Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles

›› 2012, Vol. 20 ›› Issue (3): 505-514.

• 香港科技大学化学与生物分子工程系戈登·麦凯教授退休纪念专刊 • 上一篇下一篇

Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles

T. Tuutijärvi¹, E. Repo², R. Vahala¹, M. Sillanp^1,2,3, G. Chen⁴

1. Department of Civil and Environmental Engineering, School of Science and Technology, Aalto University, P.O.Box 15200, FI-00076 Aalto, Finland;
2. Laboratory of Green Chemistry, Faculty of Technology, Lappeenranta University of Technology, Patteristonkatu 1, FI-50100 Mikkeli, Finland;
3. Laboratory of Applied Environmental Chemistry, Department of Environmental Sciences, University of Eastern Finland, Patteristonkatu 1, FI-50100 Mikkeli, Finland;
4. Department of Chemical and Biomolecular Engineering, the Hong Kong University of Science and Technology, Hong Kong, China

收稿日期:2012-02-17 修回日期:2012-03-23 出版日期:2012-06-28 发布日期:2012-08-17
通讯作者: T. Tuutijrvi, E-mail: tanja.tuutijarvi@aalto.fi

Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles

T. Tuutijärvi¹, E. Repo², R. Vahala¹, M. Sillanp^1,2,3, G. Chen⁴

1. Department of Civil and Environmental Engineering, School of Science and Technology, Aalto University, P.O.Box 15200, FI-00076 Aalto, Finland;
2. Laboratory of Green Chemistry, Faculty of Technology, Lappeenranta University of Technology, Patteristonkatu 1, FI-50100 Mikkeli, Finland;
3. Laboratory of Applied Environmental Chemistry, Department of Environmental Sciences, University of Eastern Finland, Patteristonkatu 1, FI-50100 Mikkeli, Finland;
4. Department of Chemical and Biomolecular Engineering, the Hong Kong University of Science and Technology, Hong Kong, China

Received:2012-02-17 Revised:2012-03-23 Online:2012-06-28 Published:2012-08-17

摘要/Abstract

摘要： This paper reports the effect of several competing anions on arsenate adsorption with maghemite nanoparticles.Sulphate(as SO₄),nitrate(as NO₃-N),phosphate(as PO₄-P) ions and silicate(as SiO₂) were studied in dual solution with arsenate.Moreover,the combined effect of ions and other water characteristics were examined with a natural groundwater sample which was spiked with a certain amount of arsenate.Arsenate batch adsorption experiments were carried out with two different kinds of maghemite—a commercially available one and a homemade one using the sol-gel process.Sulphate(≤250 mg·L^-1) and nitrate(≤12 mg·L^-1) had a negligible effect on the arsenate(0.5 mg·L^-1) adsorption at pH 3.However,both phosphate(≤2.9 mg·L^-1) and silicate(≤50 mg·L^-1) had an adverse impact on arsenate(≤3 mg·L^-1) adsorption at pH 7.Phosphate(≤1.5 mg·L^-1) showed minimal competition with arsenate(0.5 mg·L^-1),while silicate(≤10 mg·L^-1) inhibition was insignificant for all studied As(V) concentrations at pH 3.The removal of arsenate from the groundwater sample was as efficient as from laboratory water for 0.5 mg·L^-1 As(V) both at pH 3 and pH 7.

关键词: anion effect, groundwater, nitrate, phosphate, silicate, water treatment

Abstract: This paper reports the effect of several competing anions on arsenate adsorption with maghemite nanoparticles.Sulphate(as SO₄),nitrate(as NO₃-N),phosphate(as PO₄-P) ions and silicate(as SiO₂) were studied in dual solution with arsenate.Moreover,the combined effect of ions and other water characteristics were examined with a natural groundwater sample which was spiked with a certain amount of arsenate.Arsenate batch adsorption experiments were carried out with two different kinds of maghemite—a commercially available one and a homemade one using the sol-gel process.Sulphate(≤250 mg·L^-1) and nitrate(≤12 mg·L^-1) had a negligible effect on the arsenate(0.5 mg·L^-1) adsorption at pH 3.However,both phosphate(≤2.9 mg·L^-1) and silicate(≤50 mg·L^-1) had an adverse impact on arsenate(≤3 mg·L^-1) adsorption at pH 7.Phosphate(≤1.5 mg·L^-1) showed minimal competition with arsenate(0.5 mg·L^-1),while silicate(≤10 mg·L^-1) inhibition was insignificant for all studied As(V) concentrations at pH 3.The removal of arsenate from the groundwater sample was as efficient as from laboratory water for 0.5 mg·L^-1 As(V) both at pH 3 and pH 7.

Key words: anion effect, groundwater, nitrate, phosphate, silicate, water treatment

T. Tuutijärvi, E. Repo, R. Vahala, M. Sillanp, G. Chen. Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles[J]. , 2012, 20(3): 505-514.

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Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles

Effect of Competing Anions on Arsenate Adsorption onto Maghemite Nanoparticles

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