Magnetic Fe3O4 nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange

doi:10.1016/j.cjche.2024.09.029

中国化学工程学报 ›› 2025, Vol. 77 ›› Issue (1): 144-155.DOI: 10.1016/j.cjche.2024.09.029

Magnetic Fe₃O₄ nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange

Chen Chen, Zeming Yan, Zhuoli Ma, Dianjie Ma, Shijun Xing, Wenping Li, Jiazhi Yang, Qiaofeng Han

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

收稿日期:2024-05-23 修回日期:2024-09-05 接受日期:2024-09-14 出版日期:2025-01-28 发布日期:2024-11-15
通讯作者: Wenping Li,E-mail:lwp@njust.edu.cn;Jiazhi Yang,E-mail:jiazhiyang@njust.edu.cn
基金资助:
This research was financially supported by the National Natural Science Foundation of China (51572124), Natural Science Foundation of China Jiangsu Province (BK20230940), the Fundamental Research Funds for the Central Universities (30920130121001), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD, China), and a project funded by Jiangsu Funding Program for Excellent Postdoctoral Talent.

Magnetic Fe₃O₄ nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange

Chen Chen, Zeming Yan, Zhuoli Ma, Dianjie Ma, Shijun Xing, Wenping Li, Jiazhi Yang, Qiaofeng Han

School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received:2024-05-23 Revised:2024-09-05 Accepted:2024-09-14 Online:2025-01-28 Published:2024-11-15
Contact: Wenping Li,E-mail:lwp@njust.edu.cn;Jiazhi Yang,E-mail:jiazhiyang@njust.edu.cn
Supported by:
This research was financially supported by the National Natural Science Foundation of China (51572124), Natural Science Foundation of China Jiangsu Province (BK20230940), the Fundamental Research Funds for the Central Universities (30920130121001), a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD, China), and a project funded by Jiangsu Funding Program for Excellent Postdoctoral Talent.

摘要/Abstract

摘要： The pollution especially organic dyes pollution of water resources is an urgent issue to be solved. It is crucial to develop highly efficient, low cost and recyclable heterogeneous catalysts for wastewater treatment. In this study, a heterogeneous Fenton catalyst loaded with Fe₃O₄ nanoparticles was prepared by one step pyrolysis using natural crop waste corncob as carbon source. The prepared porous carbon catalyst can effectively degrade methyl orange (MO, 25 mg·L^-1) at room temperature, and the degradation rate is 99.7%. In addition to high catalytic degradation activity, the layered porous carbon structure of the catalyst also provides high stability and reusability. The degradation rate can be maintained above 93% after 10 cycles. Furthermore, the prepared catalyst is magnetic, which makes the catalyst easy to recycle in practical applications. In addition, the prepared Fe₃O₄/RCC catalyst has efficient Fenton degradation activity for bisphenol A (BPA) (96.9%) and antibiotic tetracycline hydrochloride (TC-HCl) (95.5%), which proves that it has universal applicability for the degradation of most organic pollutants. This study provides a feasible and scalable strategy to prepare a heterogeneous Fenton catalyst treating wastewater and high-value utilization of biomass waste.

关键词: Water treatment, Organic dyes, Fe₃O₄ nanoparticles, Heterogeneous Fenton catalyst, Corncob, Porous carbon

Abstract: The pollution especially organic dyes pollution of water resources is an urgent issue to be solved. It is crucial to develop highly efficient, low cost and recyclable heterogeneous catalysts for wastewater treatment. In this study, a heterogeneous Fenton catalyst loaded with Fe₃O₄ nanoparticles was prepared by one step pyrolysis using natural crop waste corncob as carbon source. The prepared porous carbon catalyst can effectively degrade methyl orange (MO, 25 mg·L^-1) at room temperature, and the degradation rate is 99.7%. In addition to high catalytic degradation activity, the layered porous carbon structure of the catalyst also provides high stability and reusability. The degradation rate can be maintained above 93% after 10 cycles. Furthermore, the prepared catalyst is magnetic, which makes the catalyst easy to recycle in practical applications. In addition, the prepared Fe₃O₄/RCC catalyst has efficient Fenton degradation activity for bisphenol A (BPA) (96.9%) and antibiotic tetracycline hydrochloride (TC-HCl) (95.5%), which proves that it has universal applicability for the degradation of most organic pollutants. This study provides a feasible and scalable strategy to prepare a heterogeneous Fenton catalyst treating wastewater and high-value utilization of biomass waste.

Key words: Water treatment, Organic dyes, Fe₃O₄ nanoparticles, Heterogeneous Fenton catalyst, Corncob, Porous carbon

Chen Chen, Zeming Yan, Zhuoli Ma, Dianjie Ma, Shijun Xing, Wenping Li, Jiazhi Yang, Qiaofeng Han. Magnetic Fe₃O₄ nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange[J]. 中国化学工程学报, 2025, 77(1): 144-155.

参考文献

[1] P. Kar, D. Aggarwal, K. Shukla, R.K. Gupta, Defect state modulation of TiO₂ nanostructures for photocatalytic abatement of emerging pharmaceutical pollutant in wastewater effluent, Adv. Energy Sustain. Res. 3(5) (2022) 2100162.
[2] Y.R. Zhang, H.Y. Zhang, R.P. Deng, Y.K. Cheng, Y.H. Wu, J.L. Zhang, Zn₂SnO₄/SnO₂/g-C₃N₄ heterojunction: High efficiency photocatalytic degradation of rhodamine B in simulated visible light, Chem. Eng. Sci. 285(2024) 119551.
[3] X.Y. Xue, R. Cheng, L. Shi, Z. Ma, X. Zheng, Nanomaterials for water pollution monitoring and remediation, Environ. Chem. Lett. 15(1) (2017) 23-27.
[4] A. Baraka, M. Sheashea, K. Gado, O. Abuzalat, Cerium-phthalate coordination polymer as Fenton-like durable catalyst for hydrogen peroxide activation and anionic organic dyes degradation in wastewater, Mater. Sci. Eng. B 297(2023) 116801.
[5] E.M. Abd El-Monaem, M. Hosny, A.S. Eltaweil, Synergistic effect between adsorption and Fenton-like degradation on CoNiFe-LDH/ZIF-8 composite for efficient degradation of doxycycline, Chem. Eng. Sci. 287(2024) 119707.
[6] Y.H. Wei, Q.P. Zhu, W.W. Xie, X.Y. Wang, S. Li, Z.M. Chen, Biocatalytic enhancement of laccase immobilized on ZnFe₂O₄ nanoparticles and its application for degradation of textile dyes, Chin. J. Chem. Eng. 68(2024) 216-223.
[7] A. Boutemedjet, S. Djerad, L. Tifouti, K. Bachari, Effect of Fe⁰ content on the effectiveness of Fe⁰/Fe₃O₄ catalyst in Fenton process, J. Water Process. Eng. 41(2021) 102079.
[8] U.A.A. Yasin, Zhixin Jia, Ziwen Qin, Tianyu Guo, Ruihua Zhao, Jianping Du, Synergistic effect of CuO coupled with MoS₂ for enhanced photodegradation of organic dyes under visible light, Chinese Journal of Chemical Engineering 64(2023) 96-105.
[9] A. Saravanan, P. Senthil Kumar, S. Jeevanantham, S. Karishma, B. Tajsabreen, P.R. Yaashikaa, B. Reshma, Effective water/wastewater treatment methodologies for toxic pollutants removal: Processes and applications towards sustainable development, Chemosphere 280(2021) 130595.
[10] G. Divyapriya, P.V. Nidheesh, Importance of graphene in the electro-Fenton process, ACS Omega 5(10) (2020) 4725-4732.
[11] Jun Chen, Xiaosu Wang, Yan Huang, Shanshan Lv, Xiaohua Cao, Jimmy Yun, Dapeng Cao, Adsorption removal of pollutant dyes in wastewater by nitrogen-doped porous carbons derived from natural leaves, Engineered Science 5(2019) 30-38.
[12] Y. Zhu, W.H. Fan, W.Y. Feng, Y. Wang, S. Liu, Z.M. Dong, X.M. Li, A critical review on metal complexes removal from water using methods based on Fenton-like reactions: Analysis and comparison of methods and mechanisms, J. Hazard. Mater. 414(2021) 125517.
[13] J.T. Lee, M.C. Lin, J.M. Wu, High-efficiency cycling piezo-degradation of organic pollutants over three liters using MoS₂/carbon fiber piezocatalytic filter, Nano Energy 98(2022) 107280.
[14] X.K. Jia, X. Chen, Y. Liu, B.L. Zhang, H.P. Zhang, Q.Y. Zhang, Hydrophilic Fe₃O₄ nanoparticles prepared by ferrocene as high-efficiency heterogeneous Fenton catalyst for the degradation of methyl orange, Appl. Organomet. Chem. 33(4) (2019) e4826.
[15] G. Crini, E. Lichtfouse, Advantages and disadvantages of techniques used for wastewater treatment, Environ. Chem. Lett. 17(1) (2019) 145-155.
[16] R. Li, K. Zhang, X. Yang, R. Xiao, Y. Xie, X.H. Tang, G. Miao, J. Fan, W.G. Zhang, S.R. Zheng, S.L. Cai, Construction of a carboxyl-functionalized clover-like covalent organic framework for selective adsorption of organic dyes, Sep. Purif. Technol. 340(2024) 126765.
[17] L. Giorno, Membranes that filter and destroy pollutants, Nat. Nanotechnol. 17(4) (2022) 334-335.
[18] Q.N. Ho, M. Fettweis, K.L. Spencer, B.J. Lee, Flocculation with heterogeneous composition in water environments: A review, Water Res. 213(2022) 118147.
[19] J.Y. Kang, X.B. Zhao, Y.P. Shi, Azophenyl calix
[4]arene porous organic polymer for extraction and analysis of triphenylmethane dyes from seafood, ACS Appl. Mater. Interfaces 15(36) (2023) 42981-42991.
[20] Y. Zhuang, S.Y. Yuan, J.M. Liu, Y. Zhang, H. Du, C.D. Wu, P. Zhao, H.Y. Chen, Y.P. Pei, Synergistic effect and mechanism of mass transfer and catalytic oxidation of octane degradation in yolk-shell Fe₃O₄@C/Fenton system, Chem. Eng. J. 379(2020) 122262.
[21] A. Sarswat, D. Mohan, Sustainable development of coconut shell activated carbon (CSAC) & a magnetic coconut shell activated carbon (MCSAC) for phenol (2-nitrophenol) removal, RSC Adv. 6(88) (2016) 85390-85410.
[22] K. Shapira, I. Zucker, Emerging investigator series: Molybdenum disulfide-enabled activated carbon - a multifunctional adsorbent for practical water treatment applications, Environ. Sci.: Nano 9(2) (2022) 477-488.
[23] K. Kumar Yadav, N. Gupta, A. Kumar, L.M. Reece, N. Singh, S. Rezania, S. Ahmad Khan, Mechanistic understanding and holistic approach of phytoremediation: A review on application and future prospects, Ecol. Eng. 120(2018) 274-298.
[24] V.I. Parvulescu, F. Epron, H. Garcia, P. Granger, Recent progress and prospects in catalytic water treatment, Chem. Rev. 122(3) (2022) 2981-3121.
[25] Y.C. Liu, G.M. Zhang, S. Chong, N. Zhang, H.Z. Chang, T. Huang, S.Y. Fang, NiFe(C₂O₄)_x as a heterogeneous Fenton catalyst for removal of methyl orange, J. Environ. Manage. 192(2017) 150-155.
[26] L.V. Samarasinghe, S. Muthukumaran, K. Baskaran, Recent advances in visible light-activated photocatalysts for degradation of dyes: A comprehensive review, Chemosphere 349(2024) 140818.
[27] S.Q. Zhang, Y. Wei, J. Metz, S.B. He, P.J.J. Alvarez, M.C. Long, Persistent free radicals in biochar enhance superoxide-mediated Fe(III)/Fe(II) cycling and the efficacy of CaO₂ Fenton-like treatment, J. Hazard. Mater. 421(2022) 126805.
[28] V.S. Kore, S.D. Manjare, S.V. Taralkar, Intensified degradation of reactive blue 222(RB222) textile dye by a hybrid AOP system of hydrodynamic cavitation coupled with inline UV and PMS oxidant, J. Water Process. Eng. 56(2023) 104472.
[29] Z.L. Pan, X.F. Qian, Porous carbons for use in electro-Fenton and Fenton-like reactions, New Carbon Mater. 37(1) (2022) 180-195.
[30] Y.Y. Feng, Y.Q. Chen, Z. Wang, J. Wei, Synthesis of mesoporous carbon materials from renewable plant polyphenols for environmental and energy applications, New Carbon Mater. 37(1) (2022) 196-222.
[31] Y.H. Song, J. Wei, Y.C. Ma, P. Zeng, M.H. Kong, Removal and recovery of amantadine from water by liquid-liquid extraction, Environ. Earth Sci. 73(9) (2015) 4931-4938.
[32] Jinghua Li, En Li, Shuang Zhang, Dongmei Yu, Jianping Wang, Pengshan Guo, Hongbo Sun, Hexagonal Cu₂O-Pt alloyed nano-lilies mediated Fenton catalysis for recyclable degradation of organic dye, Journal of Water Process Engineering 61(2024) 105364.
[33] Y.P. Zhu, R.L. Zhu, Y.F. Xi, J.X. Zhu, G.Q. Zhu, H.P. He, Strategies for enhancing the heterogeneous Fenton catalytic reactivity: A review, Appl. Catal. B Environ. 255(2019) 117739.
[34] H. Zhou, M. Li, L.Q. Chen, H.P. Cheng, D. Li, C.X. Tang, J.R. Yuan, F.G. Xu, Degradation of TCH by Fe₃O₄/B₄C catalyzed heterogeneous Fenton oxidation, J. Alloys Compd. 995(2024) 174787.
[35] W.S. Wang, H.Y. Xu, B. Li, L.Y. Dai, S.Q. Zhang, Y. Xu, S.Y. Qi, Preparation, catalytic efficiency and mechanism of Fe₃O₄/HNTs heterogeneous Fenton-like catalyst, Mater. Today Commun. 36(2023) 106821.
[36] C.Y. Hu, J.K. He, J.J. Liang, T. Lin, Q.L. Liu, Heterogeneous photo-Fenton catalyst α-Fe₂O₃@g-C₃N₄@NH₂-MIL-101(Fe) with dual Z-Scheme heterojunction for degradation of tetracycline, Environ. Res. 231(Pt 3) (2023) 116313.
[37] J.J. Li, J.H. You, Z.W. Wang, Y. Zhao, J.S. Xu, X.H. Li, H.Z. Zhang, Application of α-Fe₂O₃-based heterogeneous photo-Fenton catalyst in wastewater treatment: A review of recent advances, J. Environ. Chem. Eng. 10(5) (2022) 108329.
[38] Z.Y. Jia, Y.M. Yang, C.W. Yang, D. Wang, Magnetic γ-Fe₂O₃/ZnO@CNTs synthesized by a green precipitation method for the degradation of aniline through photocatalysis coupling catalytic ozonation, Appl. Surf. Sci. 659(2024) 159866.
[39] F. Liu, H.H. Zhang, N. Liu, J.X. Wang, M.L. Chen, F.Y. Qian, Enhanced removal of refractory organic pollutants in wafer surface treatment wastewater by combining Fenton oxidation and O₃/H₂O₂/FeOOH: Removal efficiency, intermediate composition, and toxicity prediction, J. Water Process. Eng. 64(2024) 105572.
[40] W. Li, Q.Q. Zhu, X. Yin, Z.F. Gao, K.J. Wei, S.Q. Liu, X.Y. Zhang, H.M. Chen, Y.H. Zhang, W.Q. Han, Enhanced heterogeneous Fenton catalysis by carbon nanotube-loaded Mn doped FeS₂ catalysts for pollutant degradation: Co-enhancement effect of Fe-S-Mn and Fe-S-C linkages, Sep. Purif. Technol. 335(2024) 126150.
[41] N.T.T. Van, A.N. Phan, V.C. Cuong, N.T.T. Van, H.G.T. Thanh, N.Q. Khai, N. Tri, T.T. Nguyen, X.T. Bui, K.P.H. Huynh, Enhanced heterogeneous Fenton degradation of p-nitrophenol by Fe 3 O 4 nanoparticles decorated cellulose aerogel from banana stem, Environ. Technol. Innov. 30(2023) 103041.
[42] R.L. Zhu, Y.P. Zhu, H.Y. Xian, L.X. Yan, H.Y. Fu, G.Q. Zhu, Y.F. Xi, J.X. Zhu, H.P. He, CNTs/ferrihydrite as a highly efficient heterogeneous Fenton catalyst for the degradation of bisphenol A: The important role of CNTs in accelerating Fe(III)/Fe(II) cycling, Appl. Catal. B Environ. 270(2020) 118891.
[43] H.D. Mou, Q. Yang, S.B. Qu, X. Hu, Z.Y. Li, Y.F. Tsang, Degradation of dimethyl phthalate by heterogeneous electro-Fenton process using Fe₃O₄-doped biomass porous carbon, Water Air Soil Pollut. 235(1) (2023) 5.
[44] Guirong Ye, Jinghong Zhou, Renting Huang, Yingjun Ke, Yecan Peng, Yongxin Zhou, Yu Weng, Chutong Ling, Weixi Pan, Magnetic sludge-based biochar derived from Fenton sludge as an efficient heterogeneous Fenton catalyst for degrading methylene blue, Journal of Environmental Chemical Engineering 10(2022) 107242.
[45] Q. Yang, L.G. Chu, T.L. Wu, Y.Y. Zhou, C. Liu, L. Cang, G.D. Fang, P.X. Cui, Y.J. Wang, Investigation of dual-functional carbon cathode catalysts from agricultural wastes in the heterogeneous electro-Fenton process, Appl. Catal. B Environ. 337(2023) 123018.
[46] Z.L. Yin, J.W. Zhu, Z.R. Wang, Y.L. Liu, Z. Yang, W.B. Yang, Novel Fe/N co-doping biochar based electro-Fenton catalytic membrane enabling enhanced tetracycline removal and self-cleaning performance, J. Clean. Prod. 402(2023) 136731.
[47] F. Guo, Y.Y. Lou, Q. Yan, J.L. Xiong, J.H. Luo, C.K. Shen, D.V. Vayenas, Insight into the Fe-Ni/biochar composite supported three-dimensional electro-Fenton removal of electronic industry wastewater, J. Environ. Manag. 325(Pt B) (2023) 116466.
[48] W.W. Zheng, X.Y. Liu, Y.P. Liu, Q. Ma, Y. Li, S.H. Zhan, Self-regulation of electron density in metal centers for ionic liquid Co-doped biochar catalysts in heterogeneous electro-Fenton-like process, Appl. Surf. Sci. 641(2023) 158479.
[49] Y. Lu, M.Q. Feng, Y.B. Wang, Enhancing the heterogeneous electro-Fenton degradation of methylene blue using sludge-derived biochar-loaded nano zero-valent iron, J. Water Process. Eng. 59(2024) 104980.
[50] D. Venu, B.J. Alappat, Synthesis of iron loaded jackfruit peel biochar through microwave heating as a stable and active heterogenous Fenton catalyst for dye degradation, Diam. Relat. Mater. 148(2024) 111452.
[51] W.J. Chen, Y.S. Ai, H.M. He, Y.L. He, L.L. Lei, J. Huang, A universal synthesis strategy for facile and scalable of magnetic biochar composite materials for PMS activation: Catalytic mechanisms, J. Alloys Compd. 991(2024) 174313.
[52] Z. Sun, Y.X. Zhang, S.T. Guo, J.M. Shi, C. Shi, K.Q. Qu, H.J. Qi, Z.H. Huang, V. Murugadoss, M.N. Huang, Z.H. Guo, Confining FeNi nanoparticles in biomass-derived carbon for effectively photo-Fenton catalytic reaction for polluted water treatment, Adv. Compos. Hybrid Mater. 5(2) (2022) 1566-1581.
[53] J.H. Park, J.J. Wang, D.C. Seo, Comparison of catalytic activity for treating recalcitrant organic pollutant in heterogeneous Fenton oxidation with iron-impregnated biochar and activated carbon, J. Water Process. Eng. 42(2021) 102141.
[54] J.L. Zhu, M. Zhu, J.J. Peng, Fenton-like degradation of bisphenol A by Fe₃O₄ rhombic dodecahedrons, New J. Chem. 47(22) (2023) 10857-10865.
[55] G.Y. Tian, K.L. Nie, G.F. Han, X. Hua, K.F. Zhang, S.Y. Dang, B.X. Yao, J.P. Meng, Iron ore tailings as efficient Fenton-like catalysts for degradation of tetracycline, Mater. Today Commun. 37(2023) 107598.
[56] Z. Sun, X.L. Wu, K.Q. Qu, Z.H. Huang, S.X. Liu, M.Y. Dong, Z.H. Guo, Bimetallic metal-organic frameworks anchored corncob-derived porous carbon photocatalysts for synergistic degradation of organic pollutants, Chemosphere 259(2020) 127389.
[57] S.L. Zhang, Q.Z. Jiao, C.X. Wang, H. Yu, Y. Zhao, H.S. Li, Q. Wu, In situ synthesis of Mg/Fe LDO/carbon nanohelix composites as absorbing materials, J. Alloys Compd. 658(2016) 505-512.
[58] M.X. Li, H.B. Liu, T.H. Chen, C. Dong, Y.B. Sun, Synthesis of magnetic biochar composites for enhanced uranium(VI) adsorption, Sci. Total Environ. 651(Pt 1) (2019) 1020-1028.
[59] Buttersack C, Modeling of type II high-resolution sorption isotherms: Evaluation of different approaches, Colloids and Surfaces A: Physicochemical and Engineering Aspects 650(2022) 129489.
[60] J.L. Yang, Q. Zhang, F. Zhang, D.H. Xia, H.D. Liu, S.H. Tian, L.P. Sun, D. Shu, C. He, S. Runa, Three-dimensional hierarchical porous sludge-derived carbon supported on silicon carbide foams as effective and stable Fenton-like catalyst for odorous methyl mercaptan elimination, J. Hazard. Mater. 358(2018) 136-144.
[61] Y. Xiao, J.M. Hill, Impact of pore size on Fenton oxidation of methyl orange adsorbed on magnetic carbon materials: Trade-off between capacity and regenerability, Environ. Sci. Technol. 51(8) (2017) 4567-4575.
[62] S.J. Salih, A.S. Abdul Kareem, S.S. Anwer, Adsorption of anionic dyes from textile wastewater utilizing raw corncob, Heliyon 8(8) (2022) e10092.
[63] Y. Wang, Y.W. Gao, L. Chen, H. Zhang, Goethite as an efficient heterogeneous Fenton catalyst for the degradation of methyl orange, Catal. Today 252(2015) 107-112.
[64] M. Li, J.Y. Song, W. Han, K.L. Yeung, S.Q. Zhou, C.H. Mo, Iron-organic frameworks as effective Fenton-like catalysts for peroxymonosulfate decomposition in advanced oxidation processes, NPJ Clean Water 6(2023) 37.
[65] X.Q. Yuan, H.Y. Xu, B. Li, L.Y. Dai, W.S. Wang, Y. Li, Fenton-like degradation of methyl orange over CeO₂ loaded on porous Al₂O₃: Catalyst preparation, efficiency and mechanism, J. Phys. Chem. Solids 178(2023) 111314.
[66] A.A. Taha, L.B. Huang, H.Y. Ma, S. Ramakrishna, Y. Liu, Metal-free nitrogen-doped porous carbon nanofiber catalyst for solar-Fenton-like system: Efficient, reusable and active catalyst over a wide range of pH, Colloids Surf. A Physicochem. Eng. Aspects 663(2023) 131021.
[67] B. Harikumar, M.K. Okla, I.A. Alaraidh, A. Mohebaldin, W. Soufan, M.A. Abdel-Maksoud, M. Aufy, A.M. Thomas, L.L. Raju, S.S. Khan, Robust visible light active CoNiO₂-BiFeO₃-NiS ternary nanocomposite for photo-Fenton degradation of rhodamine B and methyl orange: Kinetics, degradation pathway and toxicity assessment, J. Environ. Manage. 317(2022) 115321.
[68] G.F. Zhu, Y. Jin, M.Q. Ge, Simple and green method for preparing copper nanoparticles supported on carbonized cotton as a heterogeneous Fenton-like catalyst, Colloids Surf. A Physicochem. Eng. Aspects 647(2022) 128978.
[69] X. Xu, K. Jia, S.F. Chen, D.N. Lang, C. Yang, L. Wang, R.L. Wu, W. Wang, J.D. Wang, Ultra-fast degradation of phenolics and dyes by Cu₂O/Cu catalysts: Synthesis and degradation kinetics, J. Environ. Chem. Eng. 9(4) (2021) 105505.
[70] T. Zhang, X.J. Guo, H.B. Pei, F. Zha, X.H. Tang, H.F. Tian, R.B. Guo, N.J. Liu, Z.L. Mo, Design and synthesis of α-Fe₂O₃/MIL-53(Fe) composite as a photo-Fenton catalyst for efficient degradation of tetracycline hydrochloride, Colloids Surf. A Physicochem. Eng. Aspects 659(2023) 130822.

Magnetic Fe₃O₄ nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange

Magnetic Fe₃O₄ nanoparticles supported on carbonized corncob as heterogeneous Fenton catalyst for efficient degradation of methyl orange

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Honggui Han, Yaqian Zhao, Xiaolong Wu, Hongyan Yang. Multi-timescale feature extraction method of wastewater treatment process based on adaptive entropy[J]. 中国化学工程学报, 2024, 76(12): 264-271.
[2]	Sarra Hamidoud, Malek Bendjaballah, Imane Kouadri, Mohammed Rabeh Makhlouf. Multi-objective optimization of wastewater treatment using electrocoagulation[J]. 中国化学工程学报, 2024, 75(11): 152-160.
[3]	Abdellatif Aarfane, Meryem Bensemlali, Abderrahmane Elmelouky, Badreddine Hatimi, Soumia Zaim, Nicole Jaffrezic-Renault, Abdoullatif Baraket, Abdelhamid Errachid, Monkade Mohamed, Hamid Nasrellah. Electrocoagulation efficiency probed using electrochemical impedance spectroscopy[J]. 中国化学工程学报, 2024, 75(11): 266-273.
[4]	Ali Nikkhah, Hasan Nikkhah, Hadis langari, Alireza Nouri, Abdul Wahab Mohammad, Ang Wei Lun, Ng law Yong, Rosiah Rohani, Ebrahim Mahmoudi. MXene: From synthesis to environment remediation[J]. 中国化学工程学报, 2023, 61(9): 260-280.
[5]	Sufei Wang, Mengjie Hao, Danyang Xiao, Tianmiao Zhang, Hua Li, Zhongshan Chen. Synthesis of porous carbon nanomaterials and their application in tetracycline removal from aqueous solutions[J]. 中国化学工程学报, 2023, 59(7): 200-209.
[6]	Chaoyi Yin, Jingyuan Ma, Jian Qiu, Ruifang Liu, Long Ba. Mass-producible low-cost flexible electronic fabrics for azo dye wastewater treatment by electrocoagulation[J]. 中国化学工程学报, 2023, 59(7): 222-230.
[7]	Yujia Cui, Zhiqiang Tan, Yanan Wang, Shuxian Shi, Xiaonong Chen. One-step crosslinking preparation of tannic acid particles for the adsorption and separation of cationic dyes[J]. 中国化学工程学报, 2023, 57(5): 309-318.
[8]	Yuxi Chai, Yanan Zhang, Yannan Tan, Zhiwei Li, Huangzhao Wei, Chenglin Sun, Haibo Jin, Zhao Mu, Lei Ma. Life cycle assessment of high concentration organic wastewater treatment by catalytic wet air oxidation[J]. 中国化学工程学报, 2023, 56(4): 80-88.
[9]	Peipei Ai, Li Zhang, Jinchi Niu, Huiqing Jin, Wei Huang. Boron-doped lamellar porous carbon supported copper catalyst for dimethyl oxalate hydrogenation[J]. 中国化学工程学报, 2023, 55(3): 222-229.
[10]	Pengfei Liu, Wenqiao Du, Xiangjing Liu, Long Zhang, Zhimin Chen. Sustainable catalytic graphitization of biomass to graphitic porous carbon by constructing permeation network with organic ligands[J]. 中国化学工程学报, 2023, 64(12): 259-270.
[11]	Zhongwei Tan, Xingguo Xu, Yu Wan, Chengjun Kang, Zhaoqiang Zhang, Zhenxia Zhao, Fang Shen, Kungang Chai, Hongbing Ji. Efficient recovery of aromatic compounds from the wastewater of styrene monomer and propylene oxide co-production plant via hypercrosslinked aryl-rich starch-β-cyclodextrin polymeric sorbent[J]. 中国化学工程学报, 2022, 49(9): 150-160.
[12]	Zhengguo Xu, Xiaochong Wang, Shuying Sun. Performance of a synthetic resin for lithium adsorption in waste liquid of extracting aluminum from fly-ash[J]. 中国化学工程学报, 2022, 44(4): 115-123.
[13]	Haofeng Wu, Yanhong Chao, Yan Jin, Duanjian Tao, Xiaowei Li, Jing Luo, Guohua Xia, Linhua Zhu, Wenshuai Zhu. Sustainable preparation of graphene-analogue boron nitride by ball-milling for adsorption of organic pollutants[J]. 中国化学工程学报, 2022, 42(2): 73-81.
[14]	Shuang Xu, Ru-Shuai Liu, Meng-Yao Zhang, An-Hui Lu. Designed synthesis of porous carbons for the separation of light hydrocarbons[J]. 中国化学工程学报, 2022, 42(2): 130-150.
[15]	Jiahao Wei, Fan Li, Lina Zhou, Dandan Han, Junbo Gong. Strategies for enhancing peroxymonosulfate activation by heterogenous metal-based catalysis: A review[J]. 中国化学工程学报, 2022, 50(10): 12-28.