Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

doi:10.1016/j.cjche.2019.03.024

中国化学工程学报 ›› 2019, Vol. 27 ›› Issue (12): 3043-3052.DOI: 10.1016/j.cjche.2019.03.024

• Materials and Product Engineering • 上一篇下一篇

Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

Jianhui Zhou¹, Xiaotong Zhang², Ying Yan³, Jianfeng Hu³, Hang Wang¹, Yan Cai³, Jinqing Qu³

1 State Key Laboratory of Advanced Power Transmission Technology, Global Energy Interconnection Research Institute Co. Ltd., Beijing 102209, China;
2 School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK;
3 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

收稿日期:2018-12-24 修回日期:2019-02-19 出版日期:2019-12-28 发布日期:2020-03-17
通讯作者: Jianfeng Hu
基金资助:
Supported by the State Key Laboratory of Advanced Power Transmission Technology (GEIRI-SKL-2018-005).

Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

Jianhui Zhou¹, Xiaotong Zhang², Ying Yan³, Jianfeng Hu³, Hang Wang¹, Yan Cai³, Jinqing Qu³

1 State Key Laboratory of Advanced Power Transmission Technology, Global Energy Interconnection Research Institute Co. Ltd., Beijing 102209, China;
2 School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2TT, UK;
3 School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China

Received:2018-12-24 Revised:2019-02-19 Online:2019-12-28 Published:2020-03-17
Contact: Jianfeng Hu
Supported by:
Supported by the State Key Laboratory of Advanced Power Transmission Technology (GEIRI-SKL-2018-005).

摘要/Abstract

摘要： A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction. Capsaicin and acryloyl chloride were firstly esterified, and then applied to solution polymerization with acrylate monomers and styrene. The yield of the esterified products was about 85.3%. The polymer was characterized by Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), contact angle (CA) and antibacterial ring tests. The number-average molecular weight (M_n) of the polymer was 27214, based on the capsaicin-acrylate dosage of 6.5 wt%. The TGA revealed a stable thermal property. The contact angles of the polymers films on tinplate increased from 77.5° to 86.2° with the increasing amount of capsaicin-acrylate. The antibacterial tests demonstrated excellent antimicrobial capability of the polymers.

关键词: Capsaicin, Acrylate polymer, Solution polymerization, Antibacterial

Abstract: A novel antibacterial acrylate polymer composite modified with capsaicin was successfully synthesized by a two-step reaction. Capsaicin and acryloyl chloride were firstly esterified, and then applied to solution polymerization with acrylate monomers and styrene. The yield of the esterified products was about 85.3%. The polymer was characterized by Fourier transform infrared spectroscopy (FTIR), gel permeation chromatography (GPC), thermogravimetric analysis (TGA), contact angle (CA) and antibacterial ring tests. The number-average molecular weight (M_n) of the polymer was 27214, based on the capsaicin-acrylate dosage of 6.5 wt%. The TGA revealed a stable thermal property. The contact angles of the polymers films on tinplate increased from 77.5° to 86.2° with the increasing amount of capsaicin-acrylate. The antibacterial tests demonstrated excellent antimicrobial capability of the polymers.

Key words: Capsaicin, Acrylate polymer, Solution polymerization, Antibacterial

Jianhui Zhou, Xiaotong Zhang, Ying Yan, Jianfeng Hu, Hang Wang, Yan Cai, Jinqing Qu. Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin[J]. 中国化学工程学报, 2019, 27(12): 3043-3052.

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Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

Preparation and characterization of a novel antibacterial acrylate polymer composite modified with capsaicin

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