Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe3+/TiO2 catalyst

doi:10.1016/j.cjche.2018.01.017

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (7): 1528-1535.DOI: 10.1016/j.cjche.2018.01.017

• Energy, Resources and Environmental Technology • 上一篇下一篇

Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst

Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao

Beijing Engineering Research Center of Process Pollution Control, Division of Environment Technology and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

收稿日期:2017-10-29 修回日期:2017-12-05 出版日期:2018-07-28 发布日期:2018-08-16
通讯作者: Hongbin Cao,E-mail address:hbcao@ipe.ac.cn
基金资助:
Supported by the Natural Science Foundation of Beijing City (8172043), the National Science Fund for Distinguished Young Scholars (51425405) and National Natural Science Foundation of China (51378487).

Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst

Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao

Beijing Engineering Research Center of Process Pollution Control, Division of Environment Technology and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China

Received:2017-10-29 Revised:2017-12-05 Online:2018-07-28 Published:2018-08-16
Contact: Hongbin Cao,E-mail address:hbcao@ipe.ac.cn
Supported by:
Supported by the Natural Science Foundation of Beijing City (8172043), the National Science Fund for Distinguished Young Scholars (51425405) and National Natural Science Foundation of China (51378487).

摘要/Abstract

摘要： In this work, phenol and oxalic acid (OA) degradation in an ozone and photocatalysis integrated process was intensively conducted with Fe³⁺/TiO₂ catalyst. The ferrioxalate complex formed between Fe³⁺ and oxalate accelerated the removal of OA in the ozonation, photolysis and photocatalytic ozonation process, for its high reactivity with ozone and UV. Phenol was degraded in ozonation and photolysis with limited TOC removal rates, but much higher TOC removal was achieved in photocatalytic ozonation due to the generation of·OH. The sequence of UV light and ozone in the sequential process also influences the TOC removal, and ozone is very powerful to oxidize intermediates catechol and hydroquinone to maleic acid. Fenton or photo-Fenton reactions only played a small part in Fe³⁺/TiO₂ catalyzed processes, because Fe³⁺ was greatly reduced but not regenerated in many cases. The synergetic effect was found to be highly related with the property of the target pollutants. Fe³⁺/TiO₂ catalyzed system showed the highest ability to destroy organics, but the TiO₂ catalyzed system showed little higher synergy.

关键词: Catalysis, Environment, Waste water, Fe³⁺/TiO₂, Synergistic effect, Photocatalytic ozonation

Abstract: In this work, phenol and oxalic acid (OA) degradation in an ozone and photocatalysis integrated process was intensively conducted with Fe³⁺/TiO₂ catalyst. The ferrioxalate complex formed between Fe³⁺ and oxalate accelerated the removal of OA in the ozonation, photolysis and photocatalytic ozonation process, for its high reactivity with ozone and UV. Phenol was degraded in ozonation and photolysis with limited TOC removal rates, but much higher TOC removal was achieved in photocatalytic ozonation due to the generation of·OH. The sequence of UV light and ozone in the sequential process also influences the TOC removal, and ozone is very powerful to oxidize intermediates catechol and hydroquinone to maleic acid. Fenton or photo-Fenton reactions only played a small part in Fe³⁺/TiO₂ catalyzed processes, because Fe³⁺ was greatly reduced but not regenerated in many cases. The synergetic effect was found to be highly related with the property of the target pollutants. Fe³⁺/TiO₂ catalyzed system showed the highest ability to destroy organics, but the TiO₂ catalyzed system showed little higher synergy.

Key words: Catalysis, Environment, Waste water, Fe³⁺/TiO₂, Synergistic effect, Photocatalytic ozonation

Yongbing Xie, Yingying Chen, Jin Yang, Chenming Liu, He Zhao, Hongbin Cao. Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst[J]. Chinese Journal of Chemical Engineering, 2018, 26(7): 1528-1535.

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Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst

Distinct synergetic effects in the ozone enhanced photocatalytic degradation of phenol and oxalic acid with Fe³⁺/TiO₂ catalyst

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