A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature

doi:10.1016/j.cjche.2014.09.055

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (6): 1060-1063.DOI: 10.1016/j.cjche.2014.09.055

• 研究简报 • 上一篇

A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature

Zhao Wang, Yu Zhu

State Key Laboratory of Chemical Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300072, China

收稿日期:2014-05-05 修回日期:2014-09-04 出版日期:2015-06-28 发布日期:2015-07-09
通讯作者: Zhao Wang
基金资助:
Supported by the National Natural Science Foundation of China (21206109) and the Tianjin Municipal Natural Science Foundation (12JCQNJC04500).

A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature

Zhao Wang, Yu Zhu

State Key Laboratory of Chemical Engineering, School of Chemical Engineering, Tianjin University, Tianjin 300072, China

Received:2014-05-05 Revised:2014-09-04 Online:2015-06-28 Published:2015-07-09
Contact: Zhao Wang
Supported by:
Supported by the National Natural Science Foundation of China (21206109) and the Tianjin Municipal Natural Science Foundation (12JCQNJC04500).

摘要/Abstract

摘要： A simple and fast plasma reduction method is developed for synthesis of Au and Pd metal nanoparticles. The scanning electron microscopy (SEM) analysis indicates a formation of aggregates of Au and Pd nanoparticles with branched structure. The transmission electron microscopy (TEM) image shows that the inclusive nanoparticles are all about 5 nm in size. Compared to conventional hydrogen reduction method, plasmamethod inhibits the agglomeration of metal particles. The room temperature operation is very helpful to limit the nanoparticle size. Most interestingly, plasma reduction produces more flattened metal particles. This plasma reduction does not require the use of any hazardous reducing chemicals, showing the great potential for the fabrication of noble metal nanoparticles.

关键词: Glow discharge plasma, Nanoparticles, Gold, Palladium, Reduction, Preparation

Abstract: A simple and fast plasma reduction method is developed for synthesis of Au and Pd metal nanoparticles. The scanning electron microscopy (SEM) analysis indicates a formation of aggregates of Au and Pd nanoparticles with branched structure. The transmission electron microscopy (TEM) image shows that the inclusive nanoparticles are all about 5 nm in size. Compared to conventional hydrogen reduction method, plasmamethod inhibits the agglomeration of metal particles. The room temperature operation is very helpful to limit the nanoparticle size. Most interestingly, plasma reduction produces more flattened metal particles. This plasma reduction does not require the use of any hazardous reducing chemicals, showing the great potential for the fabrication of noble metal nanoparticles.

Key words: Glow discharge plasma, Nanoparticles, Gold, Palladium, Reduction, Preparation

Zhao Wang, Yu Zhu. A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature[J]. Chinese Journal of Chemical Engineering, 2015, 23(6): 1060-1063.

Zhao Wang, Yu Zhu. A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature[J]. Chin.J.Chem.Eng., 2015, 23(6): 1060-1063.

参考文献

[1] J.A. Dahl, B.L.S. Maddux, J.E. Hutchison, Toward green nanosynthesis, Chem. Rev. 107 (2007) 2228-2269.

[2] F.F. Lu, Y.X. Gao, J.L. Huang, D.H. Sun, Q.B. Li, Roles of biomolecules in the biosynthesis of silver nanoparticles: Case of Gardenia jasminoides extract, Chin. J. Chem. Eng. 22 (6) (2014) 706-712.

[3] C. Bandas, C. Orha, C. Misca, C. Lazau, P. Sforloaga, S. Olariu, Photocatalytical inactivation of Enterococcus faecalis from water using functional materials based on natural zeolite and titanium dioxide, Chin. J. Chem. Eng. 22 (1) (2014) 38-43.

[4] P. Alexandridis, Gold nanoparticle synthesis, morphology control, and stabilization facilitated by functional polymers, Chem. Eng. Technol. 34 (2011) 15-28.

[5] L. Xiao, B. Tollberg, X.K. Hu, L.C.Wang, Structural study of gold clusters, J. Chem. Phys. 124 (2006) 114309-114318.

[6] C.T. Campbell, The active site in nanoparticle gold catalysis, Science 306 (2004) 234-235.

[7] T.Y. Xu, Q.F. Zhang, H.F. Yang, X.N. Li, J.G. Wang, Role of phenolic groups in the stabilization of palladium nanoparticles, Ind. Eng. Chem. Res. 52 (2013) 9783-9789.

[8] G.W. Zhang, L.T. Ke, Q.B. Li, J.L. Huang, D. Hua, A.R. Ibrahim, D.H. Sun, Synthesis of gold nanoplates with bioreducing agent using syringe pumps: a kinetic control, Ind. Eng. Chem. Res. 51 (2012) 15753-15762.

[9] O. Hoefft, F. Endres, Plasma electrochemistry in ionic liquids: An alternative route to generate nanoparticles, Phys. Chem. Chem. Phys. 13 (2011) 13472-13478.

[10] R.G. Nikov, A.S. Nikolov, N.N. Nedyalkov, I.G. Dimitrov, P.A. Atanasov, M.T. Alexandrov, Stability of contamination-free gold and silver nanoparticles produced by nanosecond laser ablation of solid targets in water, Appl. Surf. Sci. 258 (2012) 9318-9322.

[11] C.R. Adhikari, D. Parajuli, H. Kawakita, R. Chand, K. Inoue, K. Ohto, Recovery and separation of precious metals using waste paper, Chem. Lett. 36 (2007) 1254-1255.

[12] P. Raveendran, J. Fu, S.L. Wallen, A simple and “green” method for the synthesis of Au, Ag, and Au-Ag alloy nanoparticles, Green Chem. 8 (2006) 34-38.

[13] M. Zhou, S.H. Chen, S.Y. Zhao, Preparation of branched gold nanocrystals by an electrochemical method, Chem. Lett. 35 (2006) 332-333.

[14] S.C. Chan,M.A. Barteau, Preparation of highly uniformAg/TiO₂ and Au/TiO₂ supported nanoparticle catalysts by photodeposition, Langmuir 21 (2005) 5588-5595.

[15] H.L. Zhang, Y.Y. Yang,W. Dai, S.L. Lu, H.B. Yu, Y.Y. Ji, Size-controlled Pd nanoparticles supported on alpha-Al₂O₃ as heterogeneous catalyst for selective hydrogenation of acetylene, Chin. J. Chem. Eng. 22 (5) (2014) 516-521.

[16] Z.C. Sun, X. Li, A.J. Wang, Y. Wang, Y.Y. Chen, Y.K. Hu, XAS study of Ni₂P/MCM-41 prepared by hydrogen plasma reduction, Catal. Today 211 (2013) 126-130.

[17] X.L. Zhu, P.P. Huo, Y.P. Zhang, D.G. Cheng, C.J. Liu, Characterization of argon glowdischarge plasma reduced Pt/Al₂O₃ catalyst, Ind. Eng. Chem. Res. 45 (2006) 8604-8609.

[18] C.M. Zhou, H. Chen, Y.B. Yan, X.L. Jia, C.J. Liu, Y.H. Yan, Argon plasma reduced Pt nanocatalysts supported on carbon nanotube for aqueous phase benzyl alcohol oxidation, Catal. Today 211 (2013) 104-108.

[19] J.J. Zou, Y.P. Zhang, C.J. Liu, Reduction of supported noble-metal ions using glow discharge plasma, Langmuir 22 (2006) 11388-11394.

[20] X. Liang, C.J. Liu, P.Y. Kuai, Selective oxidation of glucose to gluconic acid over argon plasma reduced Pd/Al₂O₃, Green Chem. 10 (2008) 1318-1322.

[21] Y.B. Xie, Z.H.Wei, C.J. Liu, L. Cui, C.Wang, Morphologic evolution of Au nanocrystals grown in ionic liquid by plasma reduction, J. Colloid Interface Sci. 374 (2012) 40-44.

[22] Y.T. Chen, H.P.Wang, C.J. Liu, Z.Y. Zeng, H. Zhang, C.M. Zhou, X.L. Jia, Y.H. Yan, Formation of monometallic Au and Pd and bimetallic Au-Pd nanoparticles confined in mesopores via Ar glow-discharge plasma reduction and their catalytic applications in aerobic oxidation of benzyl alcohol, J. Catal. 289 (2012) 105-117.

[23] G.W. Chen, F.L. Song, X.Q. Xiong, X.J. Peng, Fluorescent nanosensors based on fluorescence resonance energy transfer (FRET), Ind. Eng. Chem. Res. 52 (2013) 11228-11245.

[24] Z. Dai, J.M. Zhang, Q.X. Dong, N. Guo, S.C. Xu, B. Sun, Y.H. Bu, Adaption of Au nanoparticles and CdTe quantum dots in DNA detection, Chin. J. Chem. Eng. 15 (2007) 791-794.

[25] J. Castain, Handbook of X-ray Photoelectron Spectroscopy, Perkin-Elmer Corporation Publishing, Minnesota, 1992. 245-246.

[26] G.V. Buxton, C.L. Greenstock, W.P. Helman, A.B. Ross, Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals ·OH/O- in aqueous solution, J. Phys. Chem. Ref. Data 17 (1988) 513-516.

[27] X. Liang, Z.J. Wang, C.J. Liu, Size-controlled synthesis of colloidal gold nanoparticles at room temperature under the influence of glow discharge, Nanoscale Res. Lett. 5 (2010) 124-129.

[28] J.J. Zou, C.J. Liu, Y.P. Zhang, Control of the metal-support interface of NiO-loaded photocatalysts via cold plasma treatment, Langmuir 22 (2006) 2334-2339.

编辑推荐 0

Metrics

阅读次数

全文

HTML			PDF

最新录用	在线预览	正式出版	最新录用	在线预览	正式出版
0	0	0	0	0	87

来源	本网站	其他网站

次数	16	71
比例	18%	82%

摘要

2497

最新录用	在线预览	正式出版

0	0	2497

来源	本网站	其他网站

次数	92	2405
比例	4%	96%

A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature

A simple plasma reduction for synthesis of Au and Pd nanoparticles at room temperature

PDF (PC)

可视化

被引次数

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐 0

Metrics

本文评价

[1]	Yifan Jiang, Bingqi Xie, Jisong Zhang. Highly reactive and reusable heterogeneous activated carbons-based palladium catalysts for Suzuki-Miyaura reaction[J]. 中国化学工程学报, 2023, 60(8): 165-172.
[2]	Wenting Fan, Fang Zhao, Ming Chen, Jian Li, Xuhong Guo. An efficient microreactor with continuous serially connected micromixers for the synthesis of superparamagnetic magnetite nanoparticles[J]. 中国化学工程学报, 2023, 59(7): 85-91.
[3]	Chen Chen, Qiong Tang, Hong Xu, Mingxing Tang, Xuekuan Li, Lei Liu, Jinxiang Dong. Alkyl-tetralin base oils synthesized from coal-based chemicals and evaluation of their lubricating properties[J]. 中国化学工程学报, 2023, 58(6): 20-28.
[4]	Masoumeh Sheikh Hosseini Lori, Mohammad Delnavaz, Hoda Khoshvaght. Synthesizing and characterizing the magnetic EDTA/chitosan/CeZnO nanocomposite for simultaneous treating of chromium and phenol in an aqueous solution[J]. 中国化学工程学报, 2023, 58(6): 76-88.
[5]	Bin Gao, Junwen Chen, Qi Zuo, Hongyan Wang, Wenlin Li. The critical role of Zr in controlling the activity of Pd/Beta on the hydrogenation of phenol to cyclohexanone[J]. 中国化学工程学报, 2023, 57(5): 79-87.
[6]	Junyu Chen, Yu Yang, Yuzheng Pan, Yang You, Liwen Hu, Meilong Hu. Wear resistance performance of high entropy alloy–ceramic coating composites synthesized via a novel combined process[J]. 中国化学工程学报, 2023, 57(5): 202-213.
[7]	Jixiang Liu, Xin Zhou, Gengfei Yang, Hui Zhao, Zhibo Zhang, Xiang Feng, Hao Yan, Yibin Liu, Xiaobo Chen, Chaohe Yang. Conceptual carbon-reduction process design and quantitative sustainable assessment for concentrating high purity ethylene from wasted refinery gas[J]. 中国化学工程学报, 2023, 57(5): 290-308.
[8]	Feng Pan, Sugang Ma, Yu Ge, Chuanlin Fan, Qingshan Zhu. Fluidization thermal decomposition of sodium fluosilicate[J]. 中国化学工程学报, 2023, 57(5): 329-337.
[9]	Jingran Liu, Yue Wu, Jie Tang, Tao Wang, Feng Ni, Qiumin Wu, Xijiao Yang, Ayyaz Ahmad, Naveed Ramzan, Yisheng Xu. Polymeric assembled nanoparticles through kinetic stabilization by confined impingement jets dilution mixer for fluorescence switching imaging[J]. 中国化学工程学报, 2023, 56(4): 89-96.
[10]	Yuhan Zhu, Jia Wei, Jun Li. Decontamination of Cr(VI) from water using sewage sludge-derived biochar: Role of environmentally persistent free radicals[J]. 中国化学工程学报, 2023, 56(4): 97-103.
[11]	Chen Chen, Yujie Liu, Qiong Tang, Hong Xu, Mingxing Tang, Xuekuan Li, Lei Liu, Jinxiang Dong. Tribological and rheological performance of lithium grease with poly-α-olefin and alkyl-tetralin as base oils[J]. 中国化学工程学报, 2023, 56(4): 180-192.
[12]	Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He. One-pot synthesis of bimetallic CeCu-SAPO-34 for high-efficiency selective catalytic reduction of nitrogen oxides with NH₃ at low temperature[J]. 中国化学工程学报, 2023, 56(4): 193-202.
[13]	Xiaoping Li, Jiaxin Pan, Jinwen Shi, Yanlin Chai, Songwei Hu, Qiaorong Han, Yanming Zhang, Xianwen Li, Dengwei Jing. Nanoparticle-induced drag reduction for polyacrylamide in turbulent flow with high Reynolds numbers[J]. 中国化学工程学报, 2023, 56(4): 290-298.
[14]	Lianlian Zhao, Fufu Di, Xiaonan Wang, Sumbal Farid, Suzhen Ren. Constructing a hollow core-shell structure of RuO₂ wrapped by hierarchical porous carbon shell with Ru NPs loading for supercapacitor[J]. 中国化学工程学报, 2023, 55(3): 93-100.
[15]	Mingdong Sun, Dongxin Pan, Tingting Ye, Jing Gu, Yu Zhou, Jun Wang. Ionic porous polyamide derived N-doped carbon towards highly selective electroreduction of CO₂[J]. 中国化学工程学报, 2023, 55(3): 212-221.