Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO2 capture

doi:10.1016/j.cjche.2021.10.011

中国化学工程学报 ›› 2022, Vol. 46 ›› Issue (6): 207-213.DOI: 10.1016/j.cjche.2021.10.011

Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture

Jipeng Dong¹, Fei Wang¹, Guanghui Chen¹, Shougui Wang², Cailin Ji¹, Fei Gao¹

1 Shandong Key Laboratory of Multiphase Fluid Reaction and Separation Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2 Department of Chemical Engineering, Qingdao University of Science and Technology, Gaomi 261500, China

收稿日期:2021-07-06 修回日期:2021-10-24 出版日期:2022-06-28 发布日期:2022-07-20
通讯作者: Fei Gao,E-mail:feigao@tju.edu.cn
基金资助:
This work was funded by the Qingdao Science and Technology Plan Application Foundation Research Project (19-6-2-28-cg).

Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture

Jipeng Dong¹, Fei Wang¹, Guanghui Chen¹, Shougui Wang², Cailin Ji¹, Fei Gao¹

1 Shandong Key Laboratory of Multiphase Fluid Reaction and Separation Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, China;
2 Department of Chemical Engineering, Qingdao University of Science and Technology, Gaomi 261500, China

Received:2021-07-06 Revised:2021-10-24 Online:2022-06-28 Published:2022-07-20
Contact: Fei Gao,E-mail:feigao@tju.edu.cn
Supported by:
This work was funded by the Qingdao Science and Technology Plan Application Foundation Research Project (19-6-2-28-cg).

摘要/Abstract

摘要： Adsorption process is considered to be the most promising alternative for the CO₂ capture to the traditional energy-intensive amine absorption process, and the development of feasible and efficient CO₂ adsorbents is still a challenge. In this work, the NiO@USY (ultrastable Y) composites with different NiO loadings were prepared for the CO₂ adsorption using Ni(NO₃)₂ as the precursor. The composites were characterized by X-ray photoelectron spectroscopy, X-ray diffraction, nitrogen adsorption–desorption test, scanning electron microscopy analysis, and thermogravimetric analysis, and were evaluated for the CO₂ adsorption capacity, CO₂/N₂ adsorption selectivity and CO₂ cycle adsorption capacity. The characterization results show that after the activation at 423 K, the Ni(NO₃)₂ species were well dispersed into the surface of zeolite USY, and after the further activation at 823 K, Ni(NO₃)₂ could be converted into highly dispersed NiO. The adsorption results show that the presence of the active component NiO plays an important role in improving the CO₂ adsorption performance, and the NiO@USY composite with a NiO loading of 1.5 mmol·g^-1 USY support displays a high adsorption capacity and adsorption selectivity for CO₂, and shows a good cycle stability. In addition, the Clausius–Clapeyron equation was used to evaluate the isosteric heat of adsorption of CO₂ on the NiO(1.5)@USY composite, and the heat of adsorption was 17.39–38.34 kJ·mol^-1.

关键词: NiO@USY composites, Carbon dioxide, Adsorption, Separation, Adsorption selectivity

Abstract: Adsorption process is considered to be the most promising alternative for the CO₂ capture to the traditional energy-intensive amine absorption process, and the development of feasible and efficient CO₂ adsorbents is still a challenge. In this work, the NiO@USY (ultrastable Y) composites with different NiO loadings were prepared for the CO₂ adsorption using Ni(NO₃)₂ as the precursor. The composites were characterized by X-ray photoelectron spectroscopy, X-ray diffraction, nitrogen adsorption–desorption test, scanning electron microscopy analysis, and thermogravimetric analysis, and were evaluated for the CO₂ adsorption capacity, CO₂/N₂ adsorption selectivity and CO₂ cycle adsorption capacity. The characterization results show that after the activation at 423 K, the Ni(NO₃)₂ species were well dispersed into the surface of zeolite USY, and after the further activation at 823 K, Ni(NO₃)₂ could be converted into highly dispersed NiO. The adsorption results show that the presence of the active component NiO plays an important role in improving the CO₂ adsorption performance, and the NiO@USY composite with a NiO loading of 1.5 mmol·g^-1 USY support displays a high adsorption capacity and adsorption selectivity for CO₂, and shows a good cycle stability. In addition, the Clausius–Clapeyron equation was used to evaluate the isosteric heat of adsorption of CO₂ on the NiO(1.5)@USY composite, and the heat of adsorption was 17.39–38.34 kJ·mol^-1.

Key words: NiO@USY composites, Carbon dioxide, Adsorption, Separation, Adsorption selectivity

Jipeng Dong, Fei Wang, Guanghui Chen, Shougui Wang, Cailin Ji, Fei Gao. Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture[J]. 中国化学工程学报, 2022, 46(6): 207-213.

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Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture

Fabrication of nickel oxide functionalized zeolite USY composite as a promising adsorbent for CO₂ capture

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