University, Xi'an 710069, China;
Chemical Engineering Research Center of the Ministry of Education(MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
International Scientific and Technological Cooperation Base of the Ministry of Science and Technology(MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China;
Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China

收稿日期:2018-09-12 修回日期:2019-01-07 出版日期:2019-12-28 发布日期:2020-03-17
通讯作者: Xiaoxun Ma
基金资助:
Supported by the National Natural Science Foundation of China (21536009) and the Science and Technology Plan Projects of Shaanxi Province (2017ZDCXL-GY-10-03).

Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method

Lan Yang, Xiang Zhang, Qing Kan, Binran Zhao, Xiaoxun Ma

School of Chemical Engineering, Northwest University, Xi'an 710069, China;
Chemical Engineering Research Center of the Ministry of Education(MOE) for Advanced Use Technology of Shanbei Energy, Xi'an 710069, China;
Shaanxi Research Center of Engineering Technology for Clean Coal Conversion, Xi'an 710069, China;
International Scientific and Technological Cooperation Base of the Ministry of Science and Technology(MOST) for Clean Utilization of Hydrocarbon Resources, Xi'an 710069, China;
Collaborative Innovation Center for Development of Energy and Chemical Industry in Northern Shaanxi, Xi'an 710069, China

Received:2018-09-12 Revised:2019-01-07 Online:2019-12-28 Published:2020-03-17
Contact: Xiaoxun Ma
Supported by:
Supported by the National Natural Science Foundation of China (21536009) and the Science and Technology Plan Projects of Shaanxi Province (2017ZDCXL-GY-10-03).

摘要/Abstract

摘要： A new method for nitric oxide (NO) removal was developed by combining dielectric barrier discharge (DBD) and negative pulse corona (NPC). The effects of gas composition (O₂, CO₂, and H₂O) on NO removal were investigated with this method, and the effect of alcohols (methanol and ethanol) addition on NO removal was also investigated as well as the reaction mechanisms to enhance the NO removal efficiency. The experimental results showed that O₂, CO₂, and H₂O had obvious inhibition effects on NO removal, and the negative effects were in the following order:O₂ > CO₂ > H₂O. The addition of methanol or ethanol in the reaction system could mitigate the negative effects of O₂, CO₂, and H₂O on NO removal, and also eliminated the production of NO₂. The positive effect of alcohols addition with DBD-NPC denitration method was also validated in the simulated flue gas, in which the NO_x (NO, NO₂) was mainly converted into N².

关键词: Dielectric barrier discharge (DBD), Corona discharge, Nitric oxide, Alcohols, Flue gas

Abstract: A new method for nitric oxide (NO) removal was developed by combining dielectric barrier discharge (DBD) and negative pulse corona (NPC). The effects of gas composition (O₂, CO₂, and H₂O) on NO removal were investigated with this method, and the effect of alcohols (methanol and ethanol) addition on NO removal was also investigated as well as the reaction mechanisms to enhance the NO removal efficiency. The experimental results showed that O₂, CO₂, and H₂O had obvious inhibition effects on NO removal, and the negative effects were in the following order:O₂ > CO₂ > H₂O. The addition of methanol or ethanol in the reaction system could mitigate the negative effects of O₂, CO₂, and H₂O on NO removal, and also eliminated the production of NO₂. The positive effect of alcohols addition with DBD-NPC denitration method was also validated in the simulated flue gas, in which the NO_x (NO, NO₂) was mainly converted into N².

Key words: Dielectric barrier discharge (DBD), Corona discharge, Nitric oxide, Alcohols, Flue gas

Lan Yang, Xiang Zhang, Qing Kan, Binran Zhao, Xiaoxun Ma. Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method[J]. 中国化学工程学报, 2019, 27(12): 3017-3026.

Lan Yang, Xiang Zhang, Qing Kan, Binran Zhao, Xiaoxun Ma. Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method[J]. Chinese Journal of Chemical Engineering, 2019, 27(12): 3017-3026.

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Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method

Effect of gas composition on nitric oxide removal from simulated flue gas with DBD-NPC method

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