Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe2O4 supported 0D carbon dots with up-conversion property

doi:10.1016/j.cjche.2021.11.026

中国化学工程学报 ›› 2022, Vol. 49 ›› Issue (9): 213-223.DOI: 10.1016/j.cjche.2021.11.026

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Weilong Shi^1,3, Jie Gao², Haoran Sun³, Zhongyi Liu¹, Feng Guo³, Lijing Wang^1,4

1. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
2. School of Life Sciences, Northwestern Polytechnical University, Xi'an 710072, China;
3. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. Henan Engineering Center of New Energy Battery Materials, Henan D&A Engineering Center of Advanced Battery Materials, College of Chemistry and Chemical Engineering, Institute of Architectural Engineering, Shangqiu Normal University, Shangqiu 476000, China

收稿日期:2021-08-28 修回日期:2021-10-19 发布日期:2022-10-19
通讯作者: Zhongyi Liu,E-mail:liuzhongyi@zzu.edu.cn;Feng Guo,E-mail:gfeng0105@126.com;Lijing Wang,E-mail:wanglijing1989@126.com
基金资助:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass Entrepreneurship and Innovation" Project in Jiangsu Province, the Natural Science Basic Research Plan in Shaanxi Province of China (2021JM-047), Science and Technology Research Project of Henan Province (202102210055), and General project of Chinese postdoctoral program (2020M672263).

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Weilong Shi^1,3, Jie Gao², Haoran Sun³, Zhongyi Liu¹, Feng Guo³, Lijing Wang^1,4

1. College of Chemistry, Zhengzhou University, Zhengzhou 450001, China;
2. School of Life Sciences, Northwestern Polytechnical University, Xi'an 710072, China;
3. School of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
4. Henan Engineering Center of New Energy Battery Materials, Henan D&A Engineering Center of Advanced Battery Materials, College of Chemistry and Chemical Engineering, Institute of Architectural Engineering, Shangqiu Normal University, Shangqiu 476000, China

Received:2021-08-28 Revised:2021-10-19 Published:2022-10-19
Contact: Zhongyi Liu,E-mail:liuzhongyi@zzu.edu.cn;Feng Guo,E-mail:gfeng0105@126.com;Lijing Wang,E-mail:wanglijing1989@126.com
Supported by:
The authors would like to acknowledge the founding support from the National Natural Science Foundation of China (21906072 and 22006057), the Natural Science Foundation of Jiangsu Province (BK20190982), Henan Postdoctoral Foundation (202003013), "Doctor of Mass Entrepreneurship and Innovation" Project in Jiangsu Province, the Natural Science Basic Research Plan in Shaanxi Province of China (2021JM-047), Science and Technology Research Project of Henan Province (202102210055), and General project of Chinese postdoctoral program (2020M672263).

摘要/Abstract

摘要： The development of effective visible and near-infrared photocatalysts is highly promising in the current field of photocatalysis. Herein, carbon dots/ZnFe₂O₄ (CDs/ZFO) with coating zero dimensional (0D) CDs on the surface of three dimensional (3D) yolk-shell ZFO spheres was designed and synthesized via a self-templated solvothermal method. The as-prepared CDs/ZFO composites displayed outstanding visible and near-infrared photocatalytic degradation activity of tetracycline (TC), and the optimal 3% CDs/ZFO sample with loading 3% (mass) CDs displayed the highest photocatalytic TC degradation ability under visible light (79.5% within 120 min) and near-infrared light (41% within 120 min). The enhancement of photocatalytic activity for CDs/ZFO composite is mainly ascribed to the fact that 0D/3D yolk-shell CDs/ZFO structure not only effectively reflect the incident light to increase the utilization efficiency of solar light, but also utilize the up-conversion photoluminescence and electronic conductivity properties of CDs to broaden sunlight absorption range and promote separation and transfer of electron-hole pairs.

关键词: Carbon dots, ZnFe₂O₄, York-shell, Near-infrared, Photocatalytic

Abstract: The development of effective visible and near-infrared photocatalysts is highly promising in the current field of photocatalysis. Herein, carbon dots/ZnFe₂O₄ (CDs/ZFO) with coating zero dimensional (0D) CDs on the surface of three dimensional (3D) yolk-shell ZFO spheres was designed and synthesized via a self-templated solvothermal method. The as-prepared CDs/ZFO composites displayed outstanding visible and near-infrared photocatalytic degradation activity of tetracycline (TC), and the optimal 3% CDs/ZFO sample with loading 3% (mass) CDs displayed the highest photocatalytic TC degradation ability under visible light (79.5% within 120 min) and near-infrared light (41% within 120 min). The enhancement of photocatalytic activity for CDs/ZFO composite is mainly ascribed to the fact that 0D/3D yolk-shell CDs/ZFO structure not only effectively reflect the incident light to increase the utilization efficiency of solar light, but also utilize the up-conversion photoluminescence and electronic conductivity properties of CDs to broaden sunlight absorption range and promote separation and transfer of electron-hole pairs.

Key words: Carbon dots, ZnFe₂O₄, York-shell, Near-infrared, Photocatalytic

Weilong Shi, Jie Gao, Haoran Sun, Zhongyi Liu, Feng Guo, Lijing Wang. Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property[J]. 中国化学工程学报, 2022, 49(9): 213-223.

参考文献

[1] Y.H. Yang, X.L. Li, C. Lu, W.H. Huang, G-C₃N₄ nanosheets coupled with TiO₂ nanosheets as 2D/2D heterojunction photocatalysts toward high photocatalytic activity for hydrogen production, Catal. Lett. 149 (10) (2019) 2930-2939.http://dx.doi.org/10.1007/s10562-019-02805-8
[2] J.F. Niu, S.Y. Ding, L.W. Zhang, J.B. Zhao, C.H. Feng, Visible-light-mediated Sr-Bi₂O₃ photocatalysis of tetracycline:Kinetics, mechanisms and toxicity assessment, Chemosphere 93 (1) (2013) 1-8.https://pubmed.ncbi.nlm.nih.gov/23706401/
[3] H. Xu, Q. Ye, Q.G. Wang, P. Zhou, X.W. Huo, Y.Q. Wang, X. Huang, G.Y. Zhou, J. Zhang, Enhancement of organic contaminants degradation at low dosages of Fe(III) and H₂O₂ in g-C₃N₄ promoted Fe(III)/H₂O₂ system under visible light irradiation, Sep. Purif. Technol. 251 (2020) 117333.http://dx.doi.org/10.1016/j.seppur.2020.117333
[4] F. Guo, W.L. Shi, M.Y. Li, Y. Shi, H.B. Wen, 2D/2D Z-scheme heterojunction of CuInS₂/g-C₃N₄ for enhanced visible-light-driven photocatalytic activity towards the degradation of tetracycline, Sep. Purif. Technol. 210 (2019) 608-615.http://dx.doi.org/10.1016/j.seppur.2018.08.055
[5] F. Guo, M.Y. Li, H.J. Ren, X.L. Huang, W.X. Hou, C. Wang, W.L. Shi, C.Y. Lu, Fabrication of p-n CuBi₂O₄/MoS₂ heterojunction with nanosheets-on-microrods structure for enhanced photocatalytic activity towards tetracycline degradation, Appl. Surf. Sci. 491 (2019) 88-94.http://dx.doi.org/10.1016/j.apsusc.2019.06.158
[6] F. Guo, M.Y. Li, H.J. Ren, X.L. Huang, K.K. Shu, W.L. Shi, C.Y. Lu, Facile bottom-up preparation of Cl-doped porous g-C₃N₄ nanosheets for enhanced photocatalytic degradation of tetracycline under visible light, Sep. Purif. Technol. 228 (2019) 115770.http://dx.doi.org/10.1016/j.seppur.2019.115770
[7] Q. Zhu, Y.K. Sun, F.S. Na, J. Wei, S. Xu, Y.L. Li, F. Guo, Fabrication of CdS/titanium-oxo-cluster nanocomposites based on a Ti32 framework with enhanced photocatalytic activity for tetracycline hydrochloride degradation under visible light, Appl. Catal. B Environ. 254 (2019) 541-550.http://dx.doi.org/10.1016/j.apcatb.2019.05.006
[8] C.Y. Lu, F. Guo, Q.Z. Yan, Z.J. Zhang, D. Li, L.P. Wang, Y.H. Zhou, Hydrothermal synthesis of type II ZnIn₂S₄/BiPO₄ heterojunction photocatalyst with dandelion-like microflower structure for enhanced photocatalytic degradation of tetracycline under simulated solar light, J. Alloys Compd. 811 (2019) 151976.http://dx.doi.org/10.1016/j.jallcom.2019.151976
[9] Q.Y. Tian, W.J. Yao, W. Wu, C.Z. Jiang, NIR light-activated upconversion semiconductor photocatalysts, Nanoscale horiz. 4 (1) (2019) 10-25.https://doi.org/10.1039/c8nh00154e
[10] B.T. Sun, P.Y. Qiu, Z.Q. Liang, Y.J. Xue, X.L. Zhang, L. Yang, H.Z. Cui, J. Tian, The fabrication of 1D/2D CdS nanorod@Ti₃C₂ MXene composites for good photocatalytic activity of hydrogen generation and ammonia synthesis, Chem. Eng. J. 406 (2021) 127177.http://dx.doi.org/10.1016/j.cej.2020.127177
[11] W. Xiao, X.H. Wang, R.X. Liu, J. Wu, Quinuclidine and its derivatives as hydrogen-atom-transfer catalysts in photoinduced reactions, Chin. Chem. Lett. 32 (6) (2021) 1847-1856.http://dx.doi.org/10.1016/j.cclet.2021.02.009
[12] Z.Q. Liang, X.F. Meng, Y.J. Xue, X.Y. Chen, Y.L. Zhou, X.L. Zhang, H.Z. Cui, J. Tian, Facile preparation of metallic 1T phase molybdenum selenide as cocatalyst coupled with graphitic carbon nitride for enhanced photocatalytic H₂ production, J. Colloid Interface Sci. 598 (2021) 172-180.http://dx.doi.org/10.1016/j.jcis.2021.04.066
[13] P.Y. Qiu, J.W. Wang, Z.Q. Liang, Y.J. Xue, Y.L. Zhou, X.L. Zhang, H.Z. Cui, G.Q. Cheng, J. Tian, The metallic 1T-WS₂ as cocatalysts for promoting photocatalytic N₂ fixation performance of Bi₅O₇Br nanosheets, Chin. Chem. Lett. 32 (11) (2021) 3501-3504.http://dx.doi.org/10.1016/j.cclet.2021.03.077
[14] J.J. Pan, F. Guo, H.R. Sun, Y.X. Shi, W.L. Shi, Nanodiamonds anchored on porous ZnSnO₃ cubes as an efficient composite photocatalyst with improved visible-light photocatalytic degradation of tetracycline, Sep. Purif. Technol. 263 (2021) 118398.http://dx.doi.org/10.1016/j.seppur.2021.118398
[15] R.J. Guo, R. Tian, D.L. Shi, H. Li, H.Z. Liu, S-doped ZnSnO₃ nanoparticles with narrow band gaps for photocatalytic wastewater treatment, ACS Appl. Nano Mater. 2 (12) (2019) 7755-7765.https://doi.org/10.1021/acsanm.9b01804
[16] G.D. Fan, X. Lin, Y.F. You, B.H. Du, X. Li, J. Luo, Magnetically separable ZnFe₂O₄/Ag₃PO₄/g-C₃N₄ photocatalyst for inactivation of Microcystis aeruginosa:Characterization, performance and mechanism, J. Hazard. Mater. 421 (2022) 126703.http://dx.doi.org/10.1016/j.jhazmat.2021.126703
[17] L.J. Wang, R.Q. Guan, Y.F. Qi, F.L. Zhang, P. Li, J.M. Wang, P. Qu, G. Zhou, W.L. Shi, Constructing Zn-P charge transfer bridge over ZnFe₂O₄-black phosphorus 3D microcavity structure:efficient photocatalyst design in visible-near-infrared region, J. Colloid Interface Sci. 600 (2021) 463-472.http://dx.doi.org/10.1016/j.jcis.2021.05.043
[18] E. Mrotek, S. Dudziak, I. Malinowska, D. Pelczarski, Z. Ryżyńska, A. Zielińska-Jurek, Improved degradation of etodolac in the presence of core-shell ZnFe₂O₄/SiO₂/TiO₂ magnetic photocatalyst, Sci. Total. Environ. 724 (2020) 138167.http://dx.doi.org/10.1016/j.scitotenv.2020.138167
[19] K.K. Das, S. Patnaik, B. Nanda, A.C. Pradhan, K. Parida, ZnFe₂O₄-decorated mesoporous Al₂O₃Modified MCM-41:a solar-light-active photocatalyst for the effective removal of phenol and Cr (VI) from water, ChemistrySelect 4 (5) (2019) 1806-1819.https://doi.org/10.1002/slct.201803209
[20] F.X. Wang, Y.L. Chen, R.S. Zhu, J.M. Sun, Novel synthesis of magnetic, porous C/ZnFe ₂ O₄ photocatalyst with enhanced activity under visible light based on the Fenton-like reaction, Dalton Trans. 46 (34) (2017) 11306-11317.https://pubmed.ncbi.nlm.nih.gov/28805864/
[21] W.Q. Zhang, M. Wang, W.J. Zhao, B.Q. Wang, Magnetic composite photocatalyst ZnFe₂O₄/BiVO₄:synthesis, characterization, and visible-light photocatalytic activity, Dalton Trans. 42 (43) (2013) 15464.https://doi.org/10.1039/c3dt52068d
[22] T.H. Yu, W.Y. Cheng, K.J. Chao, S.Y. Lu, ZnFe₂O₄ decorated CdS nanorods as a highly efficient, visible light responsive, photochemically stable, magnetically recyclable photocatalyst for hydrogen generation, Nanoscale 5 (16) (2013) 7356-7360.https://pubmed.ncbi.nlm.nih.gov/23824310/
[23] Y.J. Yao, J.C. Qin, H. Chen, F.Y. Wei, X.T. Liu, J.L. Wang, S.B. Wang, One-pot approach for synthesis of N-doped TiO₂/ZnFe₂O₄ hybrid as an efficient photocatalyst for degradation of aqueous organic pollutants, J. Hazard. Mater. 291 (2015) 28-37.http://dx.doi.org/10.1016/j.jhazmat.2015.02.042
[24] F. Guo, X.L. Huang, Z.H. Chen, Y.X. Shi, H.R. Sun, X.F. Cheng, W.L. Shi, L.Z. Chen, Formation of unique hollow ZnSnO₃@ZnIn₂S₄ core-shell heterojunction to boost visible-light-driven photocatalytic water splitting for hydrogen production, J. Colloid Interface Sci. 602 (2021) 889-897.http://dx.doi.org/10.1016/j.jcis.2021.06.074
[25] M.L. Ma, Y.Y. Yang, W.T. Li, Y. Ma, Z.Y. Tong, W.B. Huang, L. Chen, G.L. Wu, H.L. Wang, P. Lyu, Synthesis of yolk-shell structure Fe₃O₄/P(MAA-MBAA)-PPy/Au/void/TiO₂ magnetic microspheres as visible light active photocatalyst for degradation of organic pollutants, J. Alloys Compd. 810 (2019) 151807.http://dx.doi.org/10.1016/j.jallcom.2019.151807
[26] X.N. Gao, X.Y. Wang, Z. Yang, Y.H. Shen, A.J. Xie, A novel bi-functional SiO₂@TiO₂/CDs nanocomposite with yolk-shell structure as both efficient SERS substrate and photocatalyst, Appl. Surf. Sci. 475 (2019) 135-142.http://dx.doi.org/10.1016/j.apsusc.2018.12.250
[27] W.N. Wang, C.X. Huang, C.Y. Zhang, M.L. Zhao, J. Zhang, H.J. Chen, Z.B. Zha, T.T. Zhao, H.S. Qian, Controlled synthesis of upconverting nanoparticles/Zn_xCd_1-xS yolk-shell nanoparticles for efficient photocatalysis driven by NIR light, Appl. Catal. B Environ. 224 (2018) 854-862.http://dx.doi.org/10.1016/j.apcatb.2017.11.037
[28] Z.F. Jiang, C.Z. Zhu, W.M. Wan, K. Qian, J.M. Xie, Constructing graphite-like carbon nitride modified hierarchical yolk-shell TiO₂ spheres for water pollution treatment and hydrogen production, J. Mater. Chem. A 4 (5) (2016) 1806-1818.https://doi.org/10.1039/c5ta09919f
[29] F. Guo, X.L. Huang, Z.H. Chen, H.R. Sun, W.L. Shi, Investigation of visible-light-driven photocatalytic tetracycline degradation via carbon dots modified porous ZnSnO₃ cubes:mechanism and degradation pathway, Sep. Purif. Technol. 253 (2020) 117518.http://dx.doi.org/10.1016/j.seppur.2020.117518
[30] Q. Zhou, W.Y. Huang, C. Xu, X. Liu, K. Yang, D. Li, Y. Hou, D.D. Dionysiou, Novel hierarchical carbon quantum dots-decorated BiOCl nanosheet/carbonized eggshell membrane composites for improved removal of organic contaminants from water via synergistic adsorption and photocatalysis, Chem. Eng. J. 420 (2021) 129582.http://dx.doi.org/10.1016/j.cej.2021.129582
[31] J. Di, J.X. Xia, X.L. Chen, M.X. Ji, S. Yin, Q. Zhang, H.M. Li, Tunable oxygen activation induced by oxygen defects in nitrogen doped carbon quantum dots for sustainable boosting photocatalysis, Carbon 114 (2017) 601-607.http://dx.doi.org/10.1016/j.carbon.2016.12.030
[32] W.L. Shi, F. Guo, M.Y. Li, Y. Shi, M.F. Wu, Y.B. Tang, Enhanced visible-light-driven photocatalytic H₂ evolution on the novel nitrogen-doped carbon dots/CuBi₂O₄ microrods composite, J. Alloys Compd. 775 (2019) 511-517.http://dx.doi.org/10.1016/j.jallcom.2018.10.095
[33] M.Y. Li, C.J. Ma, G.L. Wang, X.F. Zhang, X.L. Dong, H.C. Ma, Controlling the up-conversion photoluminescence property of carbon quantum dots (CQDs) by modifying its surface functional groups for enhanced photocatalytic performance of CQDs/BiVO₄ under a broad-spectrum irradiation, Res. Chem. Intermed. 47 (8) (2021) 3469-3485.http://dx.doi.org/10.1007/s11164-021-04459-x
[34] S.Q. Huang, Q. Zhang, P.Y. Liu, S.J. Ma, B. Xie, K. Yang, Y.P. Zhao, Novel up-conversion carbon quantum dots/α-FeOOH nanohybrids eliminate tetracycline and its related drug resistance in visible-light responsive Fenton system, Appl. Catal. B Environ. 263 (2020) 118336.http://dx.doi.org/10.1016/j.apcatb.2019.118336
[35] X. Zhang, X.H. Li, C.L. Shao, J.H. Li, M.Y. Zhang, P. Zhang, K.X. Wang, N. Lu, Y.C. Liu, One-dimensional hierarchical heterostructures of In₂S₃ nanosheets on electrospun TiO₂ nanofibers with enhanced visible photocatalytic activity, J. Hazard. Mater. 260 (2013) 892-900.http://dx.doi.org/10.1016/j.jhazmat.2013.06.024
[36] W.L. Shi, F. Guo, M.Y. Li, Y. Shi, Y.B. Tang, N-doped carbon dots/CdS hybrid photocatalyst that responds to visible/near-infrared light irradiation for enhanced photocatalytic hydrogen production, Sep. Purif. Technol. 212 (2019) 142-149.http://dx.doi.org/10.1016/j.seppur.2018.11.028
[37] Z.J. Guan, P. Wang, Q.Y. Li, G.Q. Li, J.J. Yang, Constructing a ZnIn ₂ S₄ nanoparticle/MoS ₂-RGO nanosheet 0D/2D heterojunction for significantly enhanced visible-light photocatalytic H₂ production, Dalton Trans. 47 (19) (2018) 6800-6807.https://pubmed.ncbi.nlm.nih.gov/29722778/
[38] J.G. Hou, C. Yang, H.J. Cheng, Z. Wang, S.Q. Jiao, H.M. Zhu, Ternary 3D architectures of CdS QDs/graphene/ZnIn₂S₄ heterostructures for efficient photocatalytic H₂ production, Phys. Chem. Chem. Phys. 15 (37) (2013) 15660-15668.https://pubmed.ncbi.nlm.nih.gov/23942887/
[39] W.L. Shi, F. Guo, H.B. Wang, M.M. Han, H. Li, S.L. Yuan, H. Huang, Y. Liu, Z.H. Kang, Carbon dots decorated the exposing high-reactive (111) facets CoO octahedrons with enhanced photocatalytic activity and stability for tetracycline degradation under visible light irradiation, Appl. Catal. B Environ. 219 (2017) 36-44.http://dx.doi.org/10.1016/j.apcatb.2017.07.019
[40] W.L. Shi, F. Guo, H.B. Wang, C.G. Liu, Y.J. Fu, S.L. Yuan, H. Huang, Y. Liu, Z.H. Kang, Carbon dots decorated magnetic ZnFe₂O₄ nanoparticles with enhanced adsorption capacity for the removal of dye from aqueous solution, Appl. Surf. Sci. 433 (2018) 790-797.http://dx.doi.org/10.1016/j.apsusc.2017.10.099
[41] H.K. Zhu, M.H. Fang, Z.H. Huang, Y.G. Liu, K. Chen, C. Tang, M. Wang, L.N. Zhang, X.W. Wu, Novel carbon-incorporated porous ZnFe₂O₄nanospheres for enhanced photocatalytic hydrogen generation under visible light irradiation, RSC Adv. 6 (61) (2016) 56069-56076.https://doi.org/10.1039/c6ra05098k
[42] W. Liu, Y.Y. Li, F.Y. Liu, W. Jiang, D.D. Zhang, J.L. Liang, Visible-light-driven photocatalytic degradation of diclofenac by carbon quantum dots modified porous g-C ₃ N₄:Mechanisms, degradation pathway and DFT calculation, Water Res. 151 (2019) 8-19.https://pubmed.ncbi.nlm.nih.gov/30579052/
[43] Y.S. Fu, X. Wang, Magnetically separable ZnFe₂O₄-graphene catalyst and its high photocatalytic performance under visible light irradiation, Ind. Eng. Chem. Res. 50 (12) (2011) 7210-7218.http://dx.doi.org/10.1021/ie200162a
[44] W.L. Shi, H.C. Lv, S.L. Yuan, H. Huang, Y. Liu, Z.H. Kang, Near-infrared light photocatalytic ability for degradation of tetracycline using carbon dots modified Ag/AgBr nanocomposites, Sep. Purif. Technol. 174 (2017) 75-83.http://dx.doi.org/10.1016/j.seppur.2016.10.005
[45] Y. Hou, X.Y. Li, Q.D. Zhao, X. Quan, G.H. Chen, Electrochemical method for synthesis of a ZnFe₂O₄/TiO₂ composite nanotube array modified electrode with enhanced photoelectrochemical activity, Adv. Funct. Mater. 20 (13) (2010) 2165-2174.https://doi.org/10.1002/adfm.200902390
[46] Y. Hou, F. Zuo, A. Dagg, P.Y. Feng, A three-dimensional branched cobalt-doped α-Fe₂O₃ nanorod/MgFe₂O₄ heterojunction array as a flexible photoanode for efficient photoelectrochemical water oxidation, Angew. Chem. Int. Ed Engl. 52 (4) (2013) 1248-1252.https://pubmed.ncbi.nlm.nih.gov/23225666/
[47] H. Kong, J. Song, J. Jang, One-step fabrication of magnetic γ-Fe₂O₃/polyrhodanine nanoparticles using in situ chemical oxidation polymerization and their antibacterial properties, Chem. Commun. 46 (36) (2010) 6735.https://doi.org/10.1039/c0cc00736f
[48] P.L. Liang, L.Y. Yuan, H. Deng, X.C. Wang, L. Wang, Z.J. Li, S.Z. Luo, W.Q. Shi, Photocatalytic reduction of uranium(VI) by magnetic ZnFe₂O₄ under visible light, Appl. Catal. B Environ. 267 (2020) 118688.http://dx.doi.org/10.1016/j.apcatb.2020.118688
[49] H.L. Zhang, C.X. Zhu, G.H. Zhang, M. Li, Q.J. Tang, J.L. Cao, Palladium modified ZnFe₂O₄/g-C₃N₄ nanocomposite as an efficiently magnetic recycling photocatalyst, J. Solid State Chem. 288 (2020) 121389.http://dx.doi.org/10.1016/j.jssc.2020.121389
[50] A. Velumani, P. Sengodan, P. Arumugam, R. Rajendran, S. Santhanam, M. Palanisamy, Carbon quantum dots supported ZnO sphere based photocatalyst for dye degradation application, Curr. Appl. Phys. 20 (10) (2020) 1176-1184.http://dx.doi.org/10.1016/j.cap.2020.07.016
[51] H.R. Sun, F. Guo, J.J. Pan, W. Huang, K. Wang, W.L. Shi, One-pot thermal polymerization route to prepare N-deficient modified g-C₃N₄ for the degradation of tetracycline by the synergistic effect of photocatalysis and persulfate-based advanced oxidation process, Chem. Eng. J. 406 (2021) 126844.http://dx.doi.org/10.1016/j.cej.2020.126844
[52] F. Guo, H.R. Sun, X.L. Huang, W.L. Shi, C. Yan, Fabrication of TiO 2/high-crystalline g-C ₃ N₄ composite with enhanced visible-light photocatalytic performance for tetracycline degradation, J. Chem. Technol. Biotechnol. (2020) jctb.6384.https://doi.org/10.1002/jctb.6384
[53] F. Guo, L.J. Wang, H.R. Sun, M.Y. Li, W.L. Shi, High-efficiency photocatalytic water splitting by a N-doped porous g-C₃N₄ nanosheet polymer photocatalyst derived from urea and N, N-dimethylformamide, Inorg. Chem. Front. 7 (8) (2020) 1770-1779.https://doi.org/10.1039/d0qi00117a
[54] F. Guo, H.R. Sun, L. Cheng, W.L. Shi, Oxygen-defective ZnO porous nanosheets modified by carbon dots to improve their visible-light photocatalytic activity and gain mechanistic insight, New J. Chem. 44 (26) (2020) 11215-11223.https://doi.org/10.1039/d0nj02268c
[55] W.L. Shi, S. Yang, H.R. Sun, J.B. Wang, X. Lin, F. Guo, J.Y. Shi, Carbon dots anchored high-crystalline g-C₃N₄ as a metal-free composite photocatalyst for boosted photocatalytic degradation of tetracycline under visible light, J. Mater. Sci. 56 (3) (2021) 2226-2240.http://dx.doi.org/10.1007/s10853-020-05436-2
[56] W.L. Shi, J.B. Wang, S. Yang, X. Lin, F. Guo, J.Y. Shi, Fabrication of a ternary carbon dots/CoO/g-C ₃ N₄ nanocomposite photocatalyst with enhanced visible-light-driven photocatalytic hydrogen production, J. Chem. Technol. Biotechnol. 95 (8) (2020) 2129-2138.https://doi.org/10.1002/jctb.6398
[57] F. Guo, Z.H. Chen, X.L. Huang, L.W. Cao, X.F. Cheng, W.L. Shi, L.Z. Chen, Cu₃P nanoparticles decorated hollow tubular carbon nitride as a superior photocatalyst for photodegradation of tetracycline under visible light, Sep. Purif. Technol. 275 (2021) 119223.http://dx.doi.org/10.1016/j.seppur.2021.119223
[58] Z.H. Chen, F. Guo, H.R. Sun, Y.X. Shi, W.L. Shi, Well-designed three-dimensional hierarchical hollow tubular g-C₃N₄/ZnIn₂S₄ nanosheets heterostructure for achieving efficient visible-light photocatalytic hydrogen evolution, J. Colloid Interface Sci. 607 (2022) 1391-1401.http://dx.doi.org/10.1016/j.jcis.2021.09.095
[59] F. Guo, X.L. Huang, Z.H. Chen, H.R. Sun, L.Z. Chen, Prominent co-catalytic effect of CoP nanoparticles anchored on high-crystalline g-C₃N₄ nanosheets for enhanced visible-light photocatalytic degradation of tetracycline in wastewater, Chem. Eng. J. 395 (2020) 125118.http://dx.doi.org/10.1016/j.cej.2020.125118
[60] W.L. Shi, M.Y. Li, H.J. Ren, F. Guo, X.L. Huang, Y. Shi, Y.B. Tang, Construction of a 0D/1D composite based on Au nanoparticles/CuBi₂O₄ microrods for efficient visible-light-driven photocatalytic activity, Beilstein J. Nanotechnol. 10 (2019) 1360-1367.https://doi.org/10.3762/bjnano.10.134
[61] S.H. Wang, L. Zhao, W. Huang, H. Zhao, J.Y. Chen, Q. Cai, X. Jiang, C.Y. Lu, W.L. Shi, Solvothermal synthesis of CoO/BiVO₄ p-n heterojunction with micro-nano spherical structure for enhanced visible light photocatalytic activity towards degradation of tetracycline, Mater. Res. Bull. 135 (2021) 111161.http://dx.doi.org/10.1016/j.materresbull.2020.111161
[62] F. Guo, X.L. Huang, Z.H. Chen, L.W. Cao, X.F. Cheng, L.Z. Chen, W.L. Shi, Construction of Cu₃P-ZnSnO₃-g-C₃N₄ p-n-n heterojunction with multiple built-in electric fields for effectively boosting visible-light photocatalytic degradation of broad-spectrum antibiotics, Sep. Purif. Technol. 265 (2021) 118477.http://dx.doi.org/10.1016/j.seppur.2021.118477
[63] E.L. Liu, X. Lin, Y.Z. Hong, L. Yang, B.F. Luo, W.L. Shi, J.Y. Shi, Rational copolymerization strategy engineered C self-doped g-C₃N₄ for efficient and robust solar photocatalytic H₂ evolution, Renew. Energy 178 (2021) 757-765.http://dx.doi.org/10.1016/j.renene.2021.06.066
[64] F. Guo, L.J. Wang, H.R. Sun, M.Y. Li, W.L. Shi, X. Lin, A one-pot sealed ammonia self-etching strategy to synthesis of N-defective g-C₃N₄ for enhanced visible-light photocatalytic hydrogen, Int. J. Hydrog. Energy 45 (55) (2020) 30521-30532.http://dx.doi.org/10.1016/j.ijhydene.2020.08.080
[65] X. Tang, Y. Yu, C.C. Ma, G.S. Zhou, X.L. Liu, M.S. Song, Z.Y. Lu, L. Liu, The fabrication of a biomass carbon quantum dot-Bi₂WO₆ hybrid photocatalyst with high performance for antibiotic degradation, New J. Chem. 43 (47) (2019) 18860-18867.https://doi.org/10.1039/c9nj04764f
[66] H. Li, H.B. Wang, J.Q. Guo, S. Ye, W.L. Shi, X. Peng, J. Song, J.L. Qu, Long-wavelength excitation of carbon dots as the probe for real-time imaging of the living-cell cycle process, Sens. Actuat. B Chem. 311 (2020) 127891.http://dx.doi.org/10.1016/j.snb.2020.127891
[67] N. Roy, Y. Shibano, C. Terashima, K.I. Katsumata, K. Nakata, T. Kondo, M. Yuasa, A. Fujishima, Ionic-liquid-assisted selective and controlled electrochemical CO₂ reduction at Cu-modified boron-doped diamond electrode, ChemElectroChem 3 (7) (2016) 1044-1047.https://doi.org/10.1002/celc.201600105
[68] G.D. Jiang, K. Geng, Y. Wu, Y.H. Han, X.D. Shen, High photocatalytic performance of ruthenium complexes sensitizing g-C₃N₄/TiO₂ hybrid in visible light irradiation, Appl. Catal. B Environ. 227 (2018) 366-375.http://dx.doi.org/10.1016/j.apcatb.2018.01.034
[69] H. Jin, R.J. Gui, J. Sun, Y.F. Wang, Retraction notice to "Facilely self-assembled magnetic nanoparticles/aptamer/carbon dots nanocomposites for highly sensitive up-conversion fluorescence turn-on detection of tetrodotoxin" Talanta 176 (2018) 277-283, Talanta 204 (2019) 882.http://dx.doi.org/10.1016/j.talanta.2019.06.097
[70] J.J. Pan, F. Guo, H.R. Sun, M.Y. Li, X.F. Zhu, L.L. Gao, W.L. Shi, Nanodiamond decorated 2D hexagonal Fe₂O₃ nanosheets with a Z-scheme photogenerated electron transfer path for enhanced photocatalytic activity, J. Mater. Sci. 56 (11) (2021) 6663-6675.http://dx.doi.org/10.1007/s10853-020-05700-5
[71] Y. Hu, K. Chen, Y.L. Li, J.Y. He, K.S. Zhang, T. Liu, W. Xu, X.J. Huang, L.T. Kong, J.H. Liu, Morphology-tunable WMoO nanowire catalysts for the extremely efficient elimination of tetracycline:kinetics, mechanisms and intermediates, Nanoscale 11 (3) (2019) 1047-1057.https://pubmed.ncbi.nlm.nih.gov/30569932/
[72] Z.Y. Lu, Z.H. Yu, J.B. Dong, M.S. Song, Y. Liu, X.L. Liu, Z.F. Ma, H. Su, Y.S. Yan, P.W. Huo, Facile microwave synthesis of a Z-scheme imprinted ZnFe₂O₄/Ag/PEDOT with the specific recognition ability towards improving photocatalytic activity and selectivity for tetracycline, Chem. Eng. J. 337 (2018) 228-241.http://dx.doi.org/10.1016/j.cej.2017.12.115

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

Highly efficient visible/near-infrared light photocatalytic degradation of antibiotic wastewater over 3D yolk-shell ZnFe₂O₄ supported 0D carbon dots with up-conversion property

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Jingjing Pan, Haoran Sun, Keyi Chen, Yuhao Zhang, Pengnian Shan, Weilong Shi, Feng Guo. Nanodiamonds decorated yolk-shell ZnFe₂O₄ sphere as magnetically separable and recyclable composite for boosting antibiotic degradation performance[J]. 中国化学工程学报, 2023, 54(2): 162-172.
[2]	Duanlian Tang, Xiaoyan Chen, Jiayan Yan, Zhuo Xiong, Xiaoyu Lou, Changshen Ye, Jie Chen, Ting Qiu. Facile one-pot synthesis of a BiOBr/Bi₂WO₆ heterojunction with enhanced visible-light photocatalytic activity for tetracycline degradation[J]. 中国化学工程学报, 2023, 53(1): 222-231.
[3]	Feng Guo, Chunli Shi, Wei Sun, Yanan Liu, Xue Lin, Weilong Shi. Pomelo biochar as an electron acceptor to modify graphitic carbon nitride for boosting visible-light-driven photocatalytic degradation of tetracycline[J]. 中国化学工程学报, 2022, 48(8): 1-11.
[4]	Hao Zhou, Qi Yin. Hydrothermal preparation of Nb-doped NaTaO₃ with enhanced photocatalytic activity for removal of organic dye[J]. 中国化学工程学报, 2022, 46(6): 142-149.
[5]	Linlan Wu, Zhengxin Jiao, Suhang Xun, Minqiang He, Lei Fan, Chao Wang, Wenshu Yang, Wenshuai Zhu, Huaming Li. Photocatalytic oxidative of Keggin-type polyoxometalate ionic liquid for enhanced extractive desulfurization in binary deep eutectic solvents[J]. 中国化学工程学报, 2022, 44(4): 205-211.
[6]	Xiaoqing Yan, Hua An, Zihao Chen, Guidong Yang. Significantly enhanced charge transfer efficiency and surface reaction on NiP₂/g-C₃N₄ heterojunction for photocatalytic hydrogen evolution[J]. 中国化学工程学报, 2022, 43(3): 31-39.
[7]	Weilong Shi, Yanan Liu, Wei Sun, Yuanzhi Hong, Xiangyu Li, Xue Lin, Feng Guo, Junyou Shi. Improvement of synergistic effect photocatalytic/peroxymonosulfate activation for degradation of amoxicillin using carbon dots anchored on rod-like CoFe₂O₄[J]. 中国化学工程学报, 2022, 52(12): 136-145.
[8]	Shaojing Zhao, Li Huang, Yong Xie, Bin Wang, Feng Wang, Minhuan Lan. Green synthesis of multifunctional carbon dots for anti-cancer and anti-fungal applications[J]. 中国化学工程学报, 2021, 37(9): 97-104.
[9]	Mohammed Abdullah Issa, Zurina Zainal Abidin, Shafreeza Sobri, Suraya Abdul-Rashid, Mohd Adzir Mahdi, Nor Azowa Ibrahim, Musa Y. Pudza. Fabrication, characterization and response surface method optimization for quantum efficiency of fluorescent nitrogen-doped carbon dots obtained from carboxymethylcellulose of oil palms empty fruit bunch[J]. 中国化学工程学报, 2020, 28(2): 584-592.
[10]	Tao Yang, Fen Liu, Houfeng Xiong, Qiyong Yang, Fushan Chen, Changchao Zhan. Fouling process and anti-fouling mechanisms of dynamic membrane assisted by photocatalytic oxidation under sub-critical fluxes[J]. 中国化学工程学报, 2019, 27(8): 1798-1806.
[11]	Yangyang Yu, Kejing Wu, Shiyu Lu, Kui Ma, Shan Zhong, Hegui Zhang, Yingming Zhu, Jing Guo, Hairong Yue, Changjun Liu, Siyang Tang, Bin Liang. Engineering an ultrathin amorphous TiO₂ layer for boosting the weatherability of TiO₂ pigment with high lightening power[J]. 中国化学工程学报, 2019, 27(11): 2825-2834.
[12]	Kaixun He, Kai Wang, Yayun Yan. Active training sample selection and updating strategy for near-infrared model with an industrial application[J]. 中国化学工程学报, 2019, 27(11): 2749-2758.
[13]	Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao. Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1528-1535.
[14]	Abdus Samad, Shamim Ahsan, Ikki Tateishi, Mai Furukawa, Hideyuki Katsumata, Tohru Suzuki, Satoshi Kaneco. Indirect photocatalytic reduction of arsenate to arsenite in aqueous solution with TiO₂ in the presence of hole scavengers[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 529-533.
[15]	Feng Zhang, Zhilong Xu, Kun Wang, Rizhi Chen, Zhaoxiang Zhong, Weihong Xing. Controllable preparation of ZnO porous flower through a membrane dispersion reactor and their photocatalytic properties[J]. Chinese Journal of Chemical Engineering, 2018, 26(10): 2192-2198.