Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K

doi:10.1016/j.cjche.2020.09.065

中国化学工程学报 ›› 2021, Vol. 34 ›› Issue (6): 198-207.DOI: 10.1016/j.cjche.2020.09.065

• Energy Science and Technology • 上一篇下一篇

Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K

Sunita Malik¹, Poonam Jangra Darolia¹, S. K. Garg², V. K. Sharma¹

1 Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India;
2 J. C. Bose University of Science and Technology, YMCA, Faridabad, Haryana, India

收稿日期:2020-07-14 修回日期:2020-09-15 出版日期:2021-06-28 发布日期:2021-08-30
通讯作者: V. K. Sharma
基金资助:
V. K. Sharma and Dr. Sunita are grateful to CSIR for the award of Emeritus Scientist and Research Associate (Reference No. 21 (1061/18/EMR-II). Ms. Poonam Jangra Darolia is also thankful to CSIR for JRF.

Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K

Sunita Malik¹, Poonam Jangra Darolia¹, S. K. Garg², V. K. Sharma¹

1 Department of Chemistry, Maharshi Dayanand University, Rohtak, Haryana, India;
2 J. C. Bose University of Science and Technology, YMCA, Faridabad, Haryana, India

Received:2020-07-14 Revised:2020-09-15 Online:2021-06-28 Published:2021-08-30
Contact: V. K. Sharma
Supported by:
V. K. Sharma and Dr. Sunita are grateful to CSIR for the award of Emeritus Scientist and Research Associate (Reference No. 21 (1061/18/EMR-II). Ms. Poonam Jangra Darolia is also thankful to CSIR for JRF.

摘要/Abstract

摘要： The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols. The densities of binary diesel (2) + 1-alkanols (C₃ or C₄) (3) and ternary Jatropha curcas biodiesel (1) + diesel (2) + 1-alkanols (C₃ or C₄) (3) blends have been reported over full range of composition at temperatures within range 288.15 to 313.15 K. Also densities of Jatropha curcas biodiesel (1) + diesel or 1-alkanols (C₃ or C₄) (2) blends have been measured at 313.15 K. Excess molar volumes, V^E, V₁₂₃^E of binary and ternary blends were calculated from the measured data and the derived properties were correlated to composition using Redlich–Kister equation. A reasonable agreement was found between the measured and estimated values. Further, densities and excess molar volumes data were reasoned to discuss molecular interactions taking into consideration effect of composition and temperature.

关键词: Jatropha curcas biodiesel, Diesel, Alcohols, Blends, Density, Excess molar volumes

Abstract: The present work is focusing on the synthesization and physico-chemical properties of Jatropha curcas biodiesel with diesel and alcohols. The densities of binary diesel (2) + 1-alkanols (C₃ or C₄) (3) and ternary Jatropha curcas biodiesel (1) + diesel (2) + 1-alkanols (C₃ or C₄) (3) blends have been reported over full range of composition at temperatures within range 288.15 to 313.15 K. Also densities of Jatropha curcas biodiesel (1) + diesel or 1-alkanols (C₃ or C₄) (2) blends have been measured at 313.15 K. Excess molar volumes, V^E, V₁₂₃^E of binary and ternary blends were calculated from the measured data and the derived properties were correlated to composition using Redlich–Kister equation. A reasonable agreement was found between the measured and estimated values. Further, densities and excess molar volumes data were reasoned to discuss molecular interactions taking into consideration effect of composition and temperature.

Key words: Jatropha curcas biodiesel, Diesel, Alcohols, Blends, Density, Excess molar volumes

Sunita Malik, Poonam Jangra Darolia, S. K. Garg, V. K. Sharma. Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K[J]. 中国化学工程学报, 2021, 34(6): 198-207.

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Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K

Densities and excess molar volumes of mixtures containing diesel, biodiesel and alkanols at temperatures from 288.15 to 313.15 K

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