Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

doi:10.1016/j.cjche.2018.04.022

Chinese Journal of Chemical Engineering ›› 2019, Vol. 27 ›› Issue (2): 369-378.DOI: 10.1016/j.cjche.2018.04.022

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

Zuojun Wei¹, Xinmiao Zhu¹, Xiaoshuang Liu², Haiqin Xu², Xinghua Li¹, Yaxin Hou¹, Yingxin Liu²

1 Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
2 College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014, China

收稿日期:2018-01-16 修回日期:2018-04-10 出版日期:2019-02-28 发布日期:2019-03-18
通讯作者: Yingxin Liu
基金资助:
Supported by the National Natural Science Foundation of China (21476211), and the Zhejiang Provincial Natural Science Foundation of China (LY16B060004 and LY18B060016)

Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

Zuojun Wei¹, Xinmiao Zhu¹, Xiaoshuang Liu², Haiqin Xu², Xinghua Li¹, Yaxin Hou¹, Yingxin Liu²

1 Key Laboratory of Biomass Chemical Engineering of the Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310027, China;
2 College of Pharmaceutical Science, Zhejiang University of Technology, Hangzhou 310014, China

Received:2018-01-16 Revised:2018-04-10 Online:2019-02-28 Published:2019-03-18
Contact: Yingxin Liu
Supported by:
Supported by the National Natural Science Foundation of China (21476211), and the Zhejiang Provincial Natural Science Foundation of China (LY16B060004 and LY18B060016)

摘要/Abstract

摘要： In the present work, a series of Pt-based catalysts, alloyed with a second metal, i.e., Re, Sn, Er, La, and Y, and supported on activated carbon, ordered mesoporous carbon, N-doped mesoporous carbon or reduced graphene oxide (rGO), have been developed for selective hydrogenation of cinnamaldehyde to cinnamylalcohol. Re and rGO were proved to be the most favorable metal dopant and catalyst support, respectively. Pt₅₀Re₅₀/rGO showed the highest cinnamylalcohol selectivity of 89% with 94% conversion of cinnamaldehyde at the reaction conditions of 120℃, 2.0 MPa H₂ and 4 h.

关键词: Catalyst, Hydrogenation, Selectivity, Cinnamaldehyde, Bimetal, Reduced Graphene Oxide

Abstract: In the present work, a series of Pt-based catalysts, alloyed with a second metal, i.e., Re, Sn, Er, La, and Y, and supported on activated carbon, ordered mesoporous carbon, N-doped mesoporous carbon or reduced graphene oxide (rGO), have been developed for selective hydrogenation of cinnamaldehyde to cinnamylalcohol. Re and rGO were proved to be the most favorable metal dopant and catalyst support, respectively. Pt₅₀Re₅₀/rGO showed the highest cinnamylalcohol selectivity of 89% with 94% conversion of cinnamaldehyde at the reaction conditions of 120℃, 2.0 MPa H₂ and 4 h.

Key words: Catalyst, Hydrogenation, Selectivity, Cinnamaldehyde, Bimetal, Reduced Graphene Oxide

Zuojun Wei, Xinmiao Zhu, Xiaoshuang Liu, Haiqin Xu, Xinghua Li, Yaxin Hou, Yingxin Liu. Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol[J]. Chinese Journal of Chemical Engineering, 2019, 27(2): 369-378.

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Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

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