TG-FTIR analysis of pyrolusite reduction bymajor biomass components

doi:10.1016/j.cjche.2015.08.028

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (10): 1691-1697.DOI: 10.1016/j.cjche.2015.08.028

• 能源、资源与环境技术 • 上一篇下一篇

TG-FTIR analysis of pyrolusite reduction bymajor biomass components

Yunfei Long¹, Le Ruan², Xiaoyan Lü¹, Yiju Lü², Jing Su¹, YanxuanWen¹

1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2 College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

收稿日期:2014-06-26 修回日期:2015-01-16 出版日期:2015-10-28 发布日期:2015-11-27
通讯作者: YanxuanWen
基金资助:
Supported by the National Natural Science Foundation of China (21166003) and the Doctoral Foundation of Ministry of Education of China (20114501110004).

TG-FTIR analysis of pyrolusite reduction bymajor biomass components

Yunfei Long¹, Le Ruan², Xiaoyan Lü¹, Yiju Lü², Jing Su¹, YanxuanWen¹

1 School of Chemistry and Chemical Engineering, Guangxi University, Nanning 530004, China;
2 College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China

Received:2014-06-26 Revised:2015-01-16 Online:2015-10-28 Published:2015-11-27
Supported by:
Supported by the National Natural Science Foundation of China (21166003) and the Doctoral Foundation of Ministry of Education of China (20114501110004).

摘要/Abstract

摘要： Pyrolusite reduction processes by three major biomass components cellulose, hemicelluloses and lignin, represented by CP, HP and LP, respectively, were investigated by thermogravimetric analyzer coupled with Fourier transforminfrared spectrometry (TG-FTIR). The Šesták-Berggren (SB) equationwas used to evaluate the kinetics of reduction processes. TG analysis reveals that the main reduction processes occur at 250-410 ℃, 220-390 ℃, and 190-410 ℃ for CP, HP, and LP, respectively. FT-IR and XRD results indicate that various reducing volatiles (e.g. aldehydes, furans, ketones and alcohols) are produced from the pyrolysiswith the three major components, which directly reduce MnO₂ in ore to MnO. The processes are described by the SB equationwith three parameters (m, n, p). Their non-zero values suggest that pyrolusite reduction is controlled by the diffusion of reducing gaseous products through an ash/inert layer associated with minerals. The apparent activation energies for pyrolusite reduction by CP, HP and LP are 40.48, 25.70 and 40.10 kJ·mol^-1, respectively.

关键词: Pyrolusite, Reduction, Biomass, Component, TG-FTIR

Abstract: Pyrolusite reduction processes by three major biomass components cellulose, hemicelluloses and lignin, represented by CP, HP and LP, respectively, were investigated by thermogravimetric analyzer coupled with Fourier transforminfrared spectrometry (TG-FTIR). The Šesták-Berggren (SB) equationwas used to evaluate the kinetics of reduction processes. TG analysis reveals that the main reduction processes occur at 250-410 ℃, 220-390 ℃, and 190-410 ℃ for CP, HP, and LP, respectively. FT-IR and XRD results indicate that various reducing volatiles (e.g. aldehydes, furans, ketones and alcohols) are produced from the pyrolysiswith the three major components, which directly reduce MnO₂ in ore to MnO. The processes are described by the SB equationwith three parameters (m, n, p). Their non-zero values suggest that pyrolusite reduction is controlled by the diffusion of reducing gaseous products through an ash/inert layer associated with minerals. The apparent activation energies for pyrolusite reduction by CP, HP and LP are 40.48, 25.70 and 40.10 kJ·mol^-1, respectively.

Key words: Pyrolusite, Reduction, Biomass, Component, TG-FTIR

Yunfei Long, Le Ruan, Xiaoyan Lü, Yiju Lü, Jing Su, YanxuanWen. TG-FTIR analysis of pyrolusite reduction bymajor biomass components[J]. Chinese Journal of Chemical Engineering, 2015, 23(10): 1691-1697.

Yunfei Long, Le Ruan, Xiaoyan Lü, Yiju Lü, Jing Su, YanxuanWen. TG-FTIR analysis of pyrolusite reduction bymajor biomass components[J]. Chin.J.Chem.Eng., 2015, 23(10): 1691-1697.

参考文献

[1] W. Zhang, C.Y. Cheng, Manganese metallurgy review. Part I: Leaching of ores/secondary materials and recovery of electrolytic/chemical manganese dioxide, Hydrometallurgy 89 (3) (2007) 137-159.

[2] I.D. Michelis, F. Ferella, F. Beolchini, F. Veglio, Reducing acid leaching of manganiferous ore: Effect of the iron removal operation on solid waste disposal, Waste Manag. 29 (1) (2009) 128-135.

[3] P.K. Sahoo, K.S. Rao, Sulphating-roasting of low grade manganese ore: Optimization by factorial design, Int. J. Miner. Process. 25 (1) (1989) 147-152.

[4] C. Acharya, R.N. Kar, Studies on reaction mechanism of bioleaching of manganese ore, Miner. Eng. 16 (10) (2003) 1027-1030.

[5] C. Abbruzzese, Percolation leaching of manganese ore by aqueous sulfur dioxide, Hydrometallurgy 25 (1) (1990) 85-97.

[6] A.A. Ismail, E.A. Ali, I.A. Ibrahim, M.S. Ahmed, A comparative study on acid leaching of low grade manganese ore using some industrial wastes as reductants, Can. J. Chem. Eng. 82 (6) (2004) 1296-1300.

[7] T. Jiang, Y.B. Yang, Z.C. Huang, G.Z. Qiu, Simultaneous leaching ofmanganese and silver from manganese-silver ores at room temperature, Hydrometallurgy 69 (1) (2003) 177-186.

[8] H.L. Zhang, G.C. Zhu, H. Yan, Y.N. Zhao, T.C. Li, X.J. Feng, Reduction of low-grade manganese dioxide ore pellets by biomass wheat stalk, Acta Metall. Sin. Engl. Lett. 26 (2) (2013) 167-172.

[9] H.L. Zhang, G.C. Zhu, H. Yan, Y.N. Zhao, F.P. Chen,W.J.Wang, An investigation on stability of biomass reduced manganese dioxide ore, Acta Metall. Sin. Engl. Lett. 25 (6) (2012) 435-442.

[10] J.J. Song, G.C. Zhu, P. Zhang, Y.N. Zhao, Reduction of low-grade manganese oxide ore by biomass roasting, Acta Metall. Sin. Engl. Lett. 23 (3) (2010) 223-229.

[11] Z. Cheng, G.C. Zhu, Y.N. Zhao, Study in reduction-roast leaching manganese from low-grade manganese dioxide ores using cornstalk as reductant, Hydrometallurgy 96 (1) (2009) 176-179.

[12] K.D. Yang, X.J. Ye, J. Su, H.F. Su, Y.F. Long, X.Y. Lv, Y.X.Wen, Response surface optimization of process parameters for reduction roasting of low-grade pyrolusite by bagasse, Trans. Nonferrous Met. Soc. China 23 (2) (2013) 548-555.

[13] Y.F. Long, J. Su, X.J. Ye, H.F. Su, Y.X.Wen, Reduction-roast leaching of low-grade pyrolusite using bagasse as a reducing agent, Adv. Mater. Res. 699 (1) (2013) 28-33.

[14] Y.H. Zhou, H. Yao, Y.F. Long, J. Su, J. Liu, X.H. Zhou, T. Gan, Z.M. Lei, Y.X.Wen, Reduction roasting and leaching of low-grade pyrolusite with bagasse pith at low temperature, Chin. J. Process. Eng. 13 (6) (2013) 946-951.

[15] M. Zhang, Y.C. Yuan, Y.Z. Liu, Research on biomass waste combustion technologies, Energy Res. Inf. 21 (1) (2005) 15-19.

[16] X.J. Ye, J. Su, H.F. Su, Y.F. Long, Y.X.Wen, Analysis of the bagasse roasting low-grade pyrolusite using TG-FTIR, J. Guangxi Uni. Nat. Sci. Ed. 37 (3) (2012) 440-444.

[17] A.W. Coats, J.P. Redfern, Kinetic parameters from thermogravimetric data, Nature 201 (1) (1964) 68-69.

[18] H.L. Zhang, G.C. Zhu, H. Yan, T.C. Li, X.J. Feng, Thermogravimetric analysis and kinetics on reducing low-grademanganese dioxide ore by biomass, Metall.Mater. Trans. B 44B (4) (2013) 878-888.

[19] T.C. Li, Y.N. Zhao, Themechanism on biomass reduction of low-grademanganese dioxide ore, Metall. Mater. Trans. B 44B (4) (2013) 878-888.

[20] Y.N. Zhao, G.C. Zhu, C. Zhuo, Thermal analysis and kinetic modeling of manganese oxide ore reduction using biomass straw as reductant, Hydrometallurgy 105 (1) (2010) 96-102.

[21] S.V. Vassilev, D. Baxter, L.K. Andersen, C.G. Vassileva, T.J.Morgan, An overviewof the organic and inorganic phase composition of biomass, Fuel 94 (1) (2012) 1-33.

[22] H.P. Yang, R. Yan, H.P. Chen, D.H. Lee, C.G. Zheng, Characteristics of hemicellulose, cellulose and lignin pyrolysis, Fuel 86 (12) (2007) 1781-1788.

[23] A. Corma, S. Iborra, A. Velty, Chemical routes for the transformation of biomass into chemicals, Chem. Rev. 107 (6) (2007) 2411-2502.

[24] S.Z. Xin, H.P. Yang, Y.Q. Chen, X.H. Wang, H.P. Chen, Assessment of pyrolysis polygeneration of biomass based on major components: product characterization and elucidation of degradation pathways, Fuel 113 (2) (2013) 266-273.

[25] L. Burhenne, J. Messmer, T. Aicher, M.P. Laborie, The effect of the biomass components lignin, cellulose and hemicellulose on TGA and fixed bed pyrolysis, J. Anal. Appl. Pyrolysis 101 (1) (2013) 177-184.

[26] W.W.Wendlandt, ThermalMethods of Analysis, 2nd ed. JohnWiley & Sons Inc., New York, 1974 1-125.

[27] L. Vlaev, N. Nedelchev, K. Gyurova, M. Zagorcheva, A comparative study of nonisothermal kinetics of decomposition of calcium oxalate monohydrate, J. Anal. Appl. Pyrolysis 82 (2) (2008) 253-262.

[28] J. Šesták, G. Berggren, Study of the kinetics of themechanismof solid state reactions at increasing temperature, Thermochim. Acta 3 (1) (1971) 1-12.

[29] P. Šimon, Fourty years of the Šesták-Berggren equation, Thermochim. Acta 520 (1) (2011) 156-157.

[30] A.K. Burnham, Application of the Šesták-Berggren equation to organic and inorganic materials of practical interest, J. Therm. Anal. Calorim. 60 (3) (2000) 895-908.

[31] P. Fu, S. Hu, J. Xiang, L. Sun, T. Yang, A. Zhang, J. Zhang, Mechanism study of rice straw pyrolysis by Fourier transform infrared technique, Chin. J. Chem. Eng. 17 (3) (2009) 522-529.

[32] D. Shen, S. Gu, The mechanism for thermal decomposition of cellulose and its main products, Bioresour. Technol. 100 (24) (2009) 6496-6504.

[33] R. French, S. Czernik, Catalytic pyrolysis of biomass for biofuels production, Fuel Process. Technol. 91 (1) (2010) 25-32.

[34] Q. Liu, S. Wang, Y. Zheng, Z. Luo, K. Cen, Mechanism of wood lignin pyrolysis by using TG-FTIR analysis, J. Anal. Appl. Pyrolysis 82 (1) (2008) 170-177.

[35] S. Li, J. Lyons-Hart, J. Banyasz, K. Shafer, Real-time evolved gas analysis by FTIR method: An experimental study of cellulose pyrolysis, Fuel 80 (12) (2001) 1809-1817.

[36] R.N. Sahoo, P.K. Naik, S.C. Das, Leaching of manganese from low-grade manganese ore using oxalic acid as reductant in sulphuric acid solution, Hydrometallurgy 98 (3-4) (2009) 314-317.

[37] M.N. Hazek, T.A. El Lasheen, A.S. Helal, Reductive leaching of manganese from low grade Sinai ore in HCl using H₂O₂ as reductant, Hydrometallurgy 84 (3-4) (2006) 187-191.

TG-FTIR analysis of pyrolusite reduction bymajor biomass components

TG-FTIR analysis of pyrolusite reduction bymajor biomass components

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