Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

doi:10.1016/S1004-9541(13)60640-0

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (12): 1370-1375.DOI: 10.1016/S1004-9541(13)60640-0

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

马征¹, 董晓霞¹, 胡玉峰², 张柏松¹, 徐长英¹, 刘艳升²

1 Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute, Shandong Academy of Agricultural Science, Jinan 250100, China;
2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

收稿日期:2012-03-08 修回日期:2012-11-04 出版日期:2013-12-28 发布日期:2013-12-27
通讯作者: LIU Yansheng
基金资助:
Supported by the National Natural Science Foundation of China (21176248).

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

MA Zheng¹, DONG Xiaoxia¹, Hu Yufeng², ZHANG Bosong¹, XU Changying¹, LIU Yansheng²

1 Shandong Province Key laboratory of Plant Nutrition and Fertilizer, Agriculture Resources and Environment Institute, Shandong Academy of Agricultural Science, Jinan 250100, China;
2 State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, China

Received:2012-03-08 Revised:2012-11-04 Online:2013-12-28 Published:2013-12-27
Contact: LIU Yansheng
Supported by:
Supported by the National Natural Science Foundation of China (21176248).

摘要/Abstract

摘要： It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

关键词: ionic liquid, activity coefficients at infinite dilution, organic reactions

Abstract: It is important to know how ILs (ionic liquids) influence organic reaction. In this paper, activity coefficients at infinite dilution of more than 80 organic compounds in ILs are collected and analyzed systematically. Through the study on typical organic reactions happened in ILs, such as Diels-Alder, esterification and Friedel-Crafts reaction, the ratio of activity coefficients at infinite dilution of products and reactants is employed to estimate different effects of different structural ILs on the rate and selectivity of reactions.

Key words: ionic liquid, activity coefficients at infinite dilution, organic reactions

马征, 董晓霞, 胡玉峰, 张柏松, 徐长英, 刘艳升. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chinese Journal of Chemical Engineering, 2013, 21(12): 1370-1375.

MA Zheng, DONG Xiaoxia, Hu Yufeng, ZHANG Bosong, XU Changying, LIU Yansheng. Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution[J]. Chin.J.Chem.Eng., 2013, 21(12): 1370-1375.

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Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

Effect of Ionic Liquids on Organic Reactions Based on Activity Coefficients at Infinite Dilution

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